首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
On the basis of data obtained by the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS) box model calculations are performed to investigate the ozone budget in the upper stratosphere. The HALOE data comprise measurements of major source gases and key chemical species involved in the ozone destruction cycles. In comparison to earlier calculations using version 17 of the HALOE data, the calculated ozone destruction rate increases when the updated data version 18 is used. However, as with the previous study using version 17 of the HALOE data, no evidence for a significant model ozone deficit is found.  相似文献   

2.
Measurements of atmospheric composition have been made over a remote rainforest landscape. A box model has previously been demonstrated to model the observed daytime chemistry well. However the box model is unable to explain the nocturnal measurements of relatively high [NO] and [O3], but relatively low observed [NO2]. It is shown that a one-dimensional (1-D) column model with simple O3-NOx chemistry and a simple representation of vertical transport is able to explain the observed nocturnal concentrations and predict the likely vertical profiles of these species in the nocturnal boundary layer (NBL). Concentrations of tracers carried over from the end of the night can affect the atmospheric chemistry of the following day. To ascertain the anomaly introduced by using the box model to represent the NBL, vertically-averaged NBL concentrations at the end of the night are compared between the 1-D model and the box model. It is found that, under low to medium [NOx] conditions (NOx?<?1 ppbv), a simple parametrisation can be used to modify the box model deposition velocity of ozone, in order to achieve good agreement between the box and 1-D models for these end-of-night concentrations of NOx and O3. This parametrisation would could also be used in global climate-chemistry models with limited vertical resolution near the surface. Box-model results for the following day differ substantially if this effective nocturnal deposition velocity for ozone is implemented; for instance, there is a 9% increase in the following days peak ozone concentration. However under medium to high [NOx] conditions (NOx > 1 ppbv), the effect on the chemistry due to the vertical distribution of the species means no box model can adequately represent chemistry in the NBL without modifying reaction rate coefficients.  相似文献   

3.
A photochemical box model has been used to simulate the mixing ratio ofozone under conditions reflecting those encountered in the marine boundarylayer at Cape Grim, Tasmania, where a decade-long record of ozone mixingratio is available. The model is based on the proposition that ozone loss byphotolysis, atmospheric reaction with hydroperoxy and hydroxyl radicals, andsurface deposition is balanced by ozone gain via entrainment from the lowerfree troposphere with a small additional source in summer from photolysis ofnitrogen dioxide. This model simulates very well the observed ozone records,reproducing both the small diurnal cycle in ozone mixing ratio observedduring the summer months, and the factor of two seasonal ozone cycle showinga distinct winter maximum and summer minimum. The model result confirms thatunder the low-NOx conditions of the clean marine boundarylayer net photochemical loss of ozone occurs at all times of year.  相似文献   

4.
国产臭氧探空仪观测数据质量分析   总被引：2，自引：1，他引：2       下载免费PDF全文
对国产臭氧探空仪从2001年4月到2004年9月在北京观测的臭氧垂直分布数据的质量进行分析。对国产臭氧探空仪系统基本测量数据(包括电化学反应池池温、臭氧最大分压及其所在的高度、对流层顶的温度和高度)进行初步分析, 结果发现国产臭氧探空仪的稳定性仍需进一步提高。与地面多谱森臭氧总量观测相比, 国产臭氧探空积分的总量普遍要高,2002年至2003年之间的差别范围基本上保持在±20%以内。与国际普遍使用的双池型电化学(ECC型)臭氧探空观测结果相比, 国产臭氧探空观测臭氧分压在15 km以下、25～30km两个高度范围, 均要高于ECC测值。分析结果建议国产臭氧探空仪应尽快参与由全球大气本底监测(GAW)技术主持的世界臭氧探空仪标定中心进行标定, 并在现有的技术条件下, 向双池型电化学型臭氧探空仪这一方向发展  相似文献   

5.
Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.  相似文献   

6.
We summarize an on-line coupled meteorological–emissions–photochemical modelling system that allows feedback from air-quality/chemistry to meteorology via radiative forcing. We focus on the radiative-forcing impacts (direct effects) of ozone. We present an application of the coupled modelling system to the episode of 23–31 July 1998 in Portland, Oregon, U.S.A. Results suggest that the inclusion of radiative-forcing feedback produces small but accountable impacts. For this region and episode, stand-alone radiative transfer simulations, i.e., evaluating the effects of radiative forcing independently of changes in meteorology or emissions, suggest that a change of 1 ppb in ground-level ozone is approximately equivalent to a change of 0.017 W m−2 in radiative forcing. In on-line, coupled, three-dimensional simulations, where the meteorological dependencies are accounted for, domain-wide peak ozone concentrations were higher by 2–4 ppb (relative to a simulated peak of 119.4 ppb) when including the effects of radiative-forcing feedback. A scenario of 10% reduction in anthropogenic emissions produced slightly larger decreases in ozone, an additional 1 ppb in local-peak reductions, relative to scenarios without feedback.  相似文献   

