Fossil brines preserved in the St-Lawrence Lowlands, Québec, Canada as revealed by their chemistry and noble gas isotopes     

Daniele L. Pinti  Catherine Béland-Otis  Alain Tremblay  Chris M. Hall  Jean-Yves Lavoie 《Geochimica et cosmochimica acta》2011,75(15):4228-4243

Brines in Cambrian sandstones and Ordovician dolostones of the St-Lawrence Lowlands at Bécancour, Québec, Canada were sampled for analysis of all stable noble gases in order to trace their origin and migration path, in addition to quantifying their residence time. Major ion chemistry indicates that the brines are of Na-Ca-Cl type, possibly derived from halite dissolution. ⁸⁷Sr/⁸⁶Sr ratios and Ca excess indicate prolonged interactions with silicate rocks of the Proterozoic Grenville basement or the Cambrian Potsdam sandstone. The brines constrain a 2-3% contribution of mantle ³He and large amounts of nucleogenic ²¹Ne^∗ and ³⁸Ar^∗ and radiogenic ⁴He and ⁴⁰Ar^∗. ⁴He/⁴⁰Ar^∗ and ²¹Ne^∗/⁴⁰Ar^∗ ratios, corrected for mass fractionation during incomplete brine degassing, are identical to their production ratios in rocks. The source of salinity (halite dissolution), plus the occurrence of large amounts of ⁴⁰Ar^∗ in brines constrain the residence time of Bécancour brines as being older than the Cretaceous. Evaporites in the St-Lawrence Lowlands likely existed only during Devonian-Silurian time. Brines might result from infiltration of Devonian water leaching halite, penetrating into or below the deeper Cambrian-Ordovician aquifers. During the Devonian, the basin reached temperatures higher than 250 °C, allowing for thermal maturation of local gas-prone source rocks (Utica shales) and possibly facilitating the release of radiogenic ⁴⁰Ar^∗ into the brines. The last thermal event that could have facilitated the liberation of ⁴⁰Ar^∗ into fluids and contributed to mantle ³He is the Cretaceous Monteregian Hills magmatic episode. For residence times younger than the Cretaceous, it is difficult to find an appropriate source of salinity and of nucleogenic/radiogenic gases to the Bécancour brines.  相似文献   

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4     

Francesco Di Benedetto  Daniele Borrini  Andrea Caneschi  Gabriele Fornaciai  Massimo Innocenti  Alessandro Lavacchi  Carlo Andrea Massa  Giordano Montegrossi  Werner Oberhauser  Luca A. Pardi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   

Nouvelles données sur le Messinien de Méditerranée occidentale : les gisements à Aphanius crassicaudus (Agassiz poissons téléostéens,cyprinodontiformes) des Marches (Italie)     

Jean Gaudant  Francesco Guerrera  Daniele Savelli 《Geodinamica Acta》2013,26(4):185-196

Résumén

La découverte, dans le Nord des Marches (Italie), de nouveaux gisements de Poissons Cyprinodontidae appartenant à l’espèce Aphanius crassicaudus (AGASSIZ), conduit à réexaminer, à la lumière des données lithostratigraphiques, la signification géodynamique des ichthyofaunes messiniennes de ce secteur de l’Apennin. Après avoir précisé la position stratigraphique et la répartition paléogéographique des gisements étudiés, les auteurs montrent que le développement des faunes à Aphanius crassicaudus (AGASSIZ) dans les eaux saumâtres du domaine continental n’implique pas la disparition corrélative du milieu marin. En effet, certains genres marins sont parfois présents à côté de cette espèce, comme c’est le cas dans le gisement de Pésaro. Les auteurs contestent en outre l’interprétation selon laquelle le fait qu’aucune ichthyofaune marine ne soit connue dans le Messinien supérieur d’Italie puisse suffire à conclure que la Méditerranée était asséchée pendant le dépôt de la « Formation à colombacci »  相似文献   

The Ligurian Helminthoid flysch units of the Emilian Apennines: stratigraphic and petrographic features,paleogeographic restoration and structural evolution     

