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1.
东桐峪金矿是小秦岭金矿田主要的石英脉型金矿之一,其主矿脉Q8501的脉石英及其脉旁蚀变片麻岩中含有丰富的变质锆石。岩相学、CL图像特征表明,这些锆石呈半自形–它形,无紧闭振荡环带构造,常见固体包裹体和次生的流体包裹体。锆石具有陡直的重稀土富集配分模型,LREE/HREE比值很低为0.02~0.14,具显著的Ce正异常(δCe=5.6~96.3)和Eu负异常(δEu=0.04~0.77)。大部分锆石的Th/U比值较低,特别是第1组(Th/U=0.14~0.56,平均0.30);Nb/Ta比值很小(0.06~0.31),普通铅含量也很低。推测变质锆石是在石英脉形成过程中从脉侧蚀变片麻岩中捕获的。LA-ICP-MS锆石微区U-Pb定年分析表明,Q8501脉第1组锆石的207Pb/206Pb表观年龄为1776~1877 Ma,加权平均年龄为1810±17 Ma,可能代表了华北克拉通中部造山带与碰撞后伸展作用有关的热事件;第2组锆石207Pb/206Pb表观年龄为1899~1922 Ma,加权平均年龄为1910±11 Ma,记录了小秦岭地区相当于五台–中岳期的第二期区域变质事件。小秦岭含金石英脉的形成可能跨越了很长的地质年代,金(钼)矿化主要发生在中生代,而载体石英脉有些可能在古生代就形成了。  相似文献   

2.
本文报道了冀东青龙地区新太古代朱杖子群和单塔子群变质岩的锆石SHRIMP U-Pb定年结果。朱杖子群底部张家沟组砾岩中的TTG砾石、花岗岩砾石和基质的岩浆锆石207Pb/206Pb加权平均年龄分别为2515±9Ma(MSWD=1.9)、2510±10Ma(MSWD=1.6)和2512±7Ma(MSWD=1.0),朱杖子群底部张家沟组黑云斜长片麻岩碎屑锆石207Pb/206Pb加权平均年龄为2540±6Ma(MSWD=1.6),朱杖子群桲罗台组变质酸性火山岩岩浆锆石207Pb/206Pb加权平均年龄为2516±8Ma(MSWD=1.1),单塔子群鲁杖子组黑云变粒岩碎屑锆石207Pb/206Pb加权平均年龄为2504±7Ma(MSWD=1.8),另有一个数据点的207Pb/206Pb年龄为3.04Ga。根据本文定年结果和前人资料,获得主要结论如下:朱杖子群和单塔子群形成于新太古代晚期,很可能为岛弧环境的产物;朱杖子群与下伏单塔子群之间虽存在角度不整合关系,但时间间断不长,朱杖子群底部张家沟组砾岩不具有底砾岩性质;③绿片岩相—角闪岩相的朱杖子群和单塔子群与角闪岩相—麻粒岩相的遵化深变质绿岩带—三屯营—太平寨—迁安岩浆杂岩区变质程度差异很大,但形成时代相同,是后期构造作用把它们置于同一地壳平面。  相似文献   

3.
稀有金属花岗伟晶岩年代学是花岗伟晶岩型稀有金属矿床研究的重要内容。目前测年方法较多,但不同方法测试结果的对比研究亟待开展。我们选择吐格曼北花岗伟晶岩型锂铍矿床3条含矿伟晶岩开展锆石、锡石、铌钽铁矿及白云母四种矿物不同方法的测年对比研究。结果显示:1)ρ31白云母-锡石伟晶岩中锡石238U/206Pb-207Pb/206Pb谐和年龄为468±8.7Ma (MSWD=1.1,N=39)、白云母-钠长石-锂辉石伟晶岩中锆石206Pb/238U谐和年龄为458.7±2.3Ma (MSWD=7.2,N=16); 2)ρ38白云母-钠长石-锂辉石伟晶岩中锆石206Pb/238U谐和年龄为454.7±4.0Ma (MSWD=8.0,N=10)、白云母40Ar/39Ar坪年龄为350.2±1.6Ma (MSWD=4.7); 3)ρ87含铌钽铁矿-白云母-石英伟晶岩中铌钽铁矿206Pb/238U谐和年龄为464.1±2.7Ma (MSWD=5.2,N=39)。可以看出,铌钽铁矿与锡石的U-Pb年龄在误差范围内一致,可能代表花岗伟晶岩岩浆结晶的年龄; 2件样品的蜕晶化锆石U-Pb年龄也可以对比,可能代表岩浆锆石蜕晶化后经流体交代作用及重结晶作用导致U-Pb同位素系统重置的时间。白云母Ar-Ar年龄明显晚于铌钽铁矿、锡石和锆石的U-Pb年龄,鉴于ρ38白云母-钠长石-锂辉石伟晶岩脉中白云母与锂辉石发生了强烈变形与蚀变,认为变形的白云母记录的是叠加变形与热液蚀变的时间。由此推断吐格曼北锂铍花岗伟晶岩形成于468～454Ma,这意味着阿尔金山地区中-晚奥陶世可能存在持续时间较长的稀有金属成矿事件。基于花岗伟晶岩矿物成因与吐格曼北锂铍花岗伟晶岩不同方法测年对比结果,可以得出以下结论:铌钽铁矿与锡石的U-Pb年龄可代表伟晶岩岩浆结晶的年龄,蜕晶化的锆石U-Pb年龄记录的是岩浆锆石蜕晶化后经流体交代作用及重结晶作用导致U-Pb同位素系统重置的时间,含钾矿物的40Ar/39Ar年龄能够约束伟晶岩的变形与蚀变年龄;多种定年方法的联合约束可以更好地限定稀有金属花岗伟晶岩的各个阶段成矿事件时间。  相似文献   

