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1.
小秦岭变质岩及脉体锆石SHRIMP U-Pb年龄及其地质意义 总被引：2，自引：0，他引：2
本文对小秦岭地区花岗伟晶岩、花岗片麻岩及含金石英脉中的锆石进行了SHRIMP U-Pb年龄测定。花岗伟晶岩中的锆石为岩浆锆石,其~(207)Pb/~(206)Pb平均年龄为1955±30Ma,MSWD=1.4;花岗片麻岩中的锆石复杂,其变质成因"幔"的~(207)pb/~(206)Pb平均年龄为2462±20Ma,MSWD=2.0,铅丢失不谐和直线的上交点年龄为2400～2600Ma;含金石英脉中的锆石为残余锆石,其~(207)Pb/~(206)Pb平均年龄为1995±86Ma,MSWD=0.092。这些年龄数据为小秦岭地区的构造演化提供了更精确的年龄依据,2400～2600Ma和1900～2000Ma分别代表了小秦岭地区第一期和第二期变质作用的年龄。含金石英脉形成于2000Ma之后,石英脉中没有热液锆石。 相似文献
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南辽河群盖县组的重新厘定:来自辽南地区黄花甸-苏子沟一带变质砂岩碎屑锆石U-Pb年代学证据 总被引：4，自引：2，他引：2
传统认为辽河群顶部的盖县组广泛分布于辽南地区。本文对岫岩县黄花甸-苏子沟一带的南辽河群盖县组变质长石石英砂岩和变质石英砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学研究。其中变质长石石英砂岩中碎屑锆石普遍发育核-边结构,核部具有清晰的振荡环带;变质石英砂岩中碎屑锆石基本无核-边结构,具有清晰或者略模糊的振荡环带。锆石微量元素分析结果显示,具有振荡环带锆石微区具有轻稀土元素(LREE)亏损、重稀土元素(HREE)相对富集的配分曲线特征,Ce正异常和Eu负异常明显,Th/U和Zr/Hf比值较高,表明其岩浆成因。变质长石石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于2506～1748Ma之间,且呈现～2178Ma和～1863Ma两个年龄主峰,表明主要物质来源为同时期花岗质岩石(条痕状花岗岩和斑状花岗岩);变质石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于3546～1950Ma之间,呈现～2149Ma年龄主峰值,表明主要物质来源为条痕状花岗岩,另有少量太古宙基底物质的加入。研究区变质长石石英砂岩～1.86Ga的年龄峰值与辽河群其它变沉积岩明显不同,表明沉积时代一定晚于～1.86Ga,即形成于辽河群古元古代变质作用之后。综合研究区盖县组变质长石石英砂岩与辽河群其它变沉积岩碎屑锆石U-Pb年龄的差异,我们建议将盖县组部分变沉积岩从辽河群中解体出来。 相似文献
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《地质科技情报》2017,(3)
河北省石湖金矿位于阜平幔枝构造核部中南段,其围岩主要是太古宇阜平群,是冀西目前已发现的唯一大型金矿。为研究石湖金矿的成矿时代,重点对含金石英脉中锆石进行了阴极发光分析和LA-ICP-MS U-Pb同位素测年。结果表明:锆石形态为自形-半自形,环带特征明显,Th/U比值大多大于0.1,为典型的岩浆锆石。锆石U-Pb年龄主要分为两组,其中一组~(207)Pb/~(206)Pb年龄主要位于(2 569±41)-(2 014±38)Ma之间,年龄数据在谐和图上基本位于一致曲线下方,显示放射成因铅明显有不同程度的丢失,其年龄数据与一致曲线的上交点年龄为(2 492±82)Ma,表示岩浆锆石的结晶年龄,可代表阜平群TTG片麻岩的结晶年龄;另一组~(206)Pb/~(238)U年龄为(136±4)Ma,结合含矿地质体之间的空间位置关系,综合表明石湖金矿主要成矿事件发生在(136±4)Ma之后。石英脉中没有热液锆石,锆石来自围岩。 相似文献
