International viewpoint and news     

Anne-Marie de Grosbois 《Environmental Geology》2008,53(8):1819-1822

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Climatic history of the African and Arabian deserts     

Anne-Marie Lézine 《Comptes Rendus Geoscience》2009,341(8-9):569-574

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GONG p-Mode Parameters Through Two Solar Cycles     

René Kiefer  Rudi Komm  Frank Hill  Anne-Marie Broomhall  Markus Roth 《Solar physics》2018,293(11):151

We investigate the parameters of global solar p-mode oscillations, namely damping width \(\Gamma\), amplitude \(A\), mean squared velocity \(\langle v^{2}\rangle\), energy \(E\), and energy supply rate \(\mathrm{d}E/\mathrm{d}t\), derived from two solar cycles’ worth (1996?–?2018) of Global Oscillation Network Group (GONG) time series for harmonic degrees \(l=0\,\mbox{--}\,150\). We correct for the effect of fill factor, apparent solar radius, and spurious jumps in the mode amplitudes. We find that the amplitude of the activity-related changes of \(\Gamma\) and \(A\) depends on both frequency and harmonic degree of the modes, with the largest variations of \(\Gamma\) for modes with \(2400~\upmu\mbox{Hz}\le\nu\le3300~\upmu\mbox{Hz}\) and \(31\le l \le60\) with a minimum-to-maximum variation of \(26.6\pm0.3\%\) and of \(A\) for modes with \(2400~\upmu\mbox{Hz}\le\nu\le 3300~\upmu\mbox{Hz}\) and \(61\le l \le100\) with a minimum-to-maximum variation of \(27.4\pm0.4\%\). The level of correlation between the solar radio flux \(F_{10.7}\) and mode parameters also depends on mode frequency and harmonic degree. As a function of mode frequency, the mode amplitudes are found to follow an asymmetric Voigt profile with \(\nu_{\text{max}}=3073.59\pm0.18~\upmu\mbox{Hz}\). From the mode parameters, we calculate physical mode quantities and average them over specific mode frequency ranges. In this way, we find that the mean squared velocities \(\langle v^{2}\rangle\) and energies \(E\) of p modes are anticorrelated with the level of activity, varying by \(14.7\pm0.3\%\) and \(18.4\pm0.3\%\), respectively, and that the mode energy supply rates show no significant correlation with activity. With this study we expand previously published results on the temporal variation of solar p-mode parameters. Our results will be helpful to future studies of the excitation and damping of p modes, i.e., the interplay between convection, magnetic field, and resonant acoustic oscillations.  相似文献   

Dissolved load of the Loire River: chemical and isotopic characterization   总被引：5，自引：0，他引：5  

C. Grosbois  Ph. Ngrel  C. Fouillac  D. Grimaud 《Chemical Geology》2000,170(1-4):179-201

The Loire River, with one of the largest watersheds in France, has been monitored just outside the city of Orleans since 1994. Physico-chemical parameters and major and trace elements were measured between 2-day and 1-week intervals according to the river flow. The sampling site represents 34% of the total Loire watershed with 76% silicate rocks and 24% carbonate rocks.

Elements are transported mainly in the dissolved phase with the ratio of total dissolved salts (TDS) to suspended matter (SM) ranging between 1.6 and 17.4. Chemical weathering of rocks and soils are thus the dominant mechanisms in the Loire waters composition. The highest TDS/SM ratios are due to dissolved anthropogenic inputs. The database shows no link between NO₃⁻ content and river flow. The Na⁺, K⁺, Mg²⁺, SO₄²⁻, and Cl⁻ concentrations are seen to decrease with increasing discharge, in agreement with a mixing process involving at least two components: the first component (during low flow) is concentrated and may be related with input from the groundwater and sewage station water, the second component (during high flow) is more dilute and is in agreement with bedrock weathering and rainwater inputs. A geochemical behaviour pattern is also observed for HCO₃⁻ and Ca²⁺ species, their concentrations increase with increasing discharge up to 300 m³/s, after which, they decrease with increasing discharge. The Sr isotopic composition of the dissolved load is controlled by at least five components — a series of natural components represented by (a) waters draining the silicate and carbonate bedrock, (b) groundwater, and (c) rainwaters, and two kinds of anthropogenic components.

