Dissociation constants of protonated cysteine species in seawater media     

Virender K. Sharma  Aurelie Moulin  Frank J. Millero  Concetta De Stefano 《Marine Chemistry》2006,99(1-4):52

The dissociation constants (pK₁, pK₂ and pK₃) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK₃ in the Na–Mg–Cl solutions have been attributed to the formation of Mg²⁺ complexes with Cys²⁻ anionsThe stability constants have been fitted toafter corrections are made for the interaction of Mg²⁺ with H⁺.The pK₁ seawater measurements indicate that H₃Cys⁺ interacts with SO₄²⁻. The Pitzer parameters β⁰(H₃CysSO₄), β¹(H₃CysSO₄) and C(H₃CysSO₄) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK₂ and pK₃ in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK₁, pK₂ and pK₃ that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids.  相似文献   

Clinoforms and clinothems: Fundamental elements of basin infill     

Claudio Pellegrini  Stefano Patruno  William Helland-Hansen  Ronald J. Steel  Fabio Trincardi 《Basin Research》2020,32(2):187-205

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The role of a national park in classifying mountain tourism destinations: An exploratory study of the Italian Western Alps     

DUGLIO Stefano  LETEY Marilisa 《山地科学学报》2019,(7)

Together with the main aim of preserving nature, national parks are also expected to play an important role for the local communities, driving economic activities toward the lens of sustainable development. This contribution aims to present an exploratory study on the relationship between the presence of a protected mountain area, the Gran Paradiso National Park(GPNP), in the North West of the Italian Alps, and the classification of tourism destinations, according to Weaver model of destination management. Starting from the model,the authors provide a quantitative analysis using a set of variables and indicators to comprehensively assess the differing patterns assumed by the municipalities within the borders of the GPNP and those that are not.The provisional results illustrate that the municipalities within the border of a protected area are more likely to be grouped alongside the sustainable mountain destinations. Meanwhile,research outcomes confirm that a protected area does not necessarily contrast the tourism industry but instead may boost local development by driving it within the borders of the sustainable development,switching from the area's only preservation function to a flywheel for the local communities.  相似文献   

Gene flow and demographic history of the mangrove crab Neosarmatium meinerti: A case study from the western Indian Ocean     

Lapo Ragionieri  Stefano Cannicci  Christoph D. Schubart  Sara Fratini 《Estuarine, Coastal and Shelf Science》2010

Most marine organisms are characterized by at least one planktonic phase during their life history, potentially allowing interconnection of populations separated by several hundred kilometers. For many years, the idea that marine species are genetically homogenous throughout their range of distribution, due to passive larval transport, has been a paradigm. Nowadays, a growing number of studies underline the existence of boundaries in the marine realm and highlight how larval dispersal is a complex process depending on biotic as well as abiotic factors. Marine fragmented habitats, such as atolls, mangroves and estuaries, are optimal systems for investigating the marine dispersion process under a metapopulation approach, since populations can be geographically defined a priori as opposed to those occupying open marine environments. Within this frame, the present paper investigates the population genetic structure and the demographic history of the mangrove crab Neosarmatium meinerti within the western Indian Ocean by partial sequences of the mitochondrial DNA cytochrome oxidase subunit I. A total of 167 specimens were sampled from six mangrove sites distributed along the East African coast, from Kenya to South Africa, also including a mangrove forest located on Mahé Island, Seychelles. A sharp genetic break between the mainland and the Seychelles is recorded, revealing the existence of two historically distinct groups that can be defined as independent evolutionary units. Gene flow along the East African coast appears to be high enough to form a single metapopulation, probably by means of stepping stone populations. Otherwise, this mainland metapopulation is currently under expansion through a gradual moving front from the subtropical toward the equatorial populations.  相似文献   

Reef status in the Rasfari region (North Malé Atoll,Maldives) five years before the mass mortality event of 1998     

Carla Morri  Stefano Aliani  Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2010

The Maldives was severely hit by massive coral bleaching and subsequent mortality in 1998. The results of reef monitoring in the following years have supported contrasting views about their recovery potential, partly because of the scarcity of information on the situation before 1998. Quantitative data on coral assemblages collected in 1993 in the Rasfari region (North Malé Atoll) may provide a base-line for the evaluation of the present status of the Maldivian reefs. Five years before the 1998 mortality, most coral communities appeared to be similar, in terms of both coral cover and growth-form composition, to those described in 1958 and 1964, notwithstanding increased human pressure and local events such as minor bleaching episodes in 1987 and crown-of-thorns starfish (COTS) attacks in 1989. Three lessons can be learnt from these results to help to understand the present situation, some ten years after the 1998 mass mortality. First, Maldivian reefs proved in the past to be capable of maintaining flourishing coral life despite various disturbances. Second, four years had been sufficient for complete reef recovery after a (minor) bleaching event. Third, recovery after both COTS attack and bleaching follows a predictable path suggesting that the presence of a three-dimensional community structure, which should reduce post settlement mortality of coral recruits, is essential for rapid coral recovery. As coral recruitment remains high and large tabular Acropora colonies are now reappearing, it is expected that Maldivian reefs should return to their original condition within the next few years.  相似文献   

