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1.
多彩铜铅锌矿床位于"三江"多金属成矿带北段青海省南部的治多县,是目前该地区新发现的唯一一个与古特提斯火山作用有关的大型矿床。矿体产于晚三叠世巴塘群火山岩地层中,直接赋矿围岩为英安质凝灰岩。矿区内主要发育硅化、绢云母化、黄铁矿化、绿泥石化、重晶石化、白云石化、方解石化等蚀变,矿化类型以块状及浸染状铜铅锌矿化和纹层状及星点状铜矿化为主,其次为细脉状铜铅锌矿化等。蚀变矿化在空间上具有明显分带性,以白云石-重晶石固结壳为界,下盘依次出现硅化-重晶石化-块状及细脉状矿化带、硅化-黄铁矿化-稠密浸染状矿化带、黄铁矿化-硅化-绢云母化-稀疏浸染状矿化带、硅化-弱绿泥石化带、绿泥石化带。上盘则多为成矿后中低温蚀变组合,如弱硅化-弱绢云母化-绿泥石化等。成矿演化上,矿床经历了3期主要成矿作用:火山沉积-气液矿化期、海底喷流热液矿化期及表生期。矿床地质特征、蚀变矿化分带及成矿演化等的综合分析表明,多彩铜铅锌矿床与日本黑矿及同一构造带的"三江"中段川西呷村VMS矿床极为相似,属于火山岩容矿的块状硫化物矿床。  相似文献   

2.
通过牟定郝家河砂岩型铜矿床两类典型矿化的围岩蚀变类型、空间分布、蚀变矿物组合特征的综合分析,识别出该矿床存在成岩期与改造期两期热液蚀变。成岩期热液蚀变分布于浅紫交互带浅色砂岩一侧,呈现大范围面状硅化、碳酸盐化、黄铁矿化,并具蚀变分带:全浅色砂岩中的强硅化、黄铁矿化亚带;浅紫过渡砂岩中的强碳酸盐化、绢云母化、绿泥石化、弱硅化亚带,并具辉铜矿-斑铜矿-黄铜矿-黄铁矿的金属矿物分带。改造期热液蚀变主要分布于断裂、节理旁侧,表现为带状、网脉状的硅化、碳酸盐化。以1580 m中段实测剖面为研究对象,采集各蚀变亚带的代表样品,以紫色砂岩为原岩,进行主量元素、微量元素及稀土元素的组分迁入、迁出计算,结果显示各亚带组分的迁入、迁出特征与镜下观察的蚀变矿物组合吻合。分析表明,蚀变矿物组合与组分迁移特征还间接指示了不同亚带的形成条件:成岩期紫色砂岩(围岩)呈氧化-碱性条件,浅色砂岩呈还原-酸性条件,浅紫过渡矿化带则处于氧化还原-酸碱转化面上;改造期构造热液属还原-中偏碱性的中温构造流体。在此基础上,探讨了两期成矿流体分别形成层状矿体及脉状富矿体的机理,为深化研究该类矿床的"矿源-构造-流体耦合成矿"机制提供了重要证据。  相似文献   

3.
本文对毕力赫金矿床Ⅱ矿带围岩蚀变及其与金矿化关系进行了研究.矿床主要蚀变类型为硅化、钾化、黄铁矿化、绢云母化、电气石化、绿泥石化、高岭土化、碳酸盐化,其中硅化、绢云母化、黄铁矿化与金矿化关系密切;蚀变分带明显,由地表向下,依次为青磐岩化带→绢英岩化带→钾质蚀变带,绢英岩化带与金矿化关系最为密切.  相似文献   

