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1.
对湖南中生代邓阜仙岩体进行了LA-ICP-MS锆石U-Pb定年和岩石学、岩石地球化学分析。获得斑状黑云母花岗岩的锆石U-Pb年龄为225.1±1.2Ma,表明其形成于晚三叠世,结合已发表的岩体年龄资料,邓阜仙岩体是侵位于印支期(222.9~225.7Ma)和燕山期(151.1~159Ma)的复式岩体。邓阜仙岩体印支期、燕山期花岗岩均具有高的SiO_2含量、高的A/CNK值,含过铝质白云母、堇青石等矿物。富集大离子亲石元素Rb、Th、U,明显亏损Nb、Ba、Sr、Ti,稀土元素配分模式为右倾,轻稀土元素富集,Eu亏损相对明显。邓阜仙岩体具低的ε_(Nd)(t)值,~(176)Hf/~(177)Hf值小于球粒陨石的值。综上认为,邓阜仙岩体印支期、燕山期为S型花岗岩,源区分别为古元古代地壳贫粘土质岩石、富粘土质岩石部分熔融。研究区印支期、燕山期花岗岩均形成于伸展构造体制下,印支期花岗岩形成于印支运动碰撞后的伸展环境,燕山期花岗岩则在太平洋板块俯冲消减作用下形成。  相似文献   

2.
湘南王仙岭岩体由主体电气石黑云母花岗岩和侵入其内部的黑云母二长花岗岩组成,LA-MC-ICPMS锆石U-Pb定年显示电气石黑云母花岗岩形成于印支期(235.0±1.3Ma),黑云母二长花岗岩形成于燕山期(155.9±1.0Ma),表明该岩体是两期岩浆活动的产物。这两期岩石均为高钾钙碱性系列,A/CNK值为1.07~1.66,属过铝-强过铝质花岗岩类。稀土元素显示LREE富集,HREE亏损,Eu负异常明显(0.01~0.38)的特征。早期电气石黑云母花岗岩和晚期黑云母二长花岗岩的εHf(t)值分别为-7.92~+4.61和-10.66~-5.35;两阶段Hf模式年龄(tDM2)分别为1758~967Ma和1875~1538Ma。两期花岗岩均来自于古中元古代地壳物质重熔,其中早期电气石黑云母花岗岩在侵位上升过程中捕获了部分幔源老锆石,成岩过程中有少量地幔物质参与,且其源区具有高εHf(t)值的特点。综合前人研究成果,本文认为华南中生代印支期和燕山期均有钨锡矿化作用,印支期花岗质岩浆形成于碰撞挤压作用间隙伸展环境,而燕山期花岗质岩浆可能形成于大陆边缘弧后伸展环境。  相似文献   

3.
诸广山复式花岗岩基位于湘、赣、粤三省交界处,是南岭花岗岩的重要组成部分,由南体和北体组成,出露面积大于5000 km2,形成于加里东期、印支期、燕山期3个时代。通过对诸广山北体3期花岗岩锆石SHRIMP U-Pb定年,结果表明,加里东期花岗闪长岩锆石SHRIMP U-Pb年龄为(414.5±4.5)Ma(n=13,MSWD=0.52)、(417.3±4.8)Ma(n=12,MSWD=0.84),形成于晚志留世末。印支期黑云母二长花岗岩锆石SHRIMP U-Pb年龄(207.5±2.7)Ma(n=10,MSWD=1.6),形成于晚三叠世末。燕山期二云母二长花岗岩锆石SHRIMP U-Pb年龄(148.2±1.7)Ma(n=13,MSWD=0.93),形成于晚侏罗世。该成果为南岭地区构造-岩浆演化及成矿作用研究,提供了重要的花岗岩年代学依据。  相似文献   

4.
丫江桥岩体是湘东地区重要的成矿花岗岩,为精确厘定丫江桥岩体侵位时代、查明岩石成因,本文对丫江桥岩体中粗粒和中细粒黑云母二长花岗岩进行了LA-ICP-MS锆石U-Pb定年、全岩地球化学和原位锆石Lu-Hf同位素分析。获得LA-ICP-MS锆石U-Pb年龄为213.0±1.2Ma(n=12,MSWD=0.67)和212.1±1.2Ma(n=14,MSWD=0.09);岩石SiO_2含量为70.39%~72.88%和73.19%~74.85%;K_2O+Na_2O值为6.94%~7.95%和7.58%~7.96%;K_2O/Na_2O比值为1.25~1.70和1.45~1.58,A/CNK比值为1.05~1.07和1.07~1.09。稀土元素配分模式右倾,轻、重稀土分馏明显,(La/Yb)N值为13.76~24.52和7.12~11.01;负Eu异常,δEu值为0.34~0.61和0.26~0.33。富集Rb、K、Pb等大离子亲石元素,亏损Ba、Sr、Eu和高场强元素Nb、Ta、Ti等。锆石ε_(Hf)(t)值为-7.01~-0.90和-6.38~+6.85,二阶段Hf模式年龄(t_(DM2))为13.1~16.9Ga和12.7~16.6Ga。上述结果表明黑云母二长花岗岩为印支晚期岩浆活动产物,属弱过铝质花岗岩,岩浆主要来源于中元古界地壳物质重熔,可能有少量地幔物质参与。结合前人研究成果认为,黑云母二长花岗岩形成于后碰撞伸展的构造背景下,地壳减薄和压力降低以及地幔物质上涌的共同作用,导致地壳部分熔融形成花岗质岩浆,岩浆侵位冷却结晶,形成花岗岩体。  相似文献   

