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1.
黑龙江霍龙门地区位于兴蒙造山带东部的兴安地块和松嫩地块接触带上,区内花岗岩类以晚古生代花岗岩为主,岩性主要为二长花岗岩、正长花岗岩、碱长花岗岩.研究区二长花岗岩SHRIMP锆石U-Pb定年结果为(351.5±3.5)Ma,表明其形成于早石炭世.该时代岩石的主量元素具有高硅、略富铝、富碱质、低镁和贫钙的特征;微量元素表现出Th、Zr、Nd、Rb、K明显富集,而Ba、Sr、Nb、P、Ti明显亏损;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,有明显的负Eu异常,轻重稀土元素分馏程度较强.岩石总体上属于高钾钙碱性系列花岗岩.花岗岩的R1-R2构造环境判别图解与微量元素Rb-(Yb+Nb)、Rb-(Yb+Ta)构造环境判别图解显示,该期发育的早石炭世花岗岩为同碰撞与造山期后的环境,结合本区所处的构造环境推测研究区内早石炭世花岗岩应为兴安地块与松嫩地块北东向拼合挤压过程由碰撞俯冲阶段向后造山阶段构造转换过程的产物.  相似文献   

2.
霍龙门地区位于兴蒙造山带东部的兴安地块和松嫩地块接触带上,区内花岗岩类以晚古生代花岗岩为主,同时还有一定量的中生代花岗岩,岩性为二长花岗岩、花岗闪长岩、石英二长岩和碱长花岗岩等.二长花岗岩的SHRIMP锆石U-Pb定年结果为175.2±2.2 Ma,表明其形成于中侏罗世.该时代岩石的主量元素具有高钾、富钠、略富铝、低镁和贫磷贫钙的特征;微量元素表现出U、Th、Zr、Ta、Rb明显富集,而Ba、Sr、Nb、P、Ti明显亏损;稀土元素含量相对偏低,具有轻稀土元素相对富集、重稀土元素相对亏损的特征,有较弱的负Eu异常,轻重稀土元素分馏程度较强.岩石总体上属于高钾钙碱性系列花岗岩.花岗岩的R1-R2构造环境判别图解与微量元素Rb-(Yb+Nb)、Rb-(Yb+Ta)构造环境判别图解显示,该期发育的中侏罗世花岗岩处于同碰撞期到造山期后的构造环境.结合区域花岗岩展布特征及反映的构造环境综合认为,研究区内中侏罗世花岗岩应处于蒙古-鄂霍次克洋闭合后陆-陆碰撞环境.  相似文献   

3.
黑龙江霍龙门地区位于兴蒙造山带东部的兴安地块和松嫩地块接触带上,区内花岗岩类以晚古生代花岗岩为主,岩性主要为正长花岗岩、二长花岗岩、碱长花岗岩和二长闪长岩等。研究区的正长花岗岩的SHRIMP锆石U-Pb定年结果为294.8 Ma±1.8Ma,表明其形成于早二叠世,且在早三叠世(244.6 Ma±4.1 Ma)遭受了较弱的岩浆侵位事件的叠加影响。该时代岩石的主量元素具有高钾(K_2O质量分数平均为4.52%)、富钠(Na_2O质量分数平均为3.85%)、略富铝(Al_2O_3质量分数平均为13.73%)、低镁(MgO质量分数平均为0.21%)和贫磷(P_2O_5质量分数平均为0.06%)贫钙(CaO质量分数平均为0.61%)的特征;微量元素表现出Th,Zr,Nd,Rb明显富集,而Ba,Sr,P,Ti明显亏损;稀土元素具有轻稀土元素富集、重稀土元素相对亏损的特征,有较明显的负Eu异常(δEu平均为0.49),轻重稀土元素分馏程度较强。岩石总体上属于高钾钙碱性系列花岗岩。花岗岩的R_1-R_2构造环境判别图解与微量元素Rb-Yb+Nb,Rb-Yb+Ta构造环境判别图解显示,该期发育的早二叠世花岗岩处于碰撞造山晚期向造山期后伸展的构造环境,结合区域北东向大量分布晚石炭世-早二叠世期间反映造山期后伸展环境的A型花岗岩的特征及本区所处的构造环境推测,研究区内早二叠世花岗岩应为兴安地块与松嫩地块北东向碰撞造山晚期向造山期后伸展拉张环境下岩浆侵位的产物。  相似文献   