7.
Radiative forcing has been widely used as a metric of climate change, i.e. as a measure by which various contributors to a net surface temperature change can be quantitatively compared. The extent to which this concept is valid for spatially inhomogeneous perturbations to the climate system is tested. A series of climate model simulations involving ozone changes of different spatial structure reveals that the climate sensitivity parameter is highly variable: for an ozone increase in the northern hemisphere lower stratosphere, it is more than twice as large as for a homogeneous CO2 perturbation. A global ozone perturbation in the upper troposphere, however, causes a significantly smaller surface temperature response than CO2. The variability of the climate sensitivity parameter is shown to be mostly due to the varying strength of the stratospheric water vapour feedback. The variability of the sea-ice albedo feedback modifies climate sensitivity of perturbations with the same vertical structure but a different horizontal structure. This feedback is also the origin of the comparatively larger climate sensitivity to perturbations restricted to the northern hemisphere extratropics. As cloud feedback does not operate independently from the other feedbacks, quantifying its effect is rather difficult. However, its effect on the variability of for horizontally and vertically inhomogeneous perturbations within one model framework seems to be comparatively small.This revised version was published online March 2005 with corrections to table 5.  相似文献   

8.
刘寅 《大气科学》2014,38(6):1066-1078
我国第二代极轨气象卫星“风云三号”A星(FY-3A)上搭载的紫外臭氧总量探测仪(Total Ozone Unit,TOU)每天可以提供一次覆盖全球的臭氧总量观测。为了在数值预报中应用TOU的臭氧资料,从资料同化角度发展了一套质量控制方案。首先基于臭氧总量和平均位势涡度的高相关性建立了逐日动态更新的臭氧线性回归预报模型,然后使用双权重算法对臭氧资料进行质量控制。将该质量控制方案应用于台风Tembin(2012)和Isaac(2012)个例,试验结果说明该方案可以体现出臭氧总量和平均位势涡度之间相关关系的逐日变化,识别出的离群资料百分比随时间变化较稳定,可以保留原始资料的主体信息,并且显著降低了原始资料的标准差。同时,质量控制后的臭氧数据与统计拟合量更加一致,观测减拟合的概率密度函数分布形式也更接近高斯分布,有利于后续的资料同化。  相似文献   

9.
随着微创手术的发展,虚拟手术的应用前景越来越广阔.力反馈作为虚拟手术的核心技术,其实现的效果直接影响了虚拟手术的沉浸感.通过对经典包围盒碰撞检测算法进行研究比对,选择了球包围盒的碰撞检测算法,并建立了精确的反馈力计算模型,实现了介入血管中的柔性碰撞仿真.该仿真具有很高的实时性和精度.  相似文献   

10.
Local ozone production and loss rates for the arctic free troposphere (58–85° N, 1–6 km, February–May) during the TroposphericOzone Production about the Spring Equinox (TOPSE) campaign were calculated using a constrained photochemical box model. Estimates were made to assess the importance of local photochemical ozone production relative to transport in accounting for the springtime maximum in arctic free tropospheric ozone. Ozone production and loss rates from our diel steady-state box model constrained by median observations were first compared to two point box models, one run to instantaneous steady-state and the other run to diel steady-state. A consistent picture of local ozone photochemistry was derived by all three box models suggesting that differences between the approaches were not critical. Our model-derived ozone production rates increased by a factor of 28 in the 1–3 km layer and a factor of 7 in the 3–6 kmlayer between February and May. The arctic ozone budget required net import of ozone into the arctic free troposphere throughout the campaign; however, the transport term exceeded the photochemical production only in the lower free troposphere (1–3 km) between February and March. Gross ozone production rates were calculated to increase linearly with NOx mixing ratiosup to 300 pptv in February and for NOx mixing ratios up to 500 pptv in May. These NOx limits are an order of magnitude higher thanmedian NOx levels observed, illustrating the strong dependence ofgross ozone production rates on NOx mixing ratios for the majority of theobservations. The threshold NOx mixing ratio needed for netpositive ozone production was also calculated to increase from NOx 10pptv in February to 25 pptv in May, suggesting that the NOx levels needed to sustain net ozone production are lower in winter than spring. This lower NOx threshold explains how wintertime photochemical ozone production can impact the build-up of ozone over winter and early spring. There is also an altitude dependence as the threshold NOx neededto produce net ozone shifts to higher values at lower altitudes. This partly explains the calculation of net ozone destruction for the 1–3 km layerand net ozone production for the 3–6 km layer throughout the campaign.  相似文献   

