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1.
通过对分布于勉略构造带中段三岔子西侧中堂沟地区的火山岩进行详实的野外地质剖面调查,发现其为一套绿片岩相浅变质火山岩,岩石组合以变安山岩为主,含有少量的变玄武岩和变英安岩,主体为钙碱性系列。岩石地球化学研究表明3类岩石均具有轻稀土富集型稀土配分曲线,并显示弱的Eu负异常;微量元素方面,岩石普遍富集大离子亲石元素Cs、Rb、Ba,亏损高场强元素Nb、Ta,相对亏损P、Ti,不活动微量元素Zr、Hf、Tb、Y等既无明显的相对亏损也无显著的相对富集。在La-La/Nb、Nb-Nb/Th和La/Yb-Sc/Ni等环境判别图解中,变玄武岩和变安山岩样品点均落在岛弧火山岩范围内,并结合其岩石组合特征指示该套火山岩应形成于大陆边缘弧(活动陆缘)环境。其中变玄武岩和变安山岩岩浆起源于楔形地幔的部分熔融,且有陆壳物质的参与;变英安岩的形成则与壳源物质的部分熔融有关。 相似文献
2.
内蒙古苏尼特右旗温都尔庙地区早石炭世火山岩的发现及其构造意义 总被引：2，自引：1，他引：1
内蒙古苏尼特右旗温都尔庙地区发现一套以片理化安山岩和蚀变流纹岩为主的火山岩,其中测得安山岩的锆石SHRIMP年龄为333±4Ma。岩石可分为玄武岩-安山岩类和英安岩-流纹岩类,其中玄武岩-安山岩类火山岩Si O2含量47.40%~62.75%,Mg#值介于17.2~25.6,属于拉斑系列;稀土总量较低,总体趋势近水平,轻重稀土分馏不明显,Eu异常不明显(δEu=1.22~1.46);岩石经历了强片理化和蚀变作用,大离子亲石元素(LILEs)容易发生活动运移,变化较大,但总体呈富集状态,Ta、Nb和Ti明显亏损,类似岛弧火山岩,其原始岩浆应起源于受俯冲板片脱水熔融交代的地幔楔。英安岩-流纹岩类火山岩Si O2含量63.50%~79.80%,相对富集大离子亲石元素,亏损高场强元素(如Nb、Ta、Ti)及Sr、P元素,类似活动大陆边缘火山岩,其原始岩浆应源于地壳物质的部分熔融。综上所述,笔者认为早石炭世期间,华北板块北缘处于古亚洲洋的俯冲作用下,古亚洲洋的闭合时间应晚于早石炭世。 相似文献
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南秦岭城口火山岩锆石LA-ICP-MS U-Pb定年和地球化学研究 总被引：3，自引：0，他引：3
南秦岭大巴山城口断裂带出露一套玄武安山岩、安山岩组合,火山岩锆石LA-ICP-MS U-Pb定年测试结果为716±4Ma,表明其为新元古代岩浆产物;岩石地球化学研究表明火山岩富集轻稀土元素,原始地幔标准化微量元素蛛网图显示以富集大离子亲石元素Cs、Ba、Th、U及高场强元素分异为特征,Nb、Ta强烈亏损以及低的Ti(Ti O_20.85%)含量,与典型的岛弧火山岩相似;微量元素La/Nb、Th/Yb及Hf/Ta比值特征也显示岛弧岩浆属性,相对高的Zr/Y、Ta/Yb和低的Zr/Nb比值区别于大洋岛弧火山岩,具有明显的大陆亲缘性,表明城口火山岩形成于陆缘岛弧环境。综合已有的地质、地球化学及同位素年代学研究表明新元古代晚期扬子板块北缘及南秦岭地区为一活动陆缘岩浆杂岩弧,暗示中国华南板块很可能位于Rodinia超大陆的边缘部位。 相似文献
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鲁西邹平盆地中生代火山岩的演化:对地幔源区的约束 总被引：2，自引：1，他引：1
邹平盆地中生代火山岩可分为三个亚组：中、下亚组具有相似的岩石组合,岩性主要为玄武岩-粗面玄武岩-玄武质粗面安山岩-粗面安山岩;上亚组岩性主要为粗面安山岩。火山岩由早期基性向晚期中偏碱性方向演化,与正常岩浆房酸度增高的岩浆分异趋势相同。具有Rb、Ba、Sr等大离子亲石元素（LILE）和轻稀土元素（LREE）富集,Nb、Ta、Ti等高场强元素（HFSE）相对亏损,类似于岛弧火山岩的地球化学特征。Nb／La、Hf／Sm比值随MgO的降低而升高或基本不变,说明高场强元素亏损是岩浆的原始特征。各亚组火山岩相似的稀土配分模式和微量元素蛛网图,表明它们具有共同的岩浆源区和密切的成因联系,分离结晶起了关键性作用。La／Nb、La／Ta、Ba／Nb比值较高,说明成岩物质可能主要来自岩石圈地幔。拆沉的大陆中、下地壳部分熔融形成的熔体与古生代岩石圈地幔（亏损的地幔橄榄岩）的相互作用是岩石圈地幔富集的重要方式,随之该富集地幔在陆内岩石圈伸展和区域热异常的双重作用下发生减压部分熔融而形成具有岛弧特征的邹平盆地火山岩。 相似文献
