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1.
辽宁鞍山地区东山杂岩带3.3～3.1Ga期间的岩浆作用——锆石SHRIMP U-Pb定年 总被引：4，自引：0，他引：4
报道了鞍山地区东山杂岩带奥长花岗岩和二长花岗岩的锆石SHRIMP U-Pb年龄。中粗粒奥长花岗岩中岩浆锆石的年龄为3329Ma±22Ma（MSWD=9.6）,存在年龄为3687~3784Ma的残余锆石。细粒奥长花岗岩和二长花岗岩中岩浆锆石的年龄分别为3141Ma±8Ma（MSWD=1.5）和3142Ma±5Ma（MSWD=0.35）。表明约3.3Ga和3.1Ga是鞍山地区2个重要的地壳演化阶段。 相似文献
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吉塘复式花岗岩位于澜沧江岩浆岩带北段,是研究澜沧江结合带演化过程的重要窗口。对澜沧江北段卡贡地区吉塘复式花岗岩中的黑云母二长花岗岩和花岗闪长岩开展了LA-ICP-MS锆石U-Pb年代学、岩石地球化学研究。研究结果表明,所选锆石样品均具有明显的生长环带,Th/U值普遍大于0.4,为典型的岩浆锆石,分别获得锆石~(206)Pb/~(238)U年龄加权平均值为222.8±1.5Ma(MSWD=1.60,n=16)、213.6±1.1Ma(MSWD=0.98,n=20)和221.1±1.5Ma(MSWD=1.30,n=15),时代均属于晚三叠世。岩石地球化学特征表明,吉塘黑云母二长花岗岩和花岗闪长岩具有较一致的主量、微量元素含量,其变化特征也具有一致性,反映这2类岩石可能为同一期岩浆演化而来;吉塘复式花岗岩属于过铝质S型花岗岩,与临沧花岗岩、纽多花岗岩具有一致的岩石地球化学性质,为澜沧江花岗岩带的重要组成部分,具有统一的构造岩浆活动模式;吉塘复式花岗岩的成因与碰撞造山导致地壳加厚增温及与岩石圈剪切、伸展期有关的深熔作用有关,澜沧江洋的闭合时间可能为273Ma左右。 相似文献
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以赣西地区蒙山岩体为研究对象,通过对该岩体地球化学、锆石U-Pb年龄及Hf同位素的研究,探讨其岩浆物质来源及构造背景。该岩体经历了印支期、燕山期岩浆侵入活动,形成六种岩石类型,LA-ICP-MS锆石U-Pb年龄分别为224.0±2.10 Ma(n=19,MSWD=1.9)、223.0±2.20 Ma(n=21,MSWD=2.6)、222.0±2.80 Ma(n=21,MSWD=2.7)、220.0±1.90 Ma(n=16,MSWD=1.5)、217.0±3.70 Ma(n=8,MSWD=1.8)、142.0±0.98 Ma(n=21,MSWD=1.4),表明岩体经历了印支期、燕山期两期岩浆活动。印支期花岗质岩石地球化学具高硅富钾、准铝-过铝质特征;微量元素富集高场强元素Zr、Hf、Th、U和稀土元素La、Ce、Sm、Nd、Y,明显亏损Rb、Ba、Sr、Ti、P;稀土元素分馏程度不高,δEu介于0.03~0.15,具强Eu负异常,Ce异常不明显,稀土配分曲线呈“V”型;为同源岩浆演化的特点。CaO/Na_(2) O比值<0.3、Rb/Sr>5,岩石二阶段模式年龄T DM2主体介于868~1465 Ma,为中-新元古代,εHf(t)对应的T DM2值显示,岩体物源起源于成熟地壳,后期有大量新生地壳物质的加入,表明岩石来源于含水矿物(如白云母、绿帘石/黝帘石)的脱水反应导致成熟度高地壳物质的熔融而形成。在花岗岩构造环境判别图上,投于碰撞大地构造背景上的花岗岩和造山后花岗岩类(POG)区域,锆石U-Pb年龄表明成岩时段滞后于印支运动高峰期(258~243 Ma),为受印支运动造成华南地壳加厚滞后,地壳进入伸展阶段,减压熔融形成的花岗质岩浆。 相似文献