Giovanna Daniele 《Geodinamica Acta》2013,26(5):313-333

Abstract

This work deals with the Cretaceous-Tertiary Helminthoid flysch successions of the Emilian Apennines and related basal complexes (Mt. Caio, Val Baganza, Solignano, Mt. Venere-Monghidoro and Mt. Cassio Units): it is based on an integrated approach which included stratigraphic, petrographic and structural observations. Detailed stratigraphic sections measured in the various successions evidenced the specific features of the different flysch formations. The main framework composition analysis of the arenites pointed out a partly ‘oceanic’ alimentation for the Mt. Caio Flysch Fm; the Mt. Venere-Monghidoro, and Mt. Cassio Flysch Fms have been alimented exclusively by a terrigenous detritus mainly derived from continental basement source areas. The heavy mineral assemblage of the Mt. Caio Flysch Fm is characterized by picotite, that of the Mt. Venere-Monghidoro, Solignano and Mt. Cassio Flysch Fms commonly contains straurolite, garnet and chloritoid, generally considered to be typical products of the Adriatic continental margin. The calcareous nannofossils biostratigraphy indicated that the flysch sedimentation started during the Late Campanian and ended between the Paleocene (Mt. Cassio Flysch Fm and Mt. Venere-Monghidoro Fms) and the Middle Eocene (Mt. Caio Flysch Fm). We propose a schematic paleogeographic restoration for the External Ligurian Domain which implies a more internal position for the Mt. Caio succession and a more external one for the Mt. Venere-Monghidoro and Mt. Cassio successions. The Helminthoid flyschs sedimented after and during deformation and subduction phases in perched and fore-arc basins partly overlying the marginal part of the Adriatic plate. The External Ligurian nappes’ stacking consists, in the study area, from the bottom, of the following units: Caio Unit, Val Baganza Ophiolitic Unit, Monghidoro Unit, Cassio Unit. This pile of thrust-nappes, sealed by the Epiligurian succession, has been already realized before Late Eocene. In our opinion it was generated by a frontal west-verging frontal accretion process (offscraping), which let the flysch successions remain, in this phase, quite undeformed. This westverging thrusting phase, starting from the Middle-Late Eocene, has been followed by an important folding event which generated striking hectometric and kilometric ‘Apenninic’ reverse folds, sometimes associated with NE-verging thrust surfaces. The Oligocene and post-Oligocene evolution is characterized by a block-translation of the Ligurian staking over the Subligurian, Tuscan and Umbrian Domains, associated with a new generation of minor thrusts and thrust related Apenninic folds. © 2000 Éditions scientifiques et médicales Elsevier SAS  相似文献   

Controls on event runoff coefficients in the eastern Italian Alps   总被引：3，自引：0，他引：3  

Daniele Norbiato  Marco Borga  Ralf Merz  Günther Blschl  Alberto Carton 《Journal of Hydrology》2009,375(3-4):312-325

Analyses of event runoff coefficients provide essential insight on catchment response, particularly if a range of catchments and a range of events are compared by a single indicator. In this study we examine the effect of climate, geology, land use, flood types and initial soil moisture conditions on the distribution functions of the event runoff coefficients for a set of 14 mountainous catchments located in the eastern Italian Alps, ranging in size from 7.3 to 608.4 km². Runoff coefficients were computed from hourly precipitation, runoff data and estimates of snowmelt. A total of 535 events were analysed over the period 1989–2004. We classified each basin using a “permeability index” which was inferred from a geologic map and ranged from “low” to “high permeability”. A continuous soil moisture accounting model was applied to each catchment to classify ‘wet’ and ‘dry’ initial soil moisture conditions. The results indicate that the spatial distribution of runoff coefficients is highly correlated with mean annual precipitation, with the mean runoff coefficient increasing with mean annual precipitation. Geology, through the ‘permeability index’, is another important control on runoff coefficients for catchments with mean annual precipitation less than 1200 mm. Land use, as indexed by the SCS curve number, influences runoff coefficient distribution to a lesser degree. An analysis of the runoff coefficients by flood type indicates that runoff coefficients increase with event snowmelt. Results show that there exists an intermediate region of subsurface water storage capacity, as indexed by a flow–duration curve-based index, which maximises the impact of initial wetness conditions on the runoff coefficient. This means that the difference between runoff coefficients characterised by wet and dry initial conditions is negligible both for basins with very large storage capacity and for basins with small storage capacity. For basins with intermediate storage capacities, the impact of the initial wetness conditions may be relatively large.  相似文献   