4.
曾淑明  韩润生  张艳  刘飞  王明志  吴子卓  田映天 《地质论评》2023,69(1):2023010001-2023010001
翁孔坝铜多金属矿床是近年来滇西南地区新发现的矿床之一。尽管前人在区域内开展了大量的研究,但对该矿床却鲜有涉及,因其热液蚀变特征及其地球化学找矿标志不明,制约了该矿床的深部找矿勘查工作。笔者等在矿化—蚀变矿物组合研究的基础上,对矿区内典型纵向剖面中各蚀变带的样品开展了元素地球化学定量分析,采用质量平衡计算方法和热液蚀变指数定量分析手段,研究矿化蚀变带中元素迁移特征。结果表明,热液蚀变具有明显的垂向分带特征,可划分为强方解石化带、绿泥石化带和弱硅化带。其中,强方解石化与铜矿化密切相关,方解石化和绿泥石化与铅锌矿化密切相关;从玄武质安山岩(围岩)至强方解石化带,热液蚀变指数(AI)整体呈递增趋势(74.85%75.85%76.29%78.98%),指示蚀变强度逐渐增强。CaO的迁入率(4.03%0.66%15.20%)、Cu的迁入率(154×10-6124×10-6642×10-6)、TFe2O3+MgO的迁入率(-1.34%4.48%2.48%)和Pb的迁入率(-961×10-6795×10-64×10-6)整体上均呈正相关,反映出强方解石化和绿泥石化热液蚀变是该矿床的重要找矿标志。  相似文献   

5.
位于特提斯成矿域西段塞尔维亚Bor成矿带内的Mali Krivelj铜矿床是一大型斑岩型矿床。为揭示该矿床热液蚀变作用过程及元素迁移规律,文章对新鲜安山岩及不同蚀变带典型样品进行了微量元素分析及元素迁移质量平衡计算。研究结果表明,绢英岩化带及绿泥石-绢云母化带显示类似元素迁移规律,REE、Sr、Ba、Zr、Th、U、Ti、Co、Ni等元素显示一定程度迁出,而Rb、Cs等元素显示一定程度迁入,绿泥石-绢云母化带发育大量磁铁矿,而绢英岩化带则大量出现石英+绢云母+黄铁矿组合,这表明随着流体的持续演化,流体的还原性逐渐增强。青磐岩化带蚀变较弱,其元素迁移程度较低。研究区Cu与Cr、Rb、Ti/Sr、Rb/Ba、Cr/Zn比值等具较好的正相关性,Cu与REE、Ba、Zn、Mn、Sr等元素具有一定的负相关性,表明该矿床全岩元素迁移规律在一定程度上也能作为地球化学勘查指标为寻找斑岩矿化中心提供依据。  相似文献   

6.
红豆山铜矿床是南澜沧江带新发现的矿床之一。通过野外地质工作和系统构造—|蚀变岩相填图,发现该矿床蚀变类型主要以钾长石化、硅化、绿泥石化、绿帘石化为主,其次为碳酸盐化、绢云母化、黄铁矿化等,且在空间上呈现一定规律,各蚀变带具有明显的叠加现象。依据区内岩石蚀变矿物组合等特点,自断裂带→上盘围岩,共出现4个典型蚀变带,依次为碎裂岩化带→长英岩化—碳酸盐化—绢云母化带→硅化—绿泥石化—绿帘石化带→弱长英岩化安山岩带。矿(化)体主要分布在长英岩化、碳酸盐化、绢云母化带和硅化、绿泥石化、绿帘石化带。由斑岩脉中心至边缘发育钾化带→硅化带→青磐岩化带→绢云母化带,斑岩旁侧围岩中发育放射状石英—方解石—黄铜矿脉。  相似文献   

7.
安徽铜陵桂花冲斑岩铜矿围岩蚀变与矿化作用   总被引:1,自引:0,他引:1  
桂花冲铜矿为安徽铜陵地区新发现的斑岩型铜矿,斑岩体为准铝质高钾钙碱性的花岗闪长斑岩。围岩蚀变与矿化作用是斑岩型矿床成矿过程研究的一项重要内容,对蚀变带岩石开展元素地球化学成分的迁移研究,是分析热液交代蚀变过程的基础。桂花冲铜矿区内围岩蚀变作用比较强烈,蚀变类型主要有钾化、绢云母化、硅化、绿泥石化和碳酸盐化等。蚀变分带比较明显,由内向外依次为钾化带、绢英岩化带和青磐岩化带,矿体主要产于绢英岩化带内。矿化蚀变自早至晚划分为钾长石、石英-绢云母、石英多金属硫化物和碳酸盐4个阶段。蚀变带物质组分迁移结果表明,在蚀变过程中,岩石的主量元素除TiO2、MnO、MgO外,其他元素迁移量发生了明显改变;微量元素除Sr和Cu外,迁移量变化较小,稀土元素在矿化强的部位亏损,在矿化弱的地带富集。岩体及蚀变带岩石稀土元素球粒陨石标准化配分模式一致,说明岩体与蚀变岩石经历了相同来源流体的交代蚀变,是岩浆流体连续作用的结果。  相似文献   