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黑龙江省漠河县洛古河多金属矿床成因与成矿时代 总被引：1，自引：0，他引：1
《矿物岩石》2015,(3)
洛古河矿床为额尔古纳地块东北部的一个以铅锌为主、伴生铜钼的多金属矿床。为确定该矿床的成因、形成时代及构造背景,开展矿床地质特征研究和同位素测年工作。矿床地质研究表明,该矿床的主矿体主要呈层状、似层状和透镜状,赋存于额尔古纳河组大理岩与黑云母二长花岗岩的接触带附近;矿石中金属矿物主要为方铅矿、闪锌矿、黄铜矿、黄铁矿、辉钼矿,矿石构造以浸染状构造和细脉状构造为主;围岩蚀变类型主要包括矽卡岩化、硅化、绢云母化、碳酸盐化和绿帘石化。同位素测年结果表明,钻孔中矿体附近的黑云母二长花岗岩锆石U-Pb年龄变化范围为137 Ma±3 Ma~123 Ma±1 Ma,加权平均值为131.4 Ma±2.1 Ma(n=21,可信度95%);矿区内花岗斑岩锆石U-Pb年龄变化范围为129 Ma±1Ma~116Ma±2Ma,加权平均值为121.8Ma±1.9Ma(n=16,可信度95%);矽卡岩型多金属矿石中辉钼矿Re-Os模式年龄为127.1 Ma±2.1 Ma。综合分析认为,洛古河矿床属接触交代型多金属矿床,黑云母二长花岗岩为成矿岩体,成岩成矿时代为130 Ma~120 Ma,属大兴安岭北部早白垩世强烈构造岩浆作用的产物。结合区域构造演化及同时代同类矿床对比分析,初步认为洛古河多金属矿床成岩成矿作用发生于蒙古—鄂霍次克洋俯冲闭合后的造山后伸展的构造背景。 相似文献
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对藏东地区浪拉山糜棱岩化二长花岗岩进行了LA-ICP-MS锆石U-Pb年龄测试,获得了该岩体的206Pb/238 U年龄加权平均值为470.5 Ma±3.7 Ma(MSWD=1.7,n=15),属于中奥陶世的产物。岩石地球化学特征表明,岩石具有高钾(Na2O/K2O=13.12~162.89)、铝(A/CNK值平均为1.30)、低钛的特征,岩石属于高钾钙碱性过铝质S型花岗岩。岩石具有明显Eu负异常,表现为Nb,Sr,P、Ti等高场强元素相对亏损,相对富集K,Rb,Th,U等大离子亲石元素,具有岛弧型花岗岩的特征。结合区域地质资料分析,该岩体与区内原特提斯洋的俯冲存在成因联系,藏东地区浪拉山糜棱岩化二长花岗岩的发现有助于进一步探索原特提斯洋演化过程。 相似文献
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粤北下庄铀矿田是我国确定的第一个花岗岩型铀矿田,矿田内的岩浆活动具有加里东、印支和燕山多期、多阶段的特点,并以印支期为主体,但部分花岗岩体的划分、命名和时代归属仍需进一步研究。现有资料显示,矿田中部的笋洞岩体又被归入中南部的高栋岩体,但笋洞岩体的单颗粒锆石稀释法年龄为189 Ma、而高栋岩体的LA-ICP-MS锆石U-Pb年龄为236～232 Ma,二者分别属于燕山期和印支期岩浆活动的产物;矿田中西部的岩庄岩体又被视为笋洞岩体的一部分,但岩庄岩体的LA-ICP-MS锆石U-Pb年龄为161 Ma,小于笋洞和高栋岩体年龄。针对这些问题,本次研究在深入研究笋洞岩体、岩庄岩体岩相学特征的基础上,采用SHRIMP锆石U-Pb法测定了它们的锆石U-Th-Pb的含量,发现笋洞和岩庄花岗岩不仅含有捕获锆石,而且笋洞岩体还含有高铀锆石。剔除这些捕获锆石和高铀锆石的年龄数据后,笋洞中粗粒二云母花岗岩和岩庄细粒二云母花岗岩的锆石206Pb/238U加权平均年龄分别为240.0±2.4 Ma(N=15、MSWD=0.98)和234.4±2.4 Ma(N=13、MS... 相似文献