11.
The interactively coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM is employed in sensitivity calculations to investigate feedback mechanisms of dynamic, chemical, and radiative processes. Two multi-year model simulations are carried out, which represent recent atmospheric conditions. It is shown that the model is able to reproduce observed features and trends with respect to dynamics and chemistry of the troposphere and lower stratosphere. In polar regions it is demonstrated that an increased persistence of the winter vortices is mainly due to enhanced greenhouse gas mixing ratios and to reduced ozone concentration in the lower stratosphere. An additional sensitivity simulation is investigated, concerning a possible future development of the chemical composition of the atmosphere and climate. The model results in the Southern Hemisphere indicate that the adopted further increase of greenhouse gas mixing ratios leads to an intensified radiative cooling in the lower stratosphere. Therefore, Antarctic ozone depletion slightly increases due to a larger PSC activity, although stratospheric chlorine is reduced. Interestingly, the behavior in the Northern Hemisphere is different. During winter, an enhanced activity of planetary waves yields a more disturbed stratospheric vortex. This "dynamical heating" compensates the additional radiative cooling due to enhanced greenhouse gas concentrations in the polar region. In connection with reduced stratospheric chlorine loading, the ozone layer clearly recovers.  相似文献   

12.
云对云中大气臭氧影响因子的分析   总被引：3，自引：0，他引：3  
应用一个较详细的气相光化学和液相化学耦合的箱体模式, 研究了云层对云中大气臭氧的影响过程。这一过程可分解为三个因子来考虑： 因子Ａ （云的辐射效应）, 由于云的存在改变太阳光辐射通量, 使得对流层光化学反应减弱或增强, 从而降低或增加臭氧浓度; 因子Ｂ（云的吸收效应）, 云层中液态水对大气臭氧及其前体物 （ＮＯｘ、ＮＭＨＣ、自由基等） 的直接吸收作用; 因子Ｃ（云的液相化学效应）, 吸收进入云中的物质发生液相化学反应从而改变大气臭氧浓度。数值研究结果表明： 上述三因子对云中臭氧浓度影响的程度差别很大, 并且与云层的物理结构有密切关系。讨论了云的吸收及液相化学效应影响臭氧浓度的主要原因  相似文献   

13.
Abstract

The role of sea‐ice in affecting the stability and long‐term variability of the oceanic thermohaline circulation (THC) is studied in this paper. The emphasis is placed on studying how sea‐ice might affect the stability and the long‐term variability of the THC through modulations of the surface heat and freshwater fluxes. A simple box model is analyzed to elucidate qualitatively the distinct physical meanings of these two processes. The analytical solution of this simple model indicates that, for the long timescales considered here, the thermal insulation stabilizes the THC while the freshwater feedback increases the effective inertia of the coupled ice‐ocean system. Sea‐ice insulation lessens the negative feedback between heat flux and the SST, and therefore, allows the SST to play a greater role in counteracting changes of the THC and high latitude salinity field. The freshwater feedback effectively links the surface heat flux to a freshwater reservoir, and thus, increases the effective inertia of the coupled ocean‐ice system. A two‐dimensional ocean model coupled with a thermodynamic sea‐ice model is used to estimate quantitatively the magnitudes of these two feedbacks. The numerical experiments involve the model's responses both to initial anomalies and to changes of forcing fields. For the free response cases (model responses to initial anomalies without changing the forcing fields), the model shows that the decay rate of an initial anomaly is greater when sea‐ice is included. For small perturbations the thermal insulation effect dominates over the freshwater feedback. The latter becomes increasingly more important for larger perturbations. In response to a change of external forcing, the presence of sea‐ice reduces the magnitude and the pace of the model's response. The numerical results are qualitatively consistent with the analytical solution of the box model.  相似文献   