4.
通过对浙西南遂昌县玉岩古元古代花岗片麻岩锆石LA-ICP-MS U-Pb年代学研究,以探讨和揭示华夏地区基底的物质组成。玉岩花岗片麻岩锆石可分为两类:第一类锆石年龄相对年轻,其~(207)Pb/~(206)Pb年龄介于597~1917 Ma之间,结合稀土元素特征,表明为变质成因锆石,在锆石谐和图上,15个年轻锆石点整体上构成了一条不一致线,其上交点年龄为1904±19Ma,代表了片麻岩形成的变质时间,表明华夏地区存在古老的古元古代晚期岩浆岩-变质岩基底,下交点年龄为262±47Ma,可能记录了华夏地块晚二叠世―早三叠世构造-变质作用的响应。第二类锆石年龄相对较老,锆石~(207)Pb/~(206)Pb年龄介于2087~2523Ma之间,锆石发育核幔结构并有明显的振荡环带,较老的锆石年龄表明华夏地区可能存在太古宙末至2.5Ga的古老基底物质。  相似文献   

5.
本文报道了冀东青龙地区新太古代朱杖子群和单塔子群变质岩的锆石SHRIMP U-Pb定年结果。朱杖子群底部张家沟组砾岩中的TTG砾石、花岗岩砾石和基质的岩浆锆石207Pb/206Pb加权平均年龄分别为2515±9 Ma (MSWD=1.9)、2510±10 Ma (MSWD=1.6)和2512±7 Ma (MSWD=1.0),朱杖子群底部张家沟组黑云斜长片麻岩碎屑锆石207Pb/206Pb加权平均年龄为2540±6 Ma (MSWD=1.6),朱杖子群桲罗台组变质酸性火山岩岩浆锆石207Pb/206Pb加权平均年龄为2516±8 Ma (MSWD=1.1),单塔子群鲁杖子组黑云变粒岩碎屑锆石207Pb/206Pb加权平均年龄为2504±7 Ma (MSWD=1.8),另有一个数据点的207Pb/206Pb年龄为3.04 Ga。根据本文定年结果和前人资料,获得主要结论如下：朱杖子群和单塔子群形成于新太古代晚期,很可能为岛弧环境的产物; 朱杖子群与下伏单塔子群之间虽存在角度不整合关系,但时间间断不长,朱杖子群底部张家沟组砾岩不具有底砾岩性质;③绿片岩相—角闪岩相的朱杖子群和单塔子群与角闪岩相—麻粒岩相的遵化深变质绿岩带—三屯营—太平寨—迁安岩浆杂岩区变质程度差异很大,但形成时代相同,是后期构造作用把它们置于同一地壳平面。  相似文献   

6.
桐柏造山带中秦岭群中出露有志留纪麻粒岩,然而其原岩形成时代和变质年龄却没有得到有效的约束。本文对北桐柏秦岭群中长英质麻粒岩中锆石开展了详细的形貌学、阴极发光图像、微量元素以及U-Pb年代学研究。LA-ICP-MS锆石U-Pb定年结果表明继承碎屑锆石给出了2.7~0.55 Ga的年龄,岩浆锆石给出了478±7 Ma(MSWD=0.73)的206Pb/238U加权平均年龄,代表了桐柏长英质麻粒岩原岩的形成年龄。变质锆石区域获得了437±7 Ma(MSWD=1.3,n=10)的206Pb/238U加权平均年龄。结合锆石微量元素特征和前人研究结果表明437±7 Ma可能代表了前进变质阶段的年龄。而最外层的增生边给出了406±8 Ma(MSWD=0.72,n=4)的206Pb/238U加权平均年龄,代表了退变质年龄。我们认为在480 Ma时,商丹洋已开始向北俯冲,导致480 Ma左右的岩浆作用,由于持续的俯冲消减,在440~420 Ma时,洋中脊与弧交汇,发生洋脊俯冲导致志留纪麻粒岩相变质作用以及岩浆作用的发生。  相似文献   

