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安徽月山石英闪长岩氧同位素分馏、Rb-Sr等时线定年与矿物蚀变之间的关系 总被引：7，自引：3，他引：7
受热液蚀变影响的侵入岩能否给出合理的矿物Rb-Sr等时线年龄是同位素年代学研究的一个重要课题。对月山岩体中的一个石英闪长岩样品进行了研究,对蚀变程度不同的矿物进行了氧同位素分析以及Rb-Sr等时线定年。各未蚀变矿物与石英构成的矿物对氧同位素表观温度的大小为:石英-角闪石对(470±15℃)>石英-黑云母对(340±10℃)>石英-斜长石对(265±20℃),表明了岩石在冷却过程中的氧同位素退化平衡。与此相应,3个未蚀变矿物(黑云母,角闪石,斜长石)的Rb-Sr等时线年龄为137.6±1.2Ma(MSWD=0.07),等时线的线性非常好,且与前人得到的Ar-Ar年龄在误差范围内一致。而石英-蚀变黑云母对的氧同位素表观温度(310±10℃)和石英-蚀变钭长石对的表观温度(325±25℃)与相应石英-未蚀变矿物对的相比,发生了显著改变,表明这两种矿物的氧同位素体系在蚀变过程中受到了扰动。但是未蚀变和蚀变共6个矿物的Rb-Sr等时线年龄为136.81±0.77Ma(MSWD=0.81),此等时线的线性也很好,且年龄与未蚀变矿物的在误差范围内一致。由于蚀变的影响,蚀变黑云母和斜长石的Rb、Sr含量和Sr同位素比值都发生了变化,但是蚀变矿物的~(87)Rb/~(86)Sr和~(87)Sr/~(86)Sr比值沿着等时线移动,因此等时线年龄不变,指示了蚀变时相当于全岩成分的内部流体与矿物之间的同位素交换。这表明受内部流体影响使花岗岩发生低温热液蚀变时,即使氧同位素体系受到扰动,Rb-Sr等时线仍可以有地质意义。 相似文献
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应用云母Rb Sr等时线法对大别山高级变质岩的后期改造历史进行了初步的探讨。采用重液变温技术将云母按比重的区别 ,分成若干组分 ,然后用常规的Rb Sr方法测定。应用这种技术对大别山黄土岭太古代麻粒岩相岩石中的黑云母和产于超高压变质带内的石马含石榴石片麻岩的白云母进行了Rb Sr等时线年龄测定。黄土岭太古代麻粒岩相片麻岩中的黑云母 全岩Rb Sr等时线年龄为 12 7± 9Ma ,与该区片麻岩中的角闪石的K Ar和Ar Ar年龄 ,及燕山期花岗岩的Rb Sr年龄一致 ,说明这一太古代下地壳岩石受到了燕山期深熔 岩浆事件的影响 ;大别山东南部石马含石榴石片麻岩 (榴辉岩相 )中的白云母Rb Sr等时线年龄为 191± 10Ma ,反映了印支 早燕山期区域性低级变质事件的时代。研究表明 ,大别山区的不同构造单元中产出的不同类型的高级变质岩自中生代以来有不同的后期演化历史。 相似文献
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本文对广西大厂矿田拉么矿区内出露的酸性侵入岩和矿石进行了精细的年代学研究,分别获得龙箱盖含斑黑云母花岗岩锆石原位SHRIMP UPb和全岩RbSr等时线年龄为94±4Ma（95%可信度）和98.6±1.9Ma（95%可信度）,矽卡岩成矿期锌铜矿石中石英矿物RbSr等时线年龄为98.6±6Ma（95%可信度）。上述测定结果表明,拉么锌铜多金属矿床的成矿年龄与相关岩体的成岩年龄接近,均形成于早白垩世晚期。 相似文献
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北大别主簿源花岗岩和片麻岩矿物的 总被引：10，自引：2，他引：10
对大别造山带北部主簿源中生代花岗岩侵入体及其围岩片麻岩进行了矿物氧同位素分析，同时对同一样品进行了矿物 Rb- Sr内部等时线定年。结果表明，花岗岩和片麻岩矿物的氧同位素温度大小顺序为：角闪石 >磁铁矿 >榍石 >石英 >黑云母 >长石，遵循缓慢冷却条件下扩散控制的氧同位素交换封闭顺序，指示这些岩石没有受到后期热液蚀变的扰动。根据黑云母-长石-磷灰石-全岩内部 Rb- Sr等时线测定，花岗岩的年龄为 (118± 3) Ma，代表了岩浆侵位冷却年龄；片麻岩的年龄为 (122± 1) Ma，代表了片麻岩受大面积燕山期岩浆侵位热烘烤达到高温同位素平衡后的冷却年龄。因此，矿物之间的氧同位素平衡与否 ,能够对矿物 Rb- Sr体系封闭后平衡状态的保存性以及矿物内部等时线定年的有效性予直接制约。 相似文献