Physical processes contributing to the water mass transformation of the Indonesian Throughflow   总被引：1，自引：1，他引：0  

Ariane Koch-Larrouy  Gurvan Madec  Daniele Iudicone  Agus Atmadipoera  Robert Molcard 《Ocean Dynamics》2008,58(3-4):275-288

The properties of the waters that move from the Pacific to the Indian Ocean via passages in the Indonesian archipelago are observed to vary with along-flow-path distance. We study an ocean model of the Indonesian Seas with reference to the observed water property distributions and diagnose the mechanisms and magnitude of the water mass transformations using a thermodynamical methodology. This model includes a key parameterization of mixing due to baroclinic tidal dissipation and simulates realistic water property distributions in all of the seas within the archipelago. A combination of air–sea forcing and mixing is found to significantly change the character of the Indonesian Throughflow (ITF). Around 6 Sv (approximately 1/3 the model net ITF transport) of the flow leaves the Indonesian Seas with reduced density. Mixing transforms both the intermediate depth waters (transforming 4.3 Sv to lighter density) and the surface waters (made denser despite the buoyancy input by air–sea exchange, net transformation?=?2 Sv). The intermediate transformation to lighter waters suggests that the Indonesian transformation contributes significantly to the upwelling of cold water in the global conveyor belt. The mixing induced by the wind is not driving the transformation. In contrast, the baroclinic tides have a major role in this transformation. In particular, they are the only source of energy acting on the thermocline and are responsible for creating the homostad thermocline water, a characteristic of the Indonesian outflow water. Furthermore, they cool the sea surface temperature by between 0.6 and 1.5°C, and thus allow the ocean to absorb more heat from the atmosphere. The additional heat imprints its characteristics into the thermocline. The Indonesian Seas cannot only be seen as a region of water mass transformation (in the sense of only transforming water masses in its interior) but also as a region of water mass formation (as it modifies the heat flux and induced more buoyancy flux). This analysis is complemented with a series of companion numerical experiments using different representations of the mixing and advection schemes. All the different schemes diagnose a lack of significant lateral mixing in the transformation.  相似文献   

Gully head modelling: A Mediterranean badland case study          下载免费PDF全文

Dino Torri  Jean Poesen  Mauro Rossi  Valerio Amici  Daniele Spennacchi  Cati Cremer 《地球表面变化过程与地形》2018,43(12):2547-2561

Predicting the location of gully heads in various environments is an important step towards predicting gully erosion rates. So far, field data collection and modelling of topographic thresholds for gully head development has mainly focused on gullies that formed in forested areas, rangelands, pastures and cropland. Such information for gullies in badlands however is very scarce. Therefore, this paper aims to extend the database on gully head topographical thresholds through data collection in a badland area and to improve the prediction of gully heads forming at sites with a very low erosion resistance value. For this, we chose a badland site located in central Italy that is characterized by biancana forms and both active and dormant gullies. The definition of the conditions under which present‐day gully heads developed allowed a better modelling of the gully head threshold equation, with modification of a previous model and the exemplification of how to use the updated model. The model shows that the resistance to gully head retreat depends on slope gradient and drainage area at gully heads, land use at the moment of gully development (as numerically expressed using parameters derived from the Runoff Curve Number method), surface rock fragment cover, presence of joints, pipes, and factors/processes affecting detachment rate. This study attempted to better understand environmental conditions that control the development of gully heads in badlands through a combination of field data collection of gully heads, an analysis of land use changes over 10 centuries, focusing on the period 1820–2005, and land use management through repeat photography and a critical examination of historical documents. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Operation of two major reservoirs of Iran under IPCC scenarios during the XXI century          下载免费PDF全文

Habib Akbari‐Alashti  Andrea Soncini  Yagob Dinpashoh  Ahmad Fakheri‐Fard  Siamak Talatahari  Daniele Bocchiola 《水文研究》2018,32(21):3254-3271

