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1.
鲁颖淮  李文博  赖勇 《岩石学报》2009,25(10):2615-2620
内蒙古中部镶黄旗哈达庙金矿床位于华北板块北缘的中亚造山带中东段,矿体受控于花岗斑岩体与围岩接触带,为斑岩型金矿床.运用激光剥蚀等离子体质谱仪(LA-ICP-MS)测定了含矿花岗斑岩中单颗粒锆石U-Pb年龄,获得15个测试点的加权平均年龄为271.8±3.3Ma(MSWD=2.3,n=15),表明花岗斑岩侵位年龄(或成矿年龄)为早二叠世.结合前人的岩相学、微量元素地球化学和同位素地球化学研究结果,认为哈达庙金矿区花岗斑岩可能形成于古生代末-三叠纪初的华北板块与西伯利亚古板块之间的大陆碰撞背景,俯冲板片部分熔融或者深熔作用形成的岩浆上侵为金矿的形成提供了成矿物质.  相似文献   

2.
摘要:阿鲁科尔沁地区位于兴蒙造山带东段,中生代岩浆岩分布广泛。对该地区晚侏罗世侵入岩进行了年代学、岩石地球化学及其成矿潜力研究。阿鲁科尔沁地区晚侏罗世侵入岩主要由石英二长闪长岩、石英二长岩、黑云母花岗闪长岩组成,主岩体黑云母花岗闪长岩的LA ICP MS锆石U Pb加权平均年龄为(14379±084) Ma(MSWD=33),属晚侏罗世,在区域Mo Au Cu成矿峰期内。岩体属准铝质高钾钙碱性-钾玄岩系列,相对富碱,稀土元素总量较低,轻重稀土分馏明显,具有中等Eu负异常,富集强不相容元素Rb、Th、U、LREE,亏损高场强元素P、Ti、Y及HREE,相对亏损Nb和Ta,相对亏损大离子亲石元素Ba,属I型花岗岩。岩体主体来源于壳源基性岩组分的部分熔融,形成于晚侏罗世的后碰撞伸展环境,为有利成矿构造演化阶段。K/Rb和Rb/Sr比值较小,DI值较大,SI值较小,Fe2O3/FeO比值较大,属中等-强演化中等分异程度的氧化型或磁铁矿系列花岗岩,地球化学含矿性参数显示其Cu、Au、Mo金属成矿潜力依次降低,与研究区已发现的矿化特征相一致。  相似文献   

3.
云南维西县阿南多塘石英斑岩是西南“三江”成矿带中段的含(锑)矿斑岩体。为深入分析该岩体岩浆来源及构造环境,开展斑岩主量元素、微量元素和稀土元素地球化学特征研究,结果表明:云南维西阿南多塘石英斑岩属高硅富钾过铝质钙碱性系列。轻稀土相对富集,稀土元素球粒陨石标准化模式图较陡向右倾斜,δCe无异常,δEu中等负亏损。富集不相容元素Cs、Rb和产热元素Th、U、K,高场强元素Zr、Hf等也相对富集,亏损Nb、Sr和Ti。经对比分析认为,该岩体是“三江”成矿带中段江达-德钦-维西陆缘弧演化后期陆陆碰撞形成的新生代富钾石英斑岩,岩浆主要来自上地壳沉积岩,具有碰撞后火山岩的典型特征。  相似文献   

4.
西秦岭早子沟金矿是与岩浆活动有关的特大型金矿床,矿区中酸性侵入岩集中发育,主要有闪长玢岩、黑云石英闪长玢岩、花岗斑岩、石英闪长岩4种岩石类型。岩石微量元素均表现出富集大离子亲石元素Rb、K,亏损高场强元素Nb、Ta、P、Ti的特征。稀土元素总量整体上黑云石英闪长玢岩>闪长玢岩>石英闪长岩,闪长玢岩、黑云母石英闪长玢岩、花岗斑岩具有弱-中等的负铕异常(δEu=0.60~0.89),深部石英闪长岩以不具Eu异常(δEu=0.96~1.07)、“Nb-Ta谷”较深明显区别于浅部脉岩。石英闪长岩锆石U-Pb年龄为230 Ma,晚于浅部脉岩10~20 Ma,与蚀变矿物绢云母年龄基本一致,推测金成矿可能始于230 Ma,主成矿期为230~211 Ma,深部石英闪长岩为早子沟金矿的成矿地质体。  相似文献   