5.
沈莽庭  周延  张晓东  武彬 《地质论评》2013,59(2):369-381
选取福建虎岗地区灌洋和增坑二个岩体进行LA-MC-ICP-MS锆石U-Pb测年.增坑细粒二长花岗岩岩体单颗粒锆石U-Pb年龄为145.4±18.2~151.4±7.9 Ma,加权平均值为147.98±0.86 Ma(可信度95%,MSWD=0.62).灌洋中细粒黑云母二长花岗岩岩体单颗粒锆石年龄为141.2±4.1 ~ 145.5±1.9Ma,加权平均值为143.0±1.1Ma(可信度95%,MSWD=0.41).二岩体形成于挤压碰撞的构造环境,微量元素含量表明,岩浆分异作用较强,酸性程度较高,n(A12O3) >n(CaO) +n(Na2O) +n(K2O),且有较高的Rb/Sr和Rb/Nb比值,低含量的Ni、Cr含量和右倾型的稀土元素模式,表明岩体岩浆起源于大陆地壳中沉积的源岩,属于铝过饱和S型花岗岩.增坑和灌洋岩体形成年代都为晚侏罗世(燕山中晚期),且为铁铜多金属矿成矿提供了物质基础.  相似文献   

6.
燕山期花岗岩是亚婆绿岩体重要组成部分,以往的研究主要通过全岩地球化学来约束其成因和岩浆来源,缺乏对岩体锆石的岩相学、微量元素地球化学研究。本文对亚婆绿岩体二长花岗岩开展锆石U-Pb年代学及微量元素和Hf同位素研究,约束其成岩时代,探讨岩体锆石成因及岩浆源区特征。锆石U-Pb定年显示亚婆绿岩体二长花岗岩侵位年龄为153.6±1.2Ma,属燕山早期岩浆活动的产物;其中锆石发育典型的振荡环带,具有明显的Ce正异常和Eu负异常,属岩浆锆石,形成于陆壳环境。结合亚婆绿岩体二长花岗岩的Lu-Hf同位素特征,认为其为壳源岩石重熔的产物,岩浆物质源于下地壳的改造、再循环。  相似文献   

7.
湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。  相似文献   

8.
湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。  相似文献   

9.
永福岩体位于永梅晚古生代拗陷带中部。利用LA-ICP-MS锆石U-Pb定年法测得永福岩体中YF-1样品的年龄为133±1 Ma(MSWD=0.50)、YF-2样品的年龄为143±1 Ma(MSWD=0.59),说明其形成于早白垩世,与燕山期岩浆活动有关。该岩体富硅、碱,里特曼指数σ=0.96~2.43,铝饱和指数(A/CNK)=0.98~1.66,属高钾钙碱性系列,准铝质到过铝质范围。稀土元素总量较高,LREE相对富集,HREE相对亏损;具中-弱Eu负异常,弱Ce负异常到无异常,轻重稀土的分馏较微弱;微量元素表现为亏损元素Ba、Sr、K、P和Ti,富集Th、U、Zr、Hf等元素。样品YF-2~YF-7具有S型花岗岩特征,为永福岩体主体,源岩可能来自古-中元古代下地壳沉积岩;而样品YF-1具有Ⅰ型花岗岩特征,源岩可能来自古-中元古代下地壳火成岩。锆石的εHf(t)值除一颗来自残留基底为正值外,其他锆石全部为负值(-4.30~-11.82),Hf同为素二阶段模式年龄tDM2为1.45~1.92 Ga,表明永福岩体可能形成于古老地壳物质的重融。岩体形成于燕山期地壳的伸展背景下,在岩石圈伸展作用下幔源岩浆底侵促使古-中元古代下地壳沉积岩先发生部分熔融,形成永福岩体早期的S型花岗岩,岩浆作用后期,古-中元古代下地壳火成岩部分熔融,形成永福岩体晚期的I型花岗岩。  相似文献   

10.
诸广山南体是一个由加里东期、印支期和燕山期花岗岩组成的巨型复式岩体。本文采用高精度的锆石SHRIMP U-Pb法首先对位于诸广山南体东、西部结合部位的长江、赤坑、企岭和茶山等4个岩体进行精确定年,测定结果分别为160±2Ma(MSWD=1.8)、154±1Ma(MSWD=0.41)、156±2Ma(MSWD=2.5)和157±3Ma(MSWD=2.7),反映它们都是燕山早期岩浆活动产物,从而进一步证实中—晚侏罗世之交是南岭地区岩浆活动的高峰时期。结合这些岩体的岩石学特征以及相邻地区地质资料,上述燕山早期花岗岩是在太平洋板块俯冲影响下,使先期印支地块与华南地块碰撞产生的薄弱构造带发生进一步伸展的背景下由位于中、下地壳部位的古老变质沉积岩发生部分熔融的方式形成。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

13.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

14.
15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

16.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

17.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

19.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引:25,自引:2,他引:25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

20.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

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