The aim of this study is to describe the mixing model in order to estimate the contribution of each component. Finally, specific export rates in the upper Loire watershed were evaluated close to 12 t year⁻¹ km⁻² for the silicate rate and 47 t year⁻¹ km⁻² for the carbonate rate.  相似文献   

Book review     

Anne-Marie de Grosbois 《Environmental Geology》2006,50(4):613-615

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Mantle-derived volatiles in continental crust: the Massif Central of France   总被引：1，自引：0，他引：1  

A. Matthews  C. Fouillac  R. Hill  R.K. O'Nions  E.R. Oxburgh 《Earth and Planetary Science Letters》1987,85(1-3)

CO₂-rich gases and groundwaters from springs and boreholes originating within the basement of the Massif Central have variable³He/⁴He ratios with correspondingR/R_a values ranging from 0.8 to 5.5 and 0.3 to 2.8 respectively, indicating the presence of a significant component of mantle helium. Molar concentrations of rare gases in the CO₂-rich gases are approximately 5 orders of magnitude greater than in the waters and suggest that a near-surface Henry's Law fractionation has occurred between exsolving CO₂ and water.δ¹³C values of the CO₂-rich gases are in the range −4.2 to −6.1‰, i.e. in that range normally attributed to mantle carbon, but which could also represent an average crustal composition and therefore do not discriminate between mantle and crustal sources.C/³He ratios show 4 orders of magnitude variation from 1.4 × 10¹² to 5 × 10⁸ and, compared to a mantleC/³He ratio of 10⁹, indicate that either a complex fractionation has occurred between mantle helium and mantle CO₂ or more likely that mantle rare gases have been diluted by large quantities of CO₂ with an average crustal carbon isotope composition. The regional distribution of³He and C does not show any obvious relationship to age or proximity of volcanic centres or major faults, suggesting that mantle-derived C and He components decoupled from their silicate melt sources at some depth.The results from this area of active fluid circulation suggest that C-isotope data derived from metamorphic terrains should be interpreted with great caution, but that input of some mantle-derived carbon is expected to accompany crustal extension.  相似文献   

Solubility of silica polymorphs in electrolyte solutions, I. Activity coefficient of aqueous silica from 25° to 250°C, Pitzer''s parameterisation     

M. Azaroual  C. Fouillac  J. M. Matray 《Chemical Geology》1997,140(3-4):155-165

Within the framework of Pitzer's specific interaction model, interaction parameters for aqueous silica in concentrated electrolyte solutions have been derived from Marshall and co-authors amorphous silica solubility measurements. The values, at 25°C, of the Pitzer interaction parameter (λ_SiO2(aq)−i) determined in this study are the following: 0.092 (i = Na⁺), 0.032 (K⁺), 0.165 (Li⁺), 0.292 (Ca²⁺, Mg²⁺), −0.139 (SO₄²⁻), and −0.009 (NO₃⁻). A set of polynomial equations has been derived which can be used to calculate λ_SiO2(aq)−i for these ions at any temperature up to 250°C. A linear relationship between the aqueous silica-ion interaction parameters (λ_SiO2(aq)−i) and the surface electrostatic field (Z_i/r_e,i) of ions was obtained. This empirical equation can be used to estimate, in first approximation, λ_SiO2(aq)−i if no measurements are available. From this parameterisation, the calculated activity coefficient of aqueous silica is 2.52 at 25°C and 1.45 at 250°C in 5 m NaCl solution. At lower concentrations, e.g. 2 m NaCl, the activity coefficient of silica is 1.45 at 25°C and 1.2 at 250°C. Hence, in practice, it is necessary to take into account the activity coefficient of aqueous silica (λ_SiO2(aq)≠1) in hydrothermal solutions and basinal brines where the ionic strength exceeds 1. A comparison of measured [Marshall, W.L., Chen, C.-T.A., 1982. Amorphous silica solubilities, V. Prediction of solubility behaviour in aqueous mixed electrolyte solutions to 300°C. Geochim. Cosmochim. Acta 46, 289–291.] and computed amorphous silica solubility, using this parameterisation, shows a good agreement. Because the effect of individual ions on silicate and silica polymorph solubilities are additive, the present study has permitted to derive Pitzer interaction parameters that allow a precise computation of γ_SiO2(aq) in the Na---K---Ca---Mg---Cl---SO₄---HCO₃---SiO₂---H₂O system, over a large range of salt concentrations and up to temperatures of 250°C.  相似文献   

