Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale     

Dale P. Cruikshank  Allan W. Meyer  Roger N. Clark  Katrin Stephan  Scott A. Sandford  Gianrico Filacchione  Philip D. Nicholson  Thomas B. McCord  J. Brad Dalton  Dennis L. Matson 《Icarus》2010,206(2):561-572

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.  相似文献   

Structural styles and tectonic evolution of the Kolia-Boboti sedimentary Basin,Kédougou-Kéniéba inlier,eastern Senegal     

Moussa Dabo  Tahar Aïfa 《Comptes Rendus Geoscience》2010,342(10):796-805

New structural data obtained on the Birimian terranes of the Kolia-Boboti sedimentary Basin, the eastern part of the Dialé-Daléma Supergroup in the Kédougou-Kéniéba inlier show two major phases of Eburnean compressional deformation: (1) a D1 phase of thrusting tectonics affected the Lower Birimian B1 tourmalinized sediments. This first tectonic phase is characterized by isoclinals overturned to recumbent folds P1 with N040° 20°NE trending axis, associated with axial plane schistosity S₀S₁ which is mainly transposed in the bedding; (2) a D2 phase of compressional (D2a) and transpressional (D2b) tectonics is responsible for the crossfolds P2a-P2b exhibiting curved axes. These P2 folds are associated with the major schistosity S₂, north-south to SW-NE trending, mainly dipping to the south-east. The S₂ schistosity is mostly displayed in the large shear zones corridors where it steeply dips locally toward the north-west. A north-west vergence thrusting phase (D2c) of flats and ramps, associated with reverse folds, represents the last Eburnean event. This geometrical feature is characteristic of a “positive flower structure”. These different Eburnean compressional phases are separated by extensional deformation which is characterized by sedimentary deposits and volcanic flows.  相似文献   

Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran     

Mahnaz Khodami  Moussa Noghreyan  Ali Reza Davoudian 《Arabian Journal of Geosciences》2010,3(3):257-266

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.  相似文献   

Enhancing the relevance of Shared Socioeconomic Pathways for climate change impacts,adaptation and vulnerability research   总被引：1，自引：1，他引：0  

Bas J. van Ruijven  Marc A. Levy  Arun Agrawal  Frank Biermann  Joern Birkmann  Timothy R. Carter  Kristie L. Ebi  Matthias Garschagen  Bryan Jones  Roger Jones  Eric Kemp-Benedict  Marcel Kok  Kasper Kok  Maria Carmen Lemos  Paul L. Lucas  Ben Orlove  Shonali Pachauri  Tom M. Parris  Anand Patwardhan  Arthur Petersen  Benjamin L. Preston  Jesse Ribot  Dale S. Rothman  Vanessa J. Schweizer 《Climatic change》2014,122(3):481-494

This paper discusses the role and relevance of the shared socioeconomic pathways (SSPs) and the new scenarios that combine SSPs with representative concentration pathways (RCPs) for climate change impacts, adaptation, and vulnerability (IAV) research. It first provides an overview of uses of social–environmental scenarios in IAV studies and identifies the main shortcomings of earlier such scenarios. Second, the paper elaborates on two aspects of the SSPs and new scenarios that would improve their usefulness for IAV studies compared to earlier scenario sets: (i) enhancing their applicability while retaining coherence across spatial scales, and (ii) adding indicators of importance for projecting vulnerability. The paper therefore presents an agenda for future research, recommending that SSPs incorporate not only the standard variables of population and gross domestic product, but also indicators such as income distribution, spatial population, human health and governance.  相似文献   

Late Miocene sedimentary architecture of the Ebro Continental Margin (Western Mediterranean): implications to the Messinian Salinity Crisis     

Alejandra L. Cameselle  Roger Urgeles  Ben De Mol  Angelo Camerlenghi  Jason C. Canning 《International Journal of Earth Sciences》2014,103(2):423-440

The Messinian Salinity Crisis (MSC) resulted from a significant multi-phase drop and subsequent reflooding of the Mediterranean Sea from 5.96 to 5.33 Ma. Well-developed drainage networks, characterized by step-like profiles and abrasion platforms, are associated to this event. The Ebro Continental Margin (Western Mediterranean) presents an additional complexity since the capture of the drainage of the adjacent subaerial Ebro Basin took place sometime prior to the Messinian stage. Using 3D seismic reflection data, this work provides new insights into the origin of the step-like profile of the Messinian erosional surface (MES) and timing of the capture of the subaerial Ebro Basin. The results obtained indicate a sedimentary-active continental slope and delta progradation during Middle-Late Miocene, in a normal regressive context associated to a pre-Messinian proto-Ebro River. The mature development attained by the Messinian Ebro River network during the MSC corroborates that the capture of the Ebro Basin occurred prior to the MSC. The configuration of the clinoforms below the MES suggests that deltaic sediments of the Messinian Paleo-Ebro River deposited during the Tortonian and initial Messinian sea-level drawdown. The MES formed at the top of the Tortonian Highstand, where a fluvial network was deeply carved, and in the topset region of the Messinian Falling Stage Systems Tract, where minor erosion occurred. Fluvial deposits are outstandingly preserved on the main valleys of the MES. Therefore, the step-like profile of the MES was not created during Zanclean inundation, but during the latest stages of the main Messinian sea-level fall and lowstand.  相似文献   