5.
毕力赫大型斑岩型金矿位于华北克拉通北缘白乃庙-哈达庙铜-钼-金矿化集中区。矿区侵入岩包括以花岗闪长斑岩为主的含金次火山侵入杂岩体和地表广泛出露的钾长花岗斑岩。次火山杂岩体SiO2含量61.5%~71.4%,属亚碱性钙碱性系列,岩石REE配分具LREE富集型,弱Eu负异常,相对富集大离子亲石元素(LILEs)、亏损高场强元素(HFSEs)和Ba,具壳幔混源特征,除亏损Ba之外总体类似陆缘弧花岗岩。LA-ICP-MS锆石U-Pb测年获得含金次火山侵入杂岩体和钾长花岗斑岩成岩年龄分别为283.8±4.2Ma~279.9±6.8Ma和264.2Ma,为早、中二叠世,与野外地质体穿插关系吻合。哈达庙-白乃庙地区晚古生代中-早二叠世的大规模构造-岩浆-成矿作用,与白云鄂博-西拉木伦缝合带两侧大陆对接碰撞的时间一致,受同碰撞构造环境制约。  相似文献   

6.
西藏革吉县尕尔穷铜金矿矽卡岩特征及成因意义   总被引:1,自引:0,他引:1  
通过对矽卡岩岩石学特征、矿物学特征研究,发现矽卡岩主要产于大理岩和石英闪长岩、花岗斑岩接触带上,垂向上多有大理岩-硅化角岩-矽卡岩化大理岩-硅灰石矽卡岩-透辉石矽卡岩-石榴子石矽卡岩-石英闪长岩的分带特征。矽卡岩岩石地球化学特征、稀土元素和微量元素特征显示矽卡岩主要为钙矽卡岩,具有弱Eu负异常和轻稀土富集等特征;同时具有富集Rb、Th、Cs、U等大离子亲石元素和亏损Hf、Ti、Y等高场强元素特征。矽卡岩地球化学特征受大理岩和石英闪长岩、花岗斑岩的控制和影响,显示其与大理岩、石英闪长岩和花岗斑岩成因上有密切关系。通过对班公湖-怒江成矿带成矿背景和时空关系的讨论,指示了尕尔穷矿床成因是与岩浆热液有关的接触交代型矿床。  相似文献   

7.
白山钼矿赋矿岩体为花岗斑岩,其主量、微量及稀土元素地球化学特征研究表明,岩体属过铝质高钾钙碱性系列,并相对富集大离子亲石元素(Rb,Th,Sr等),亏损高场强元素(Nb,Ce,Zr等),以及具有LREE富集的右倾稀土元素分布模式。根据矿物稀土元素作为示踪剂提供的信息表明,含钼矿物的石英脉稀土元素组成和分布模式与壳幔同熔型花岗岩有众多相似之处,推测该成矿物质来源与花岗岩岩浆有关,来自同一源区,形成于碰撞后演化阶段向板内转化的构造环境,并具相同的成岩方式与成岩成矿同期。  相似文献   

8.
内蒙古哈达庙金矿床位于天山—内蒙海西晚期褶皱带镶黄旗复向斜内。金矿化主要分布在燕山期花岗斑岩与石英闪长岩接触带以及邻近的火山角砾岩脉群内,矿体主要由含金石英脉和含金石英-电气石脉组成,金矿石品位较高。围岩蚀变自含金矿脉向外分别为硅化、电气石化、钾化、绿帘石化和碳酸盐化,金矿化同硅化和电气石化有关。硫、碳、氧和氢同位素数据以及黄铁矿痕量元素分析表明:同斑岩体有关的金矿化和在火山角砾岩脉群中产出的金矿化是同源不周演化阶段的产物,高f_(o2)和低pH值的物理化学环境是金沉淀富集的重要控制因素,矿床成因类型属斑岩型中温热液矿床。  相似文献   

9.
内蒙古哈达庙金矿床地质特征及矿床成因探讨   总被引:1,自引:0,他引:1  
内蒙古哈达庙金矿床位于天山一内蒙海西晚期褶皱带镶黄旗复向斜内。金矿化主要分布在燕山期花岗斑岩与石英闪长岩接触带以及邻近的火山角砾岩脉群内,矿体主要由含金石英脉和含金石英一电气石脉组成,金矿石品位较高。围岩蚀变自含金矿脉向外分别为硅化、电气石化、钾化、绿帘石化和碳酸盐化,金矿化同硅化和电气石化有关。硫、碳、氧和氢同位素数据以及黄铁矿痕量元素分析表明:同斑岩体有关的金矿化和在火山角砾岩脉群中产出的金矿化是同源不周演化阶段的产物,高fO2和低pH值的物理化学环境是金沉淀富集的重要控制因素,矿床成因类型属斑岩型中温热液矿床。  相似文献   

10.
白乃庙金矿位于中亚造山带南缘白乃庙岛弧区域,是华北地台北缘中段金成矿远景区的重要组成部分.本文通过白乃庙金矿床流体包裹体和C-H-O-S稳定同位素的系统工作,揭示其成矿物质来源、成矿流体性质以及矿床成因.流体包裹体测试均一温度(126.5~283.4℃)和盐度(0.88% ~7.59%NaCl equiv)显示成矿流体...  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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