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61.
62.
Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal 总被引:4,自引:4,他引:0
Akihiro Hachikubo Oleg Khlystov Alexey Krylov Hirotoshi Sakagami Hirotsugu Minami Yutaka Nunokawa Satoshi Yamashita Nobuo Takahashi Hitoshi Shoji Shin’ya Nishio Masato Kida Takao Ebinuma Gennadiy Kalmychkov Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329
We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ13C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ13C signatures at two sites where ethane δ13C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which 13C and deuterium were both highly depleted (mean δ13C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C2 δ13C–δD classification for hydrate-bound gas in either freshwater or marine environments. 相似文献
63.
It is widely recognized that the use of Froude similarity for scaling up wave impact pressures recorded during physical model tests may lead to over-estimation of impact maxima. Based on reviewing historical work dating back to the 30s and further developments in the 60s and 80s, a general method is presented that is suitable for scaling up impact pressures and rise times measured during small scale physical model tests. The method accounts for the effect of air leakage and is applicable to most wave impact loads. The model is applied to scale wave impact pressures on vertical walls and similar structures, and consistent correction factors for the Froude scaling law are derived. 相似文献
64.
A pattern of slick streaks winding into a spiral, known as a spiral eddy, was identified in 5 images taken by the ERS-1/2
synthetic aperture radar (SAR) in Mutsu Bay (Japan); dynamic and kinematic models of these spiral eddies have been proposed.
Common characteristics of the five spiral eddies are: 1) an eddy diameter of about 15 km; 2) their location in the western
part of the bay; and 3) their cyclonic direction of rotation. Moreover, the wind conditions over the bay were common: prior
to acquiring the images, a strong easterly wind continued blowing for more than one day. The wind field on the bay is known
to be orographically steered and has strong windstress vorticity, which generates cyclonic circulation. The diameter and location
of the circulation simulated with a numerical ocean model corresponded well to those of the identified spiral eddies. Based
on these facts, we propose a dynamic model for the movement of a slick streak, and a kinematic model for the formation of
a spiral eddy. We have assumed calm air, a microlayer and seawater with a cyclonic circulation in the dynamic model. The balance
of forces is established in the microlayer among the frictional force from the seawater, the frictional force from the calm
air, the gravitational force, and the Coriolis force. As a result, the velocity vector of the microlayer deflects slightly
towards the center of the cyclonic circulation. We have assumed a point source of the microlayer in the kinematic model. The
shapes of a slick streak simulated with the models agree well with the identified patterns in the SAR images. 相似文献
65.
Wataru Takahashi Hiroshi Kawamura Takuo Omura Ken Furuya 《Journal of Oceanography》2009,65(5):647-656
A multi-spectral classification scheme is proposed to identify water with red tide(s) using satellite ocean color imagery
obtained by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The study area was the eastern Seto Inland Sea in Japan,
where serious red tides frequently occur. “Background Ocean Colors” (BOCs hereafter), or colors of water around a red tide
or those of the water before/after a red tide, are calculated as the monthly climatological average of normalized water-leaving
radiances (nLw) with 0.01 degree spatial resolution with SeaWiFS imagery. Criteria for detecting red-tide pixels are established
from analyses of characteristics of the nLws (in the 443, 490, 510, and 555 nm bands) anomalies from BOCs and the nLw spectra
together with the red-tide records in Osaka Bay. The proposed scheme can efficiently indicate the presence or absence of red
tides for independent match-ups with 83% accuracy. Additional validations of specific events indicate that the algorithm performed
well in the study area. These results suggest that the scheme is appropriate to detect red tides in the optically complex
coastal water of the eastern Seto Inland Sea. 相似文献
66.
Hiroshi Ishida Yutaka W. Watanabe Joji Ishizaka Toshiya Nakano Naoki Nagai Yuji Watanabe Akifumi Shimamoto Nobuhiro Maeda Michimasa Magi 《Journal of Oceanography》2009,65(2):179-186
Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a
(Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season,
as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4
and 2.3% year−1 in the subtropical area along 137°E (STA137) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA175) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year−1 in STA137 and KEA175; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year−1 in STA137 and KEA175, respectively. Water density (σ
θ
) at 75 m depth had also decreased by 0.006 and 0.05 year−1 in STA137 and KEA175, respectively. The ratio of biogenic opal to biogenic CaCO3 in the sinking flux decreased by 0.015 year−1 in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening
and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density
of surface water caused by warming in the western North Pacific, especially in the summer. 相似文献
67.