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北秦岭松树沟榴闪岩锆石U-Pb定年、矿物包裹体和Lu-Hf同位素特征及其地质意义 总被引：6，自引：5，他引：1
采用LA-ICP-MS锆石U-Pb定年法对松树沟榴闪岩中的锆石进行年代学分析,得到锆石残留核的206Pb/238U加权平均年龄为729±24Ma,对应的Th/U比值为0.70~1.01;变质锆石的206Pb/238U加权平均年龄为496±9.1Ma,对应的Th/U比值为0.02~0.11。通过激光拉曼探针在变质锆石里寻找到斜长石、单斜辉石、石榴石、石英、榍石、磷灰石等矿物包裹体,结合岩石具有的石榴石变斑晶和单斜辉石+斜长石嵌晶,推测变质锆石可能生长于岩石的高压麻粒岩相变质阶段,不排除早期存在榴辉岩相变质的可能性,所获~496Ma的变质时代记录了一期与陆壳深俯冲相关的区域地质事件。利用LA-MC-ICP-MS法测定了变质重结晶锆石的176Hf/177Hf=0.282560~0.282663;以t=730Ma计算出εHf(t)=+8.6~+12.2;Hf模式年龄为867±43Ma。锆石残留核年龄和变质重结晶锆石的t DM(Hf)数值,表明该榴闪岩的原岩应老于729Ma,原岩物质从亏损地幔分离的时间不晚于867±43Ma。结合前人研究成果,认为松树沟榴闪岩是早期侵位的岩石遭受早古生代高压-超高压区域变质作用的产物。 相似文献
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西秦岭造山带北缘古元古界变质杂岩中新识别出新元古代元龙花岗质片麻岩和新阳花岗质片麻岩。花岗质片麻岩中锆石Th/U比值较高,阴极发光图象显示锆石内部发育振荡环带,具岩浆成因特点。LA-ICP-MS锆石U-Pb同位素206Pb/238U加权平均年龄分别为914.7±7.6Ma(MSWD=4.8)、978.5±4.8Ma(MSWD=1.5)和935.5±3.1Ma(MSWD=1.3),表明花岗岩岩体形成于新元古代,反映了新元古代早期西秦岭北缘存在一次俯冲碰撞事件,与Rodinia超大陆的汇聚事件具有一致性。 相似文献
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山东半岛荆山群富铝片麻岩锆石U-Pb定年及其地质意义 总被引：12，自引：0，他引：12
荆山群富铝片麻岩广泛分布于山东半岛早前寒武纪变质基底之中。锆石阴极发光图像分析和U-Pb定年结果表明,荆山群富铝片麻岩中锆石成因比较复杂,可划分为3种类型:第一类为继承性(岩浆或碎屑)锆石,U-Pb定年结果显示该类锆石微区记录了~2 650 Ma和~2 100 Ma两组207Pb/206Pb年龄,这不仅表明研究区变质基底在中太古代末期和古元古代早期至少存在两期岩浆-热事件,同时,也说明荆山群原岩形成时代应晚于2 100 Ma;第二类为变质锆石,记录的207Pb/206Pb年龄集中在1 900~1 850 Ma之间,应代表荆山群富铝片麻岩峰期高压麻粒岩相变质时代;第三类亦为变质锆石,记录的207Pb/206Pb年龄集中在1 840~1 820 Ma之间,应代表荆山群富铝片麻岩峰后中低压麻粒岩相退变质时代。该项成果准确地限定了荆山群富铝片麻岩的原岩形成时代、峰期高压麻粒岩相变质时代和峰后中低压麻粒岩相退变质时代的年代学格架,对深入探讨华北克拉通东南缘高压麻粒岩的成因机制及其形成的动力学背景具有重要的科学意义。 相似文献
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冀东青龙地区新太古代朱杖子群和单塔子群形成时代:锆石SHRIMP U-Pb定年 总被引：12，自引：0，他引：12