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对西天山特克斯西北乌孙山中部地区出露的火山岩进行了地球化学研究,结果表明玄武岩、安山岩均为拉斑质火山岩,LREE较富集[(La/Yb)N介于3.44~11.36之间],具有弱的Eu负异常(δEu=0.79~1.13),安山岩与流纹岩明显富集强不相容元素(如Cs、Rb、Ba、Th、U)和LREE。玄武岩与中酸性岩样品具有轻微的差异,但所有样品具有较明显的Nb、Ta、Ti负异常,并且除了活动性较强的元素(Cs、Rb、Ba)外,其余微量元素均接近于下地壳的含量,(Th/Nb)N介于2.02~8.12之间,(Nb/La)N介于0.40~0.45之间,远远小于1,La/Ba值低(0.01~0.07),Ba/Nb值高(90~410);Zr/Nb值平均为16.48,最为接近原始地幔(15.71)的比值;而Ta/Nb、Hf/Ta、Th/Yb值平均为0.10、3.77、0.64,较为接近上地壳(0.10、3.50、0.48)的比值,Zr含量大于90×10-6,Zr/Y值在4左右,显示了板内玄武岩的特征。结合区域上地质特征,认为该地区在石炭纪时碰撞结束进入碰撞后伸展阶段,局部具有裂谷化特征。样品的Nb、Ta、Ti负异常应为地壳混染引起,火山岩的形成环境为碰撞后伸展的构造环境。 相似文献
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为了了解大别山北缘构造属性,对定远组地层组成、形成时代及地球化学特征进行调查与研究.野外调查表明,定远组主要由一套变火山岩及云母片岩、云母石英片岩、浅粒岩、板岩等组成,其中变火山岩包括变玄武岩与变流纹质火山岩,并构成典型的双峰式火山岩建造;此外,还含有早古生代构造地层单位.运用LA-ICP-MS对酸性火山岩锆石进行U-Pb定年,获得725.7±1.4 Ma、736.6±5.4 Ma的年龄,形成时代为新元古代,不是前人认为的早古生代.变玄武岩分为低Ti（TiO2=1.19%）和高Ti（TiO2平均含量为3.11%）两种类型.低Ti玄武岩稀土总量较低（低于N-MORB）,岩浆来自亏损的地幔源区.高Ti玄武岩又可以分为两种类型,一类富集Nb、Ta等元素,不相容元素的比值接近大陆裂谷玄武岩;另一种类型亏损Nb、Ta、Th、U等元素,岩浆可能来源于被下地壳或蚀变大洋地壳改造的地幔,其Th/Ta为1.6,与大陆裂谷玄武岩相当.总之,变玄武岩地球化学特征具有很大差别,是地幔源区不均一的反映.变酸性火山岩富集大离子亲石元素Rb、Ba、Th、U、K,亏损Nb、Ta、P、Ti等元素,锆石Hf同位素分析显示主体εHf（t）值为-3.0~-10,二阶段Hf模式年龄TDM2（Hf）为1 630~2 258 Ma,揭示其来源于古老地壳的部分熔融.定远组新元古代双峰式火山岩形成于大陆裂谷环境,并非岛弧构造背景.定远组双峰式火山岩及广泛分布的同时代岩浆岩,揭示了扬子陆块北缘在新元古代（800~611 Ma）时期一次重要的大陆边缘裂解-岩浆事件,是Rodinia超级古大陆裂解作用深部地球动力学的地表响应. 相似文献
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藏北双湖地区海西期和印支期火山岩均以夹层形式产于海相沉积岩层中.海西期火山岩高度富集轻稀土元素和明显富集Rb、Ba、K等大离子亲石元素与Nb、Ta、Ti、P等高场强元素,无Nb、Ta、Ti亏损等特点,表明其具有大陆裂谷碱性玄武岩和洋岛碱性玄武岩的特征;以其不相容元素比值,相当于Gough岛EMⅠ OIB型洋岛玄武岩,其构造环境判别图进一步印证了海西期火山岩形成于洋岛碱性玄武岩环境.印支期火山岩贫轻稀土元素和Rb、Ba、K等大离子亲石元素,相对贫Nb、Ta、Ti、P等高场强元素;但Nb、Ta并不亏损以及稀土配分曲线较平缓等特点,表明其具有大陆裂谷拉斑玄武岩特征;其微量元素、稀土元素的丰度及曲线特征可以与确定环境的红海88GTV岩样、东非大裂谷B10C岩样的丰度及曲线特征相类比,且构造环境判别图也共同印证了印支期火山岩形成于类似红海-东非裂谷型的大陆裂谷,初始洋盆的环境. 相似文献