Taro Takahashi Stewart C. Sutherland Rik Wanninkhof Colm Sweeney Richard A. Feely David W. Chipman Burke Hales Gernot Friederich Francisco Chavez Christopher Sabine Andrew Watson Dorothee C.E. Bakker Ute Schuster Nicolas Metzl Hisayuki Yoshikawa-Inoue Masao Ishii Takashi Midorikawa Yukihiro Nojiri Arne Krtzinger Tobias Steinhoff Mario Hoppema Jon Olafsson Thorarinn S. Arnarson Bronte Tilbrook Truls Johannessen Are Olsen Richard Bellerby C.S. Wong Bruno Delille N.R. Bates Hein J.W. de Baar 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2075-2076
68.
Yasutaka Terakado Hiroshi Shimizu Akimasa Masuda 《Contributions to Mineralogy and Petrology》1988,99(1):1-10
Initial Nd and Sr isotopic ratios were obtained for middle Miocene igneous rocks as well as for related rocks from the Outer Zone of Southwest Japan to investigate the petrogenesis of acidic magmas and their relation to a peculiar tectonic environment bearing on the back-arc spreading of the Japan Sea. On the
Nd-
Sr diagram, data points for the acidic rocks fall in the –
Nd, +
Sr quadrant occupying different positions from those for sedimentary and old crustal rocks, and seem to define several subparallel lines which extend towards the lower-righthand sedimentary field. The S-type acidic rocks occupy an intermediate position between I-type rocks and sedimentary ones, a fact suggesting mixing of an igneous component and a sedimentary one. The linear mixing trend observed on the
Nd-
Sr diagram can be attained in the restricted case that the igneous component has similar Sr/Nd concentration ratios to that of the sedimentary one, which implies an intermediate to acidic composition for the igneous component. Inconsistency between the elemental and isotopic variations observed may be reconciled by considering that mixing, probably in the relatively deep part of the crust, might have occured prior to chemical differentiation processes. The episodic igneous activity and the high heat energy required to melt such materials involving sedimentary rocks may be explained by a model in which a hot mantle region probably corresponding to the rising part of the mantle convection supplied the heating energy to the Outer Zone of Southwest Japan when passing beneath Southwest Japan in the course of movement of the hot rising part from the Shikoku basin areas to the Japan Sea area. 相似文献
69.
Tadashi Akamatsu Kiyoshi Fujino Mineo Kumazawa Akio Fujimura Manabu Kato Hiroshi Sawamoto Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113
Synthetic (Mg0.51, Mn0.49)2SiO4 olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (~500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K D = (Mn/Mg) M1/(Mn/Mg) M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction. 相似文献
70.
Initial 87Sr/86Sr ratios, major and trace element compositions have been determined for the Paleogene granitic rocks in the Tsukuba district, Japan. Isotopic ages strongly suggest that the granitic rocks (seven units) were continuously emplaced and solidified during a short time interval. Initial 87Sr/86Sr ratios for seven granitic units vary from 0.7082 to 0.7132, while sedimentary and metasedimentary country rocks have ratios at the time of granitic magma emplacement ranging from 0.7149 to 0.7298. Continuous linear arrays for the granitic rocks in the diagrams of initial 87Sr/86Sr ratios versus some chemical parameters can be explained by either of following two processes. One is the assimilation — fractional crystallization (AFC) process between the parental magma (SiO2 of 68% and initial ratio of 0.7078) and sedimentary country rocks, and the other is magma mixing process between above parental magma and sediment derived acidic magma (melt) (SiO2 of 75%). The high initial ratios (0.7078–0.7098) for basic rocks such as gabbro or diorite in the Tsukuba district and the similar characteristics observed in the rocks of Ryoke belt (SW Japan) suggest that the parental magma had the same source region as the basic rocks, probably the lower crustal source. 相似文献