14.
The relationship between the emission of ozone precursors and the chemical production of tropospheric ozone(O3) in the Pearl River Delta Region(PRD) was studied using numerical simulation.The aim of this study was to examine the volatile organic compound(VOC)-or nitrogen oxide(NOx =NO+NO2)limited conditions at present and when surface temperature is increasing due to global warming,thus to make recommendations for future ozone abatement policies for the PRD region.The model used for this application is the U.S.Environmental Protection Agency’s(EPA’s) third-generation air-quality modeling system;it consists of the mesoscale meteorological model MM5 and the chemical transport model named Community Multi-scale Air Quality(CMAQ).A series of sensitivity tests were conducted to assess the influence of VOC and NOx variations on ozone production.Tropical cyclone was shown to be one of the important synoptic weather patterns leading to ozone pollution.The simulations were based on a tropicalcyclone-related episode that occurred during 14-16 September 2004.The results show that,in the future,the control strategy for emissions should be tightened.To reduce the current level of ozone to meet the Hong Kong Environmental Protection Department(EPD) air-quality objective(hourly average of 120 ppb),emphasis should be put on restricting the increase of NOx emissions.Furthermore,for a wide range of possible changes in precursor emissions,temperature increase will increase the ozone peak in the PRD region;the areas affected by photochemical smog are growing wider,but the locations of the ozone plume are rather invariant.  相似文献   

15.
Wintertime temperature and ozone in the Northern Hemisphere stratosphere vary significantly between years. Largely random, those variations are marked by compensating changes at high and low latitudes, a feature that reflects the residual mean circulation of the stratosphere. Interannual changes of temperature and ozone each track anomalous forcing of the residual circulation. This relationship is shown to be obeyed even over the Arctic, where transport is augmented by heterogeneous chemical processes that destroy ozone. Chlorine activation obeys a similar relationship, reflecting feedback between changes of the residual circulation and anomalous photochemistry.Changes of stratospheric dynamical and chemical structure are found be accompanied by coherent changes in the troposphere. Vertically extensive, they reflect inter-dependent changes in the stratosphere and troposphere, which are coupled by the residual circulation through transfers of mass. The corresponding structure is shown to share major features with empirical modes of interannual variability associated with the AO and its cousin, the NAO.A 3D model of dynamics and photochemistry is used to simulate anomalous temperature and ozone. Driven by anomalous wave activity representative of that observed, the model reproduces the salient structure of observed interannual changes. Anomalous temperature and ozone follow in the integrations from anomalous downwelling, which, under disturbed conditions, renders temperature over the Arctic anomalously warm, and from anomalous poleward transport, which renders Arctic ozone anomalously rich.Accompanying random interannual changes in the observed record was a systematic decline of Northern Hemisphere temperature and ozone during the 1980s and early 1990s. Comprising decadal trends, these systematic changes are shown to have the same essential structure and seasonality as random changes, which, in turn, vary coherently with anomalous forcing of the residual circulation. Implications of the findings to the interpretation of stratospheric trends are discussed in light of anomalous residual motion, photochemistry, and feedback between them.  相似文献   

16.
北极臭氧垂直分布和天气尺度变化的观测研究   总被引：2，自引：0，他引：2  
北极地区臭氧对北极气候和环境系统起着重要作用。研究其分布和变化有助于了解北极的气候和环境及其对全球气候系统的影响,有助于气候和环境变化的数值预报。中国北极科学探测1999在北冰洋楚可奇海域成功的进行了大气臭氧观测。通过在中国“雪龙”号破冰船甲板上（于1999年8月18-24日在75°N,160°W附近处）释放大气臭氧探空仪获得了高分辨率的大气垂直结构和臭氧分布资料,可以进行大气尺度的大气臭氧变化研究。分析大气监测资料、TOMS臭氧总量资料和NCEP大气环流资料表明,大气臭氧总量随着对流层顶的低一高一低变化呈高一低一高的变化过程。研究还表明,大气柱的臭氧总量与13公里以下的大气臭氧含量关系密切,而在约20公里处的大气臭氧浓度最大值的变化与整个气柱臭氧的关系不大。500 hPa天气形势图上一个弱一强一弱的西南天气型造成的弱臭氧平流可能是这次臭氧变化的主要原因。  相似文献   