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澜沧江构造带中南段小定西组火山岩形成时代的厘定及其构造意义 总被引：2，自引：0，他引：2
三叠纪忙怀组、小定西组火山岩是澜沧江构造带中南段火山岩带的重要组成部分,是澜沧江古特提斯缝合带构造演化的产物。本文报道了小定西组巨厚玄武岩中安山岩和流纹岩夹层的岩石学、地球化学及锆石LA-ICP-MS年代学及Lu-Hf同位素特征。流纹岩锆石LA-ICP-MS U-Pb定年结果显示小定西组火山岩形成于230Ma。安山岩为高Al2O3的高钾钙碱性岩类,其较强的Nb、Sr和Ti负异常、较弱的Eu负异常、较低的Mg#、(La/Yb)N比值和Cr、Ni含量等特征与小定西组高铝玄武岩极为相似,说明安山岩岩浆与玄武岩岩浆来源相同或相似,是交代地幔物质部分熔融形成的玄武岩浆熔离分异的产物。流纹岩的过铝质特征,强烈Ba、Nb、Ta、Sr、P、Eu和Ti的负异常,与芒怀组流纹岩和临沧花岗岩极为相似,Nb/Ta、Th/Ce和Th/U比值与大陆地壳一致,以及εHf(t)值为-11.6~+9.6,峰值分布于-6.0~+2.0之间,对应的地壳模式年龄(tDM2)为658~1990Ma,大部分集中在1100~1600Ma范围内,反映其岩浆来源于中上地壳物质部分熔融的产物,并加入少量幔源组分的混合岩浆。小定西组玄武岩夹层中的安山岩和流纹岩都具有Rb、Ba、Th、U富集和Nb、Ta和Ti亏损,在微量元素构造环境判别图解上分布于陆缘弧或同碰撞岩浆岩区的特征。结合该区早三叠世地层缺失、晚三叠世磨拉石建造不整合覆盖在下伏地层之上,以及高压变质带的存在等分析认为澜沧江构造带中南段火山岩带中生代火山岩形成于同碰撞环境。在保山地块与印支地块碰撞过程中,交代地幔楔物质部分熔融形成的基性岩浆在上升过程中诱发地壳物质部分熔融形成酸性岩浆,下部基性和上部酸性两个岩浆房的岩浆间歇式喷发,形成下部以酸性火山岩为主(芒怀组),上部以基性火山岩为主(小定西组)的"双峰式"中三叠世火山岩带。 相似文献
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小兴安岭红彦地区发育一套早石炭世火山岩.这套火山岩由玄武岩、安山岩、英安岩、流纹岩及凝灰岩组成.岩石地球化学特征研究表明,该区早石炭世火山岩属于典型的钙碱系列岩石,并具有富钾特点,相对富集轻稀土元素(LREE/HREE=4.19～ 13.83)和大离子亲石元素(Rb、Ba、Th、U),相对亏损高场强元素(Nb、Ta、Ti),具有活动大陆边缘型火山岩的特点.认为红彦地区早石炭世火山岩起源于富集的岩石圈地幔的部分熔融,岩浆在演化过程中以结晶分异作用为主,伴有少量的地壳混染作用,即AFC过程.结合区域构造认为红彦地区早石炭世火山岩形成于碰撞前的俯冲环境,可能与额尔古纳-兴安地块与松嫩地块的碰撞拼合密切相关. 相似文献
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西藏改则县托和平错地区展金组中发育一套早—中二叠世以玄武岩类为主、玄武安山岩次之、安山岩少量的海相火山岩组合。该火山岩中玄武岩、玄武安山岩的SiO2含量为44.43%～54.87%,TiO2含量多在4%以上,K2O+Na2O平均为4.57%,玄武岩类富K,玄武安山岩富Na。区内火山岩富集K、Ba、Th、Ta、Ce、P、Zr、Sm、Ti、Cr,亏损Rb、Nb、Hf、Sc,Y/Nb在0.322～0.499之间。综合常量元素和微量元素特征,可将该火山岩归入碱性玄武岩系列。区内火山岩从基性到中性稀土元素总量基本没有变化,REE平均为402.31×10-6,LREE/HREE为8.17～12.69,为轻稀土强烈富集型,δEu为0.93～1.04,平均为0.99,无Eu异常,玄武岩的Th/Ta值多数大于1.6。火山岩的地质特征和地球化学特征表明,本区火山岩产出的大地构造环境为冈瓦纳大陆北缘裂谷环境。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床. 相似文献