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诸广山复式花岗岩基位于湘、赣、粤三省交界处,是南岭花岗岩的重要组成部分,由南体和北体组成,出露面积大于5000 km2,形成于加里东期、印支期、燕山期3个时代。通过对诸广山北体3期花岗岩锆石SHRIMP U-Pb定年,结果表明,加里东期花岗闪长岩锆石SHRIMP U-Pb年龄为(414.5±4.5)Ma(n=13,MSWD=0.52)、(417.3±4.8)Ma(n=12,MSWD=0.84),形成于晚志留世末。印支期黑云母二长花岗岩锆石SHRIMP U-Pb年龄(207.5±2.7)Ma(n=10,MSWD=1.6),形成于晚三叠世末。燕山期二云母二长花岗岩锆石SHRIMP U-Pb年龄(148.2±1.7)Ma(n=13,MSWD=0.93),形成于晚侏罗世。该成果为南岭地区构造-岩浆演化及成矿作用研究,提供了重要的花岗岩年代学依据。 相似文献
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岗讲铜钼矿床是西藏冈底斯成矿带中段典型的斑岩型矿床,岗讲矿床成岩成矿时代、岩浆演化过程及其与成岩成矿关系尚不明确,利用LA-ICP-MS锆石U-Pb定年方法对岗讲矿区主要岩体二长花岗斑岩、花岗闪长斑岩和英云闪长玢岩成岩时代进行研究,获得锆石U-Pb年龄加权平均值分别为16.6±0.3 Ma (MSWD=0.94,n=10)、16.1±0.2 Ma (MSWD=1.07,n=12)、14.4±0.4 Ma (MSWD=1.12,n=7);同时采用辉钼矿Re-Os同位素测年方法首次对岗讲矿床石英硫化物脉中的辉钼矿进行定年,获得12件辉钼矿Re-Os同位素模式年龄集中于13.24±0.20 Ma~13.55±0.22 Ma,加权平均年龄为13.4±0.1 Ma (MSWD=0.65),等时线年龄为13.6±1.6 Ma (MSWD=1.2).结果表明:(1) 岗讲矿区复式岩体侵入序列为含巨斑黑云二长花岗岩-二长花岗斑岩-花岗闪长斑岩-流纹斑岩 (深部定名为英云闪长玢岩),成岩时限为16.6~14.4 Ma,成矿时代为13.4 Ma左右,成岩成矿是一个连续的岩浆演化过程;(2) 辉钼矿中Re含量为155.4~171.1 μg/g,均值为162.9 μg/g,指示其成矿物质中有幔源成分的加入;(3) 矿床产出于中新世印度-亚洲大陆碰撞后伸展构造环境. 相似文献
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江南隆起带中段新元古代花岗岩锆石U-Pb年代学和Hf同位素组成研究 总被引：5，自引：1，他引：4
对江南隆起带中段湘东西园坑岩体和赣西九岭岩体的LA-ICPMS锆石U-Pb年代学测定和LA-MC-ICPMS锆石Hf同位素原位分析测试表明:西园坑岩体形成于(804±3)Ma,赣西九岭岩体的年龄为(813±4)Ma和(823±2)Ma,均为新元古代花岗岩.上述三个样品的εHf(t)的加权平均值分别为0.68±0.71,... 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献