17.
A photochemical box model has been used to model themeasured diurnal ozone cycle in spring at Jungfraujochin the Swiss Alps. The comparison of the modelleddiurnal ozone cycle with the mean measured diurnalozone cycle in spring, over the period 1988–1996,shows a good agreement both with regard to the shapeand amplitude. Ozone concentrations increase duringthe daytime and reach a maximum at about 16:00–17:00(GMT) in both the modelled and the mean observed ozonecycle, indicative of net ozone production during thedaytime at Jungfraujoch in spring. The agreement isbetter when the modelled ozone cycle is compared withthe mean measured diurnal cycle (1988–1996) filteredfor north-westerly winds >5 m/s (representative ofregional background conditions at Jungfraujoch). Inaddition to ozone, the modelled diurnal cycle of[HO2] + [CH3O2] also shows rather goodagreement with the mean diurnal cycle of the peroxyradicals measured during FREETEX '96, a FREETropopsheric Experiment at Jungfraujoch in April/May1996. Furthermore, this mean diurnal cycle of the sumof the peroxy radicals measured during FREETEX '96 isused to calculate, using steady-state expressions, therespective diurnal cycle of the OH radical. Thecomparison of the OH diurnal cycle, calculated fromthe peroxy radical measurements during FREETEX '96,with the modelled one, reveals also good agreement.The net ozone production rate during the day-time is0.27 ppbv h-1 from the model, and 0.13 ppbvh-1 from the observations during FREETEX '96. Theobservations and model results both suggest that thediurnal ozone variation in spring at Jungfraujoch isprimarily of photochemical origin. Furthermore, theobserved and modelled positive net ozone productionrates imply that tropospheric in situphotochemistry contributes significantly to theobserved high spring ozone values in the observedbroad spring-summer ozone maximum at Jungfraujoch.  相似文献   

18.
为检验臭氧卫星资料同化对臭氧分析场和预报场的影响,基于集合平方根滤波(ENSRF)理论,结合通用地球系统模式(CESM),构建了CESM-ENSRF同化预报系统。系统构建过程考虑了卡尔曼滤波同化中的关键问题:利用全场随机扰动对初始场加扰,结合一般协方差膨胀和松弛协方差膨胀方法实现协方差膨胀,使用五阶距离相关函数进行协方差局地化。将构建的系统用于微波临边探测器(MLS)臭氧廓线数据的同化,分析臭氧卫星资料同化对模式预报的影响。结果表明:构建的CESM-ENSRF同化系统有效实现了臭氧资料同化,臭氧卫星资料同化对臭氧分析场和预报场精度有较大改进。  相似文献   

19.
Global secondary organic aerosol formation (SOA) is currently assumed to be between 11.2 and 270 Tg/yr. This range of uncertainty is reflected in the gas-phase chemistry. In this study, we focus on the feedback of SOA formation on the concentrations of most important trace gases such as ozone, and compare it to the impact of monoterpene gas-phase chemistry with a newly developed reduced monoterpene mechanism (MMM) for either α- or β-pinene in the global chemistry transport model MATCH-MPIC. With this set-up an uncertainty range of 3.5–4.0% increase in annually averaged tropospheric ozone was found to be caused by the gas-phase chemistry of the investigated monoterpenes. Moreover, a strong feedback has been observed for NOx, HCHO, HNO3 and PAN. These observations are affected remarkably by different SOA formation approaches like partitioning or saturation vapour pressure limitation and by the structure of the monoterpene used, e.g. reducing the impact on tropospheric ozone to 1.2–1.9% by using the partitioning approach versus the simulation with gas-phase chemistry only. Therefore, a consideration of the individual processes associated with SOA formation seems to be necessary to reduce the uncertainty in SOA formation and to understand the impact of VOCs on atmospheric chemistry. An erratum to this article is available at .  相似文献   

20.
Ozone photochemical production and loss in very different environments at Waliguan baseline station and Lin'an background station were simulated by using the measurement data and photochemical box model.The results show that net ozone photochemical production rate is negative,about 0.5 ppb/d,at Waliguan baseline sation,because of very low precursor concentrations.But at Lin'an background station,the net photochemical ozone production is positive,about 2-3 ppb/h.which is very closed with the measurement at Lin'an.That means ozone production was controlled by photochemical reactions at Lin'an background station,because of the higher precursor concentrations.The net destruction rate,at Waliguan Mt.,is not large,so that future increase in anthropogenic emission of reactive nitrogen will lead to larger production rates of steady-state O3 concentration.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号