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1.
笔者等以出露于红石山—百合山蛇绿混杂岩带南侧的英云闪长岩体为研究对象,通过野外地质调查和岩石学、地球化学、锆石LA-ICP-MS U-Pb年代学研究,探讨其成因、构造环境及红石山洋俯冲消亡过程。岩石地球化学研究表明,红石山南英云闪长岩体富硅(SiO2=63.95%~66.22%)、高铝(Al2O3=15.31%~16.61%)、富钠(Na2O=3.73%~4.33%)、低钾(K2O=1.00%~1.85%),相对高锶(Sr=246.0×10-6~417.0×10-6)、低钇(Y=8.83×10-6~11.80×10-6),富集Rb、Sr等大离子亲石元素和LREE,亏损Nb、Ta、Ti、P等高场强元素,HREE相对亏损,无明显Eu异常。岩石学和岩石地球化学特征表明,为俯冲洋壳脱水熔融的产物。锆石LA-ICP-MS U-Pb测年表明,红石山南英云闪长岩体的形成年龄为306.9~309.9 Ma,...  相似文献   

2.
巴颜喀拉-松潘甘孜造山带三叠纪花岗岩是研究青藏高原中部古特提斯造山作用过程与地壳生长演化机制的重要探针。本次研究对巴颜喀拉中部的花岗质岩体进行了详细的岩石学、锆石U-Pb年代学和全岩地球化学研究,探讨其岩石成因和动力学背景。锆石U-Pb年代学研究表明,本次研究的花岗质岩体形成于209~217 Ma,是晚三叠世岩浆活动的产物。岩石地球化学分析揭示,岩体由高Sr/Y值和低Sr/Y值花岗岩类组成。其中,高Sr/Y值岩体具有中等K2O(2.13%~3.75%)、较高的Sr(373×10–6~521×10–6)含量和Sr/Y值(47.5~69.4),较低的Yb(0.42×10–6~0.62×10–6)、Y(6.79×10–6~7.99×10–6)、Cr(5.86×10–6~13.0×10–6)和Ni(1.91×10–6~6.63×10–6)含量, La/Yb...  相似文献   

3.
车路沟金矿是北祁连山发现的首例与斑岩有关的金矿床,矿体产于加里东晚期侵入的中酸性斑岩体及其与围岩接触带内。为了查明含矿斑岩体侵位时代、岩石成因和源区性质,本文以车路沟一带含矿斑岩体作为研究对象,对其开展了岩石地球化学、LA-ICP-MS锆石U-Pb同位素定年和Hf同位素特征研究。该岩体主要由花岗闪长斑岩、石英闪长斑岩、英云闪长斑岩组成,对花岗闪长斑岩、英云闪长斑岩进行了LA-ICP-MS锆石U-Pb同位素定年,分别获得锆石206Pb/238U加权平均年龄为438.6±3.8Ma和433.0±3.8Ma,指示岩浆侵位时代为早志留世晚期。岩石Si O2含量为61.4%~68.6%,Al2O3含量为15.0%~16.7%,MgO含量为0.36%~2.95%,σ值介于1.20~2.03之间,A/CNK值为1.0~1.1之间,属钙碱性系列准铝质花岗岩类;具有弱负铕异常-正铕异常(δEu=0.90~1.18),高Sr(319×10-6~549×10-6  相似文献   

4.
西藏岗讲斑岩铜钼矿床位于冈底斯斑岩铜矿带尼木斑岩铜矿田中。该区中-酸性岩浆活动较为发育,形成以黑云母二长花岗斑岩为主的含矿斑岩体。为限定冈底斯斑岩铜矿带岗讲铜钼矿床含矿斑岩体的形成时代及成因背景,本次研究对成矿黑云母二长花岗斑岩进行了LA-ICP-MS锆石U-Pb定年和地球化学研究。锆石U-Pb年代学分析揭示,岗讲黑云母二长花岗斑岩形成于中新世(14.47±0.19 Ma)。岩石地球化学研究表明,岗讲黑云母二长花岗斑岩的w(SiO2)为69.12%~72.62%,w(Al2O3)为13.31%~15.57%、K2O/Na2O为0.76~1.66。属于钾玄岩系列-高钾钙碱性系列,为过铝质花岗岩。岩石的ΣREE为83.19×10-6~154.28×10-6,轻、重稀土分异明显,(LREE/HREE)=3.57~14.73,(La/Yb)N值为31.4~39.5,δEu为0.83~1.29,具有较弱的负Eu异常;稀土元...  相似文献   