本文报道了冀东青龙地区新太古代朱杖子群和单塔子群变质岩的锆石SHRIMP U-Pb定年结果。朱杖子群底部张家沟组砾岩中的TTG砾石、花岗岩砾石和基质的岩浆锆石207Pb/206Pb加权平均年龄分别为2515±9Ma(MSWD=1.9)、2510±10Ma(MSWD=1.6)和2512±7Ma(MSWD=1.0),朱杖子群底部张家沟组黑云斜长片麻岩碎屑锆石207Pb/206Pb加权平均年龄为2540±6Ma(MSWD=1.6),朱杖子群桲罗台组变质酸性火山岩岩浆锆石207Pb/206Pb加权平均年龄为2516±8Ma(MSWD=1.1),单塔子群鲁杖子组黑云变粒岩碎屑锆石207Pb/206Pb加权平均年龄为2504±7Ma(MSWD=1.8),另有一个数据点的207Pb/206Pb年龄为3.04Ga。根据本文定年结果和前人资料,获得主要结论如下:朱杖子群和单塔子群形成于新太古代晚期,很可能为岛弧环境的产物;朱杖子群与下伏单塔子群之间虽存在角度不整合关系,但时间间断不长,朱杖子群底部张家沟组砾岩不具有底砾岩性质;③绿片岩相—角闪岩相的朱杖子群和单塔子群与角闪岩相—麻粒岩相的遵化深变质绿岩带—三屯营—太平寨—迁安岩浆杂岩区变质程度差异很大,但形成时代相同,是后期构造作用把它们置于同一地壳平面。 相似文献
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四会岩体:一个潜在的含钼铜矿化岩体 总被引：1，自引：0，他引：1
四会岩体位于广东省四会市境内,主要由黑云母花岗岩、白云母花岗岩和钾长花岗岩组成。在全岩主、微量元素分析的基础上,对采自该岩体的黑云母花岗岩进行了微区原位LA-ICP-MS锆石微量元素分析和U-Pb定年。CL图像显示这些锆石自形,具有明显的岩浆生长环带,个别有暗色的核。获得了20个有效的206Pb/238U年龄,年龄范围从161~1069Ma。锆石微量元素分析显示这些锆石样品具有高的Th、U和REE含量,明显富集HREE,其Th/U比值普遍高于0.4,表明这些锆石属于岩浆成因。其中年龄最新的一组共10个点比较集中,206Pb/238Pb加权平均年龄为166.6±2.9Ma,代表岩体的成岩时代;其余较老的10个年龄数据比较分散,代表捕获锆石信息。同时这些锆石的Ce(Ⅳ)/Ce(Ⅲ)值为146~681,平均为441,表明形成该岩体的岩浆具有较高的氧逸度;Eu/Eu*值为0.41~0.60,明显高于一般不含矿的岩体(0.4)。将四会岩体锆石Ce(Ⅳ)/Ce(Ⅲ)和Eu/Eu*与邻区粤北大宝山含矿斑岩中锆石(Ce(Ⅳ)/Ce(Ⅲ)=13.9~414;Eu/Eu*=0.14~0.70)进行对比,发现两个参数都比较一致。综合分析表明,四会岩体可能是一个潜在的具有铜钼矿成矿潜力的含矿岩体。 相似文献
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通过对浙西南遂昌县玉岩古元古代花岗片麻岩锆石LA-ICP-MS U-Pb年代学研究,以探讨和揭示华夏地区基底的物质组成。玉岩花岗片麻岩锆石可分为两类:第一类锆石年龄相对年轻,其~(207)Pb/~(206)Pb年龄介于597~1917 Ma之间,结合稀土元素特征,表明为变质成因锆石,在锆石谐和图上,15个年轻锆石点整体上构成了一条不一致线,其上交点年龄为1904±19Ma,代表了片麻岩形成的变质时间,表明华夏地区存在古老的古元古代晚期岩浆岩-变质岩基底,下交点年龄为262±47Ma,可能记录了华夏地块晚二叠世―早三叠世构造-变质作用的响应。第二类锆石年龄相对较老,锆石~(207)Pb/~(206)Pb年龄介于2087~2523Ma之间,锆石发育核幔结构并有明显的振荡环带,较老的锆石年龄表明华夏地区可能存在太古宙末至2.5Ga的古老基底物质。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献