7.
本文报道了安徽洪镇地区董岭群片麻岩中高精度的独居石SIMS U-Th-Pb定年结果,以~(207)Pb含量为基准对普通Pb进行校正后得到~(206)Pb/~(238)U的加权平均年龄为128.4±0.7 Ma(MSWD=1.6),~(208)Pb/~(232)Th年龄的加权平均值为128.6±0.4 Ma(MSWD=1.4)。作者认为独居石的SIMS U-Th-Pb年龄(128.4±0.7 Ma)代表了董岭群片麻岩的前进变质年龄。综合区域地质资料,提出董岭群片麻岩为新元古代沉积物在中生代经岩浆热动力接触变质的产物。这一发现不仅否定了前人提出的董岭群为前寒武纪区域变质地体的观点,而且否定了这一地区的"洪镇变质核杂岩",对进一步研究中国东部零星出露的中高级片麻岩的大地构造属性和构造演化具有借鉴意义。  相似文献   

8.
报道了华北克拉通大青山地区哈德门沟钾长伟晶岩脉的锆石SHRIMP U-Pb年龄和Hf同位素组成。钾长伟晶岩脉广泛分布,不定向切割早期地质体。部分钾长石具出溶结构,利用三元长石温度计获得其形成温度为750～800℃。锆石粒度粗大,大多呈等轴状,锆石的阴极发图像中部具板状环带或扇形结构,边部出现振荡环带。SHRIMP锆石U-Pb定年,数据点位于谐和线上,207Pb/206Pb年龄加权平均值为1841Ma±9Ma(MSWD=1.5)。锆石的εHf(t)和tDM1(Hf)分别为-10.4～-6.6和2498～2648Ma。结合其它资料,可得出如下结论:①大青山地区至少在1.84Ga已进入伸展体制;②钾长伟晶岩脉形成于高温条件;③钾长伟晶岩脉的物质来自该区早前寒武纪变质基底。  相似文献   

9.
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。  相似文献   

10.
云开地区前寒武纪变质基底主要是以片麻岩类为代表的高州杂岩和以浅变沉积岩类为代表的云开群,均不同程度受到了后期加里东期和印支期构造-岩浆事件的改造。对高州杂岩中1个变粒岩(YK1016)和1个黑云斜长片麻岩(YK1014-3)、云开群中1个黑云斜长片麻岩(YK1017-1)样品进行了锆石LA-ICP-MS U-Pb定年。样品YK1016中获得的不一致曲线上下交点年龄分别为(1 035±43)Ma和(437±30)Ma(n=16,MSWD=1.3),上交点年龄与10个谐和点207Pb/206Pb加权平均年龄(970±30)Ma(MSWD=0.22)一致,解释为其形成年龄。样品YK1014-3获得的206Pb/238 U表观年龄范围为949~2 395 Ma,主要集中在1 000~1 200 Ma,9个最年轻且谐和的分析点207Pb/206Pb加权平均年龄为(970±32)Ma(MSWD=0.53),对其最大沉积年龄进行了约束。样品YK1017-1获得的206Pb/238 U表观年龄范围为650~2 383 Ma,也主要集中在1 000~1 200 Ma,最年轻且谐和的碎屑锆石年龄将其时代约束在650 Ma。结合云开地区变质基底中已有的高精度年龄数据,认为高州杂岩形成时代为中元古代晚期—新元古代早期,云开群的形成时代为新元古代晚期。另外,研究结果及云开地区已有的数据表明,该区除出露Grenville期岩石外,新元古代变沉积岩中还存在大量Grenville期(900~1 350 Ma)碎屑锆石,部分晶形较好具岩浆起源,这一现象从云开地区一直延伸到华夏东部;但在华夏地块由南往北,Grenville期锆石呈减少趋势,新元古代锆石(820~860 Ma)逐渐增多。这些暗示华夏地块南缘存在一个由南东向北西推进的Grenvillian造山带,和(或)在华夏地块内部存在略晚于Grenville期的构造-岩浆事件。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

13.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

14.
Emilio Biagini 《GeoJournal》1998,44(2):163-165
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15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

16.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

17.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

19.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引：25，自引：2，他引：25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

20.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

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