4.
大兴安岭诺敏地区大地构造位置位于兴蒙造山带的东段.该区发育大量的二叠纪花岗岩类岩石,岩性主要为二长花岗岩、钾长花岗岩.岩石地球化学分析结果表明,该区岩体具有高硅,略富铝,偏碱,低镁、钠,贫钙的特征.微量元素表现出富集Rb、Th、K、Nd、Cs和亏损U、Nb、Sr、P、Ti等特点;稀土元素具有明显的轻稀土元素富集、重稀土元素亏损和明显的负Eu异常特征.轻重稀土元素分馏程度较强.岩石总体上属于高钾钙碱性系列花岗岩.地球化学特征表明其应为S型花岗岩,可能为同源的地壳物质的部分熔融作用所形成,源岩可能为变杂砂岩和变中性火山岩.根据R1-R2与Rb-(Yb+Nb)、Rb-(Yb+Ta)等微量元素判别图解,结合该区所处的构造环境推测,该区花岗岩应形成于兴安地块与松嫩地块碰撞造山过程的后碰撞阶段.  相似文献   

5.
黑龙江宝山地区在构造上位于兴蒙造山带东部的松嫩地块和佳木斯地块之间的伊春-延寿花岗岩带北段,区内分布大面积的古生代-中生代花岗岩.其中海西晚期花岗岩,岩性主要为碱长花岗岩、二长花岗岩和花岗闪长岩等,锆石U-Pb法 LA-ICP MS测年结果为252.6±3 Ma.其主量元素表现出富Si、略富Al、富碱质和低Mg、低Ca的特点;微量元素表现出富集Rb、Nd、K、Pb、U和亏损Nb、Ta、P、Ti等高场强元素的特点,并且Sr、Ba呈明显的负异常;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,轻重稀土元素分馏程度较高.岩石总体上属于高钾钙碱性花岗岩,是岩浆经历了高度结晶分异作用的产物.矿物化学和岩石地球化学特征表明其特征类似于S型花岗岩,源岩物质来自于地壳.  相似文献   

6.
大兴安岭多宝山地区在构造上位于兴蒙造山带东部的兴安地块和松嫩地块接触带上,区内花岗岩类以晚古生代花岗岩为主,岩性主要为碱长花岗岩、正长花岗岩.两类岩性的锆石SHRIMP测年结果分别为(309.0±3.0)Ma、(299.3±2.8)Ma,均为晚石炭世.其主量元素以富Si、略富Al、富碱质和低Mg、低Ca为特点;微量元素表现出富集Th、Zr、Nd、Rb、K和亏损Ba、Sr、P、Ti的特点;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,轻重稀土元素分馏程度较强.岩石总体上属于高钾钙碱性系列花岗岩,是岩浆经历了高度结晶分异作用的产物.岩石地球化学特征表明其特征类似S型花岗岩,其源岩物质来自于地壳.  相似文献   

7.
勐养侵入岩体位于滇西腾冲地块梁河县南勐养镇一带,主要由黑云母二长花岗岩和花岗闪长岩组成,其中发育闪长质包体。闪长岩包体与寄主岩石黑云母二长花岗岩和花岗闪长岩之间呈渐变过渡关系。锆石U-Pb LA-ICP-MS定年表明,黑云母二长花岗岩形成年龄为127.7Ma±0.7Ma,花岗闪长岩形成年龄为115.2Ma±1.1Ma。闪长岩包体形成年龄为122.6Ma±0.8 Ma。表明该花岗岩体的形成时代属于早白垩世。地球化学特征研究表明,闪长岩包体为准铝质、钙碱性系列,具有低SiO2、高MgO、高K20和Mg#的特征。Sm/Nd为0.18~0.20,ΣLREE/ΣHREE=2.91~4.64,Eu存在弱到中等程度的负异常。相对富集U,Th,Rb,Ba等大离子亲石元素(LILE),亏损Tb,Nb,Zr,Hf等高场强元素(HFSE);反映勐养闪长岩包体岩浆成分主要为幔源的特点。根据地球化学特征和微量元素构造判别图解判别结果表明,勐养早白垩世侵入岩形成于碰撞后岩浆弧环境。闪长岩包体的原生岩浆应是地幔橄榄岩部分熔融的产物。黑云二长花岗岩浆可能来源于本区中晚元古代高黎贡山群为代表的地壳物质的部分熔融。花岗闪长岩为幔源岩浆与高黎贡山群古老地壳部分熔融的岩浆混合的产物。腾冲地块早白垩世侵入岩与班公湖—怒江—泸水—瑞丽洋盆的闭合、洋壳向南西俯冲及板块间的碰撞造山作用密切相关。  相似文献   