5.
白垩纪碰撞后花岗岩是研究大别造山带碰撞后伸展垮塌的重要载体,西大别南缘的桥店花岗斑岩脉为约束大别山碰撞后构造机制转化提供了新的约束信息。SIMS和LA-ICP-MS锆石定年结果表明,桥店花岗斑岩脉侵位年龄约为129 Ma,并具有富集的锆石Hf同位素组成(εHf(t)=-24.5-14.7)和古元古代二阶段模式年龄(2.41.9 Ga)。矿物组成上,花岗斑岩脉以富含粗粒的长石斑晶为主要特征。它们具有变化的SiO2含量(63.07%73.22%)和A/CNK值(0.871.73),同时具有高的K2O(4.51%5.47%)、低的MgO (0.42%1.82%)含量,属于高钾钙碱性花岗岩类。岩石的轻稀土元素相对重稀土元素富集,具有Eu的负异常(Eu/Eu*=0.770.92);同时富集Rb、Ba和Pb,而亏损Nb、Ta和Ti。相较于典型埃达克质岩石,桥店花岗斑岩的Sr含量(78×10-6724 ×10 -6)变化较大,Y(11.8×10-614.8×10-6)和Yb(1.09×10-61.37×10-6)含量相对较高,对应的Sr/Y(6.755.5)和(La/Yb)N(29.634.2)比值较低。以上地球化学特征,结合古元古代的残留锆石和二阶段铪模式年龄,共同反映出桥店花岗斑岩是区内古元古代下地壳物质在中-低压力条件下部分熔融的产物。与区域上碰撞后岩浆岩的对比研究表明,桥店花岗斑岩的侵位指示了西大别地壳在约129 Ma已经开始减薄,西大别白垩纪加厚下地壳的拆沉及构造机制转换的时间可能在约130 Ma前后。  相似文献   

6.
宋家冲矿床是长江中下游成矿带九瑞矿集区西南部新发现的矽卡岩型Au、Cu-Mo矿床。矿区内与成矿关系密切的岩体为花岗闪长斑岩。LA-ICP-MS锆石U-Pb测年结果显示,该岩体形成于早白垩世早期((142.8±0.6)Ma)。主量元素组成上,宋家冲岩体属于准铝质岩石(A/CNK=0.801.03),具低镁(ω(MgO)=1.29%2.58%)、富铝(ω(Al2O3)=15.52%16.88%)、高碱(富钠)(K2O/Na2O=0.571.04)特征。微量元素方面,表现为富集Rb、Ba、Th和La等大离子亲石元素(LILE),相对亏损Nb、Ta和Zr等高场强元素(HFSE),ω(Sr)较高(>618×10-6)、ω(Y)较低(<17.1×10-6)、Sr/Y值大(3961)、轻重稀土分馏强烈(ω(Yb)<1.45×10-6;(La/Yb)N>30)等特点,类似于埃达克岩的地球化学特征。全岩Sr-Nd和锆石Hf同位素组成变化范围相对较小:(87Sr/86Sr)i为0.705 80.706 7,εNd(t)为-6.4-4.9,εHr(t)为-10.1-5.1。结合区域地质研究成果认为:宋家冲岩体可能形成于陆内挤压-伸展的过渡环境下,为富集岩石圈地慢部分熔融的产物。  相似文献   

7.
珲春小西南岔地区白垩纪花岗岩主要有英云闪长岩和花岗闪长岩两种类型。英云闪长岩属于中钾钙碱性系列(Na2O/K2O=1.99~2.76),具有高Al2O3(15.46%~17.13%)、Sr(559×10-6~731×10-6)、Sr/Y(40~78)、La/Yb(16~21),低Y(9×10-6~14×10-6)、Yb(0.8×10-6~1.3×10-6)的特征,与埃达克质岩石地球化学特征类似。花岗闪长岩为高钾钙碱性系列,Na2O/K2O=1.01~1.56,w(Sr)=312×10-6~410×10-6w(Yb)=1.23×10-6~2.13×10-6、Sr/Y=13~32,属正常的高钾钙碱性花岗岩。两类花岗岩的源区均为玄武质下地壳物质,英云闪长质岩浆形成压力较高(> 1.0 GPa),深度大于33 km,花岗闪长质岩浆形成压力相对较低(0.8~1.0 GPa),岩浆来源深度为26~33 km。  相似文献   