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胶东金矿集中区金矿成矿年代学研究 总被引：9，自引：0，他引：9
对不同研究者采用蚀变矿物Rb Sr、K Ar和Ar Ar法 ,流体包裹体Rb Sr等时线法 ,石英Ar Ar法和矿石矿物 (黄铁矿 )Rb Sr等时线法等多种同位素定年方法获得的胶东金矿集中区金矿成矿年龄数据进行了方法适用性研究和应用选择 ,筛选后的成矿年龄集中于 15 3 8～ 80 6Ma。综合考虑与金矿床有密切时空关系的花岗岩类侵入体及脉岩的K Ar、Ar Ar及U Pb (SHRIMP)年龄 ,确认胶东金矿集中区金矿主成矿期年龄为 (115± 10 )Ma ,金 银 多金属矿成矿期年龄为 (85± 5 )Ma ,分别为中生代早白垩世晚期 (K21)和晚白垩世早期 (K12 )。 相似文献
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华北地块南缘中段中生代花岗质岩石的40Ar-39Ar年代学研究 总被引：6，自引：4，他引：2
对华北地块南缘4个中生代花岗质岩体中的角闪石和黑云母进行了40Ar-39Ar定年研究。结果表明,陕西黑山村岩体黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 3Ma,河南马家湾岩体细粒黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 2Ma,河南洛宁南八百坡岩体黑云母二长花岗岩中角闪石的40Ar-39Ar坪年龄为128. 3±0. 3Ma,山西蚕坊岩体花岗闪长岩中角闪石的40Ar-39Ar坪年龄为129. 2±0. 2Ma。上述结果显示华北地块南缘中生代的岩浆活动主要发生在早白垩世。该期岩浆的产生应与中国东部早白垩世的伸展环境相联系。 相似文献
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对大别造山带双河超高压榴辉岩和片麻岩Sm-Nd和Rb-Sr等时线矿物进行了O同位素地质测温。尽管Sm-Nd等时线给出一致的三叠纪年龄(213~238 Ma)，同一样品Rb-Sr等时线却给出侏罗纪年龄(171~174 Ma)。片麻岩、榴辉岩和榴闪岩矿物对O同位素测温得到600~720℃和420~550℃两组温度，分别对应于约225±5 Ma榴辉岩相变质和约175±5 Ma角闪岩相退变质条件下停止同位素扩散交换的温度。同一样品三叠纪Sm-Nd等时线年龄的保存、侏罗纪Rb-Sr等时线年龄的出现以及有规律的O同位素温度，表明在角闪岩相退变质过程中，Sr和O在含水矿物（如黑云母和角闪石）中的扩散速率在手标本尺度上比石榴石Nd和多硅白云母Sr的扩散速率快。 相似文献
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赣北香炉山白钨矿床的同位素年代学研究及其地质意义 总被引：22，自引：0，他引：22
赣南钨矿闻名世界,但赣北—皖南也存在钨的矿集区,香炉山就是其中之一。该矿床属矽卡岩型层状白钨矿床,与赣南钨矿明显不同。本文通过对矿区内与成矿作用关系密切的花岗岩、白钨矿及其共生的石英矿物的年代学研究,分别获得黑云母花岗岩全岩RbSr等时线年龄为126.2±2.6Ma（95%可信度）、白钨矿SmNd等时线年龄和石英矿物RbSr等时线年龄为121±11Ma（95%可信度）和128±3Ma（95%可信度）。上述测定结果表明,其成矿时代与区内花岗岩岩浆侵位所发生的时间有明显的耦合关系,与区域上同时代形成的斑岩型锡矿（如岩背）及铌钽矿相似,均属燕山晚期岩浆活动的产物。 相似文献
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吉林中部呼兰群同位素年代学及其地质意义 总被引：7，自引：2，他引：7
呼兰群地层位于吉林省中部,包括黄莺屯组、小三个顶子组与北岔屯组,是一套中低级变质的变质岩系,其Rb-Sr全岩等时线年龄为(524±16)Ma和(357±23)Ma。呼兰群中部含有奥陶纪小型腹足类化石。黄莺屯组下段黑云母片麻岩和上段白云母片岩中变质矿物黑云母、白云母的40Ar39Ar计时年龄分别为(223 6±0 8)Ma和(229 2±4 6)Ma。呼兰群的40Ar39Ar计时年龄代表其变质年龄,变质作用是由古亚洲蒙古洋构造域中生代造山事件所引起。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献