We assess the effects of prospective climate change until 2100 on water management of two major reservoirs of Iran, namely, Dez (3.34 × 10⁹ m³) and Alavian (6 × 10⁷ m³). We tune the Poly‐Hydro model suited for simulation of hydrological cycle in high altitude snow‐fed catchments. We assess optimal operation rules (ORs) for the reservoirs using three algorithms under dynamic and static operation and linear and non‐linear decision rules during control run (1990–2010 for Dez and 2000–2010 for Alavian). We use projected climate scenarios (plus statistical downscaling) from three general circulation models, EC‐Earth, CCSM4, and ECHAM6, and three emission scenarios, or representative concentration pathways (RCPs), RCP2.6, RCP4.5, and RCP8.5, for a grand total of nine scenarios, to mimic evolution of the hydrological cycle under future climate until 2100. We subsequently test the ORs under the future hydrological scenarios (at half century and end of century) and the need for reoptimization. Poly‐Hydro model when benchmarked against historical data well mimics the hydrological budget of both catchments, including the main processes of evapotranspiration and streamflows. Teaching–learning‐based optimization delivers the best performance in both reservoirs according to objective scores and is used for future operation. Our projections in Dez catchment depict decreased precipitation along the XXI century, with ?1% on average (of the nine scenarios) at half century and ?6% at the end of century, with changes in streamflows on average ?7% yearly and ?13% yearly, respectively. In Alavian, precipitation would decrease by ?10% on average at half century and ?13% at the end of century, with streamflows ?14% yearly and ?18% yearly, respectively. Under the projected future hydrology, reservoirs' operation would provide lower performance (i.e., larger lack of water) than now, especially for Alavian dam. Our results provide evidence of potentially decreasing water availability and less effective water management in water stressed areas like Northern Iran here during this century.  相似文献   

Using the applied element method for modelling calcium silicate brick masonry subjected to in‐plane cyclic loading          下载免费PDF全文

Daniele Malomo  Rui Pinho  Andrea Penna 《地震工程与结构动力学》2018,47(7):1610-1630

The response of calcium silicate unreinforced masonry construction to horizontal cyclic loading has recently become the focus of experimental and numerical research, given its extensive use in some areas of the world that are now exposed to induced earthquakes (eg, north of the Netherlands). To assess the seismic behaviour of such construction, a relatively wide range of modelling methodologies are available, amongst which the discrete elements approach, which takes into account the intrinsic heterogeneity of a brick‐mortar assembly, can probably be deemed as the most appropriate computational procedure. On the other hand, however, since discrete elements numerical methods are based on a discontinuum domain, often they are not able to model every stage of the structural response adequately, and because of the high computational burden required, the analysis scale should be chosen carefully. The applied element method is a relatively recent addition to the discrete elements family, with a high potential for overcoming the aforementioned limitations or difficulties. Initially conceived to model blast events and concrete structures, its use in the earthquake engineering field is, of late, increasing noticeably. In this paper, the use of the applied element method to model the in‐plane cyclic response of calcium silicate masonry walls is discussed and scrutinised, also through the comparison with experimental results of in‐plane cyclic shear‐compression tests on unreinforced masonry walls.  相似文献   

Estimating free parameters in 2D inversion: example of gravity inversion in a rifted basement     

João B.C. Silva  Darcicléa F. Santos  Daniele P. Monteiro 《Geophysical Prospecting》2020,68(3):1057-1071

We advance a principle directed to assigning numerical values to free parameters usually present in inversion methods. It may be formulated as: ‘Optimum estimates of free parameters in an inversion procedure must lead, in tests using synthetic data, to solutions whose geometrical expression reflects the main qualitative or semiquantitative geological characteristic of the study area.’ To this end, the interpreter should (i) specify a typical anomalous source geometry which incorporates the most relevant geological information for the study area, (ii) compute the corresponding gravity anomaly and (iii) invert the anomaly for the source geometry finding the numerical values of the free parameters that lead to a solution closest to the typical source. Application of the above methodology to synthetic and real data from the basement relief of a rift basin has asserted its efficacy.  相似文献