8.
红海VMS铜锌矿床位于新疆东天山大南湖-头苏泉岛弧带的卡拉塔格地区,矿床上部发育似层状块状硫化物矿体,下部为不整合的脉状-网脉状矿体,块状矿体上盘火山岩盖层中也发育少量铜矿化。本文在前人工作基础上,根据矿物交代次序、脉体穿插关系和矿物共生组合类型,精细划分了矿床的蚀变分带和成矿期次。矿床(含盖层)从浅到深依次发育绿泥石-钠长石-绢云母-碳酸盐化、绿帘石-绿泥石-钠长石-绢云母-碳酸盐化、石英-绢云母-黄铁矿化、块状硫化物矿体、绿泥石-黄铁矿±绢云母化和绿泥石-石英-绢云母化。红海矿床成矿过程可分为VMS成矿期、后期热液叠加期和表生期,其中VMS成矿期可细分为黄铁矿阶段、黄铜矿-闪锌矿阶段和重晶石阶段,后期热液叠加期可细分为钠长石化阶段、绿泥石-绿帘石阶段和石英-碳酸盐阶段。主矿化期及蚀变特征与典型VMS矿床类似,但同时还表现出许多海底交代作用的特征。后期热液在矿体上盘火山岩中所产生的绿帘石化、绿泥石化和绿帘石-石英-黄铜矿-斑铜矿脉、石英-碳酸盐脉等蚀变和矿化,与斑岩矿化系统的青磐岩化类似,表明红海矿床后期可能受到斑岩系统的叠加,矿区具有斑岩铜矿床的找矿潜力。  相似文献   

9.
中咀铜矿属典型中高温热液充填交代成因。通过对中咀铜矿矿床的蚀变特征、矿化及其分布特征进行分析表明,矿床经历早期黑云母化、斜长石化,中期电气石化、硅化到晚期绢云母化和绿泥石化的蚀变演变。矿区蚀变带分布明显,可分四个热液蚀变带,矿化蚀变带及其矿体分布均受韧性剪切带的控制,矿区矿化作用与热液蚀变关系密切,矿化均出现在热液蚀变带中。  相似文献   

10.
【研究目的】黄沙坪铜锡多金属矿床是湘南地区岩浆热液成矿系统的典型矿床之一。为了深化研究该矿床成岩成矿机制、高效指导深部找矿勘查,需要揭示与隐伏花岗斑岩有关的多金属矿化-蚀变分带规律,构建深部矿化-蚀变空间分带模式。【研究方法】应用热液矿床的大比例尺蚀变岩相定位找矿预测方法,开展矿区内-136 m、-176 m、-256 m中段典型穿脉剖面的矿化蚀变测量和矿物岩石地球化学研究,剖析了矿化-蚀变的强弱变化、矿物共生组合及其空间分带特征,探讨了成矿元素、元素组合及其元素比值变化规律。【研究结果】构建了矿化-蚀变空间分带模式:从花岗斑岩体(内带)→接触带→围岩(外带),依次为钨钼(黄铁)矿化-硅化-绢云母化花岗斑岩带(Ⅰ)→磁铁(钨锡)矿化石榴石矽卡岩带(Ⅱ-1)→钨钼-磁黄铁矿化石榴石矽卡岩带(Ⅱ-2)→铅锌矿化结晶灰岩带(Ⅲ)→强方解石化灰岩带(Ⅳ)的分带规律,各带对应的主要矿物组合为:石英+(黄铁矿+绢云母)→磁铁矿+透辉石+硅灰石+绿帘石+绿泥石+(白钨矿+锡石+黄铁矿+石榴石)→白钨矿+辉钼矿+磁黄铁矿+(锡石+黄铜矿+黄铁矿+闪锌矿+方铅矿)+石榴石+符山石+透辉石+角闪石+萤石+...  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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