Promoting geodiversity: learning lessons from biodiversity     

Roger Crofts 《Proceedings of the Geologists' Association. Geologists' Association》2014

Progress made in promoting geodiversity in recent times is reviewed, concluding that it is now an established component of the Earth Sciences. However, it still lacks the status and standing of biodiversity in governmental, political and public forums. The paper assesses what can be learnt from the experience of the development and promotion of biodiversity. Based on this experience, eight suggestions for increasing the understanding and ownership of geodiversity beyond the Earth science community are provided as a basis for discussion.  相似文献   

Contrasting geochemical signatures on land from the Middle and Late Permian extinction events     

Nathan D. Sheldon  Ramananda Chakrabarti  Gregory J. Retallack  Roger M. H. Smith 《Sedimentology》2014,61(6):1812-1829

The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ¹³C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.  相似文献   

Observations on the crystal structures of lueshite     

Roger H. Mitchell  Peter C. Burns  Kevin S. Knight  Christopher J. Howard  Anton R. Chakhmouradian 《Physics and Chemistry of Minerals》2014,41(6):393-401

Laboratory powder XRD patterns of the perovskite-group mineral lueshite from the type locality (Lueshe, Kivu, DRC) and pure NaNbO₃ demonstrate that lueshite does not adopt the same space group (Pbma; #57) as the synthetic compound. The crystal structures of lueshite (2 samples) from Lueshe, Mont Saint-Hilaire (Quebec, Canada) and Sallanlatvi (Kola, Russia) have been determined by single-crystal CCD X-ray diffraction. These room temperature X-ray data for all single-crystal samples can be satisfactorily refined in the orthorhombic space group Pbnm (#62). Cell dimensions, atomic coordinates of the atoms, bond lengths and octahedron tilt angles are given for four crystals. Conventional neutron diffraction patterns for Lueshe lueshite recorded over the temperature range 11–1,000 K confirm that lueshite does not adopt space group Pbma within these temperatures. Neutron diffraction indicates no phase changes on cooling from room temperature to 11 K. None of these neutron diffraction data give satisfactorily refinements but suggest that this is the space group Pbnm. Time-of-flight neutron diffraction patterns for Lueshe lueshite recorded from room temperature to 700 °C demonstrate phase transitions above 550 °C from Cmcm through P4/mbm to \(Pm\overline{3} m\) above 650 °C. Cell dimensions and atomic coordinates of the atoms are given for the three high-temperature phases. The room temperature to 400 °C structures cannot be satisfactorily resolved, and it is suggested that the lueshite at room temperature consists of domains of pinned metastable phases with orthorhombic and/or monoclinic structures. However, the sequence of high-temperature phase transitions observed is similar to those determined for synthetic NaTaO₃, suggesting that the equilibrated room temperature structure of lueshite is orthorhombic Pbnm.  相似文献   

Barriers in the science-policy-practice interface: Toward a knowledge-action-system in global environmental change research     

Juergen Weichselgartner  Roger Kasperson 《Global Environmental Change》2010,20(2):266-277

This paper presents the results of a case study analysis from the knowledge domains of vulnerability and resilience. We analyzed 20 scientific assessments to provide empirical evidence for successes and failures in collaborative knowledge production, i.e., the joint creation of assessments reports by researchers and decision makers in policy and practice. It became clear that the latter typically use insufficiently the research-based knowledge available and researchers typically produce insufficiently knowledge that is directly usable. We found a number of functional, structural, and social factors inhibiting a joint problem identification and framing of knowledge producers and potential users: divergent objectives, needs, scope, and priorities; different institutional settings and standards, as well as differing cultural values, understanding, and mistrust. Combining understanding from multiple sources and providing mechanisms for linking solutions proposed by research with articulated needs and problems of practitioners would reduce the discrepancies in activities of different actors and result in more timely and context-appropriate solutions. In the concluding section we argue for a more locally embedded and socially contingent production of actionable knowledge and make suggestions about ways to enhance effectiveness of research-based knowledge.  相似文献   

The Three Gorges Dam of the Yangtze River, China: engineering geology in China     

Roger Mason 《Geology Today》1999,15(1):30-33

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