Changes in Venice Lagoon dynamics due to construction of mobile barriers     

Michol Ghezzo  Stefano Guerzoni  Andrea Cucco  Georg Umgiesser 《Coastal Engineering》2010

The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios.  相似文献   

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation     

Pasquale Crea  Concetta De Stefano  Demetrio Milea  Silvio Sammartano   《Marine Chemistry》2008,112(3-4):142-148

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).  相似文献   

Cave clastic sediments as a tool for refining the study of human occupation of prehistoric sites: insights from the cave site of La Cala (Cilento,southern Italy)          下载免费PDF全文

Ivan Martini  Annamaria Ronchitelli  Simona Arrighi  Giulia Capecchi  Stefano Ricci  Sem Scaramucci  Vincenzo Spagnolo  Paolo Gambassini  Adriana Moroni 《第四纪科学杂志》2018,33(5):586-596

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Active thrust tectonics in western Sicily (southern Italy): the 1968 Belice earthquake sequence     

Carmelo Monaco  Stefano Mazzoli  Luigi Tortorici 《地学学报》1996,8(4):372-381

The 1968 Belice earthquake sequence, characterized by six main shocks with 5 < M < 5.4, represents the strongest seismic event recorded in western Sicily in historical times. The epicentral area is located in the Belice Valley, a region lacking any topographic lineament likely to result from a fault with significant offsets of any kind. Instrumental data show that hypocentres of the major shocks are distributed along a roughly N-dipping plane extending from about 36 km to 1 km depth. Fault plane solutions show pure thrusting mechanisms on N-dipping, ENE-trending planes, or oblique slip with a right-lateral component of motion along steep WSW-dipping planes, both as a result of approximate N-S shortening. The observed destruction indicates that isoseismal areas are elongated in an ENE direction. Similarly, the epiccntral distribution of events with M ≥ 4 outlines a roughly elliptical ENE-elongated area located 20 km NW of the Sciacca-Rocca Ficuzza thrust front. This ENE-striking structure, representing the regional morphotectonic feature closest to the epicentral area, consists of two main imbricate fan systems. In the southernmost system, Quaternary deposits (tentatively dated as 1.0–0.7 Myr old) are involved in a large ramp anticline uplifting them to a maximum altitude of 346 m. The occurrence of Holocene lacustrine piggy-back basins on the rear of this structure also indicates late Quaternary activity of the underlying thrust. Seismological, structural and morphotectonic observations suggest that multiple ruptures might have occurred during the 1968 sequence on a blind crustal thrust ramp located beneath the epicentral area. Slip propagated southwards along the shallow ramp-flat system characterizing the thin-skinned foreland fold and thrust belt of southwestern Sicily, being dispersed in flexural folding processes and diffuse strain along this path.  相似文献   

A record of the Messinian salinity crisis in the eastern Ionian tectonically active domain (Greece,eastern Mediterranean)          下载免费PDF全文

Vasileios Karakitsios  Marco Roveri  Stefano Lugli  Vinicio Manzi  Rocco Gennari  Assimina Antonarakou  Maria Triantaphyllou  Konstantina Agiadi  George Kontakiotis  Nefeli Kafousia  Marc de Rafelis 《Basin Research》2017,29(2):203-233

This integrated study (field observations, micropalaeontology, magnetostratigraphy, geochemistry, borehole data and seismic profiles) of the Messinian–Zanclean deposits on Zakynthos Island (Ionian Sea) focuses on the sedimentary succession recording the pre‐evaporitic phase of the Messinian salinity crisis (MSC) through the re‐establishment of the marine conditions in a transitional area between the eastern and the western Mediterranean. Two intervals are distinguished through the palaeoenvironmental reconstruction of the pre‐evaporitic Messinian in Kalamaki: (a) 6.45–6.122 Ma and (b) 6.122–5.97 Ma. Both the planktonic foraminifer and the fish assemblages indicate a cooling phase punctuated by hypersalinity episodes at around 6.05 Ma. Two evaporite units are recognized and associated with the tectonic evolution of the Kalamaki–Argassi area. The Primary Lower Gypsum (PLG) unit was deposited during the first MSC stage (5.971–5.60 Ma) in late‐Messinian marginal basins within the pre‐Apulian foreland basin and in the wedge‐top (<300 m) developed over the Ionian zone. During the second MSC stage (5.60–5.55 Ma), the PLG evaporites were deeply eroded in the forebulge–backbulge and the wedge‐top areas, and supplied the foreland basin's depocentre with gypsum turbidites assigned to the Resedimented Lower Gypsum (RLG) unit. In this study, we propose a simple model for the Neogene–Pliocene continental foreland‐directed migration of the Hellenide thrusting, which explains the palaeogeography of the Zakynthos basin. The diapiric movements of the Ionian Triassic evaporites regulated the configuration and the overall subsidence of the foreland basin and, therefore, the MSC expression in this area.  相似文献