8.
加容检德工卡侵入岩序列由石英闪长岩-英云闪长岩-花岗闪长岩-正长花岗岩组成。岩石化学成分表现为从中基性到酸性的演化及岩浆向富硅、富碱方向演化。稀土元素特征表现为轻稀土元素富集;微量元素特征表现为富集大离子亲石元素Rb、K、Ba、Th,而Sr、Nb、Ta略显亏损,Ti、P较强亏损。构造环境为同碰撞花岗岩,时代为早白垩世。  相似文献   

9.
大兴安岭东北部哈拉巴奇花岗岩体锆石U-Pb年龄及其成因   总被引:13,自引:4,他引:13  
哈拉巴奇岩体主要由二长花岗岩钾长花岗岩和花岗闪长岩组成。样品的LAICPMS锆石UPb年龄测定和主量及微量元素的分析结果表明,哈拉巴奇岩体为两次侵位的早古生代花岗岩体,其中二长花岗岩钾长花岗岩的侵位时间较早(500Ma),花岗闪长岩的侵位时间相对较晚(461Ma);岩体具有后造山花岗岩类的岩石组合特征和地球化学特征,为额尔古纳地块与兴安地块碰撞拼贴作用结束后的后造山阶段的产物;二长花岗岩钾长花岗岩和花岗闪长岩起源于相同的岩浆源区,其源区物质可能是中元古代期间地幔中新增生的地壳物质,二者地球化学特征的差别是源岩部份熔融程度不同所致。  相似文献   

10.
上黑龙江盆地前哨林场位于兴蒙造山带东段额尔古纳微地块北缘, 北与西伯利亚古陆以蒙古—鄂霍次克缝合带相隔, 东以塔源—喜桂图断裂与兴安地块相邻。本文通过对上黑龙江盆地前哨林场黑云母二长花岗岩进行锆石U-Pb年龄、主微量及同位素地球化学系统研究, 为探讨早古生代额尔古纳微地块与相邻地块的碰撞机制提供理论依据。利用LA-ICP-MS锆石U-Pb同位素测定技术, 获得研究区黑云母二长花岗岩结晶年龄为(458.4±2.4) Ma(MSWD=0.022), 确定了岩体形成时代为早古生代中—晚奥陶纪。岩石中锆石Hf同位素?Hf(t)值介于–4.64 ~ 1.84, 其测点大部分位于球粒陨石演化线之下, 两阶段模式年龄(tDM2)介于 715 ~ 1 126 Ma。地球化学显示岩石具有富硅、富铝、富碱等特征; 稀土配分曲线表现出轻稀土(LREE)相对富集, 重稀土(HREE)相对亏损的右倾特征, 且岩石相对富集大离子亲石元素Rb、K及高场强元素Th、U、Zr、Hf, 相对亏损大离子亲石元素Ba、Sr及高场强元素Nb、Ta、P、Ti。岩石成因类型判别图显示前哨林场黑云母二长花岗岩具A型花岗岩特征, 岩石Hf同位素及微量元素特征显示岩体岩浆来源于中—新元古代古老地壳的熔融, 且存在少许幔源物质及新增生地壳物质熔融的参与, 元素特征暗示岩石形成于额尔古纳地块与西伯利亚古陆碰撞后的伸展构造环境背景下。结合前人对额尔古纳地块早古生代花岗岩形成背景的研究, 认为额尔古纳地块北缘及东北缘早古生代花岗岩形成机制不同, 前者形成于额尔古纳地块与西伯利亚古陆及蒙古—图瓦地块碰撞、拼接后伸展背景下; 后者主要形成于额尔古纳与兴安地块碰撞伸展背景下。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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