Solubility of silica polymorphs in electrolyte solutions, II. Activity of aqueous silica and solid silica polymorphs in deep solutions from the sedimentary Paris Basin     

M. Azaroual  C. Fouillac  J. M. Matray 《Chemical Geology》1997,140(3-4):167-179

Activity coefficient for aqueous silica in saline waters and brines from the Paris Basin was calculated using Pitzer's specific interaction model. Quartz and chalcedony are the only reported authigenic silica minerals in the Dogger aquifer of the Paris Basin (France). However, the measured silica concentrations fall between those of these two phases. The silica concentrations measured in Dogger fluids seem to be controlled by a microcrystalline quartz phase with a grain size computed to be about 20 nm. Studies have shown that pressure can preserve small grain size for a long time at the geological scale. The effective mechanism of pressure action is probably linked to the fact that pressure simultaneously favours dissolution at the grain-contact inducing a quartz supersaturation and prohibits the increase in size of reprecipitated microcrystalline quartz grains. This hypothesis is supported by other studies reported in the literature. The proposed model, which incorporates silica mineralogy and a precise calculation of aqueous silica activity, allows us to explain measured silica concentrations in the deep sedimentary solutions of the Dogger aquifers. In the Keuper brines, silica solubility can in most cases be explained by an equilibrium with either chalcedony or quartz. Another application of the present work is shown by an example, where we examined the importance of precisely evaluating the activity coefficient in basin characterisation, as the goal of reservoir characterisation is to describe the spatial distribution of petrophysical parameters such as porosity, permeability, and saturations.  相似文献   

Upcoming International Events     

Anne-Marie de Grosbois 《Environmental Geology》2007,52(6):1225-1230

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Impact of partial steps and momentum advection schemes in a global ocean circulation model at eddy-permitting resolution   总被引：4，自引：6，他引：4  

Barnier Bernard  Gurvan Madec  Thierry Penduff  Jean-Marc Molines  Anne-Marie Treguier  Julien Le Sommer  Aike Beckmann  Arne Biastoch  Claus Böning  Joachim Dengg  Corine Derval  Edmée Durand  Sergei Gulev  Elizabeth Remy  Claude Talandier  Sébastien Theetten  Mathew Maltrud  Julie McClean  Beverly De Cuevas 《Ocean Dynamics》2006,56(5-6):543-567

Series of sensitivity tests were performed with a z-coordinate, global eddy-permitting (1/4°) ocean/sea-ice model (the ORCA-R025 model configuration developed for the DRAKKAR project) to carefully evaluate the impact of recent state-of-the-art numerical schemes on model solutions. The combination of an energy–enstrophy conserving (EEN) scheme for momentum advection with a partial step (PS) representation of the bottom topography yields significant improvements in the mean circulation. Well known biases in the representation of western boundary currents, such as in the Atlantic the detachment of the Gulf Stream, the path of the North Atlantic Current, the location of the Confluence, and the strength of the Zapiola Eddy in the south Atlantic, are partly corrected. Similar improvements are found in the Pacific, Indian, and Southern Oceans, and characteristics of the mean flow are generally much closer to observations. Comparisons with other state-of-the-art models show that the ORCA-R025 configuration generally performs better at similar resolution. In addition, the model solution is often comparable to solutions obtained at 1/6 or 1/10° resolution in some aspects concerning mean flow patterns and distribution of eddy kinetic energy. Although the reasons for these improvements are not analyzed in detail in this paper, evidence is shown that the combination of EEN with PS reduces numerical noise near the bottom, which is likely to affect current–topography interactions in a systematic way. We conclude that significant corrections of the mean biases presently seen in general circulation model solutions at eddy-permitting resolution can still be expected from the development of numerical methods, which represent an alternative to increasing resolution.  相似文献