8.
云南中甸红牛—红山矿床位于义敦岛弧南端,该区域主要发育印支期与燕山晚期两期成矿作用。本次研究对红牛—红山斑岩—矽卡岩型铜矿床与成矿有关的隐伏花岗斑岩锆石进行U-Pb年代学、元素地球化学以及同位素地球化学特征研究,结果表明:红牛—红山矿床与成矿相关的隐伏花岗斑岩属于I型花岗岩,其w(K2O)为2.05%~7.32%;可见轻微负Eu异常,Eu/Eu*变化范围为0.56~0.89;Mg#值较低,为20.04~47.08,暗示加厚下地壳来源;(La/Yb)N为28.65~103.24,呈现出强烈的轻重稀土分馏模式;Sr含量较高且变化范围较大,为131×10-6~715×10-6,具埃达克岩的特征。花岗斑岩锆石Th/U比值为0.32~1.21,表明其为岩浆锆石;锆石平均协和年龄为76.7 Ma,与成矿年龄一致,表明其形成于晚白垩世;锆石重稀土元素显著富集,δEu=0.38~0.99,结晶温度为600.3~813.5℃,平均值为681.5℃,氧逸度平均值△FMQ=1....  相似文献   

9.
西藏次玛班硕地区含矿斑岩体具备斑岩型铜矿成矿有利地质条件,结合本地区野外工作的新认识和新发现,展开该地区成岩成矿地质背景及成因等问题研究.对次玛班硕地区由秋米斑岩体开展了详细的锆石U-Pb测年及岩石地球化学研究,结果表明:花岗闪长斑岩LA-ICP-MS锆石U-Pb年龄为15.2±0.8 Ma~15.2±0.7 Ma,即形成时代为中新世.花岗闪长斑岩具有高硅(SiO2=65.08%~66.85%)、高钾(K2O=3.85%~4.58%)、富碱(K2O+Na2O=7.87%~8.90%)、贫镁(MgO=1.51%~1.84%)、准铝质(A/CNK=0.88~0.95)地球化学特征.稀土元素配分模式右倾,具有弱的铕负异常,(La/Yb)N=36.60~47.43,富集强不相容元素(Rb、Th、U、K)和亏损高场强元素(Nb、Ta、Ce、P、Ti);特殊地,岩石具有典型埃达克岩地球化学特征,即:高Sr(674×10-6~876×10-6)、低Yb(0.560×10-6~0.757×10-6)、低Y(7.97×10-6~9.98×10-6)、高Sr/Y比(73.84~109.98).全岩Sr-Nd同位素组成中(87Sr/86Sr)i=0.707 878、εNd(t)=-8.26,Nd二阶段模式年龄T2DM=1 503 Ma,说明其岩浆源于基性下地壳部分熔融.结合区域的火成岩,认为岩石形成于印度大陆与亚洲大陆后碰撞伸展构造背景.   相似文献   

10.
为揭示华北克拉通北缘凉城基性岩墙的形成时代、岩石成因、构造背景及对罗迪尼亚超大陆重建的意义,本研究借助激光烧蚀多接收器等离子质谱(LA-MC-ICP-MS)锆石U-Pb定年、Hf同位素及全岩地球化学研究手段,对凉城桃花沟岩墙开展了系统研究。研究结果显示,凉城桃花沟岩墙为新元古代早期(903±15 Ma)基性岩浆活动的产物,归属拉斑岩石系列,具有较高的TFeO(12.78%~16.30%)及TiO2(2.59%~3.31%)含量、较低的MgO(2.87%~3.83%)、Cr(32.7×10-6~42.0×10-6)、Ni(11.6×10-6~14.5×10-6)含量及Mg#值(29~38),富集轻稀土元素(LREE)、Rb、Pb、Zr及Hf元素,亏损Ba、Sr、Nb、Ta、Ti及Eu(Eu/Eu*=0.74~0.83)元素。锆石原位εHf(t)范围为2.4~13.4,单阶段Hf模式年龄(tDM1  相似文献   

11.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

15.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

16.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

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The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite and quartz veins. The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock, alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite, volcanic tuff, phosphatic rock and chert breccia. The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon.  相似文献   

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