Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy          下载免费PDF全文

Luke Daly  Phil A. Bland  Svetlana Tessalina  David W. Saxey  Steven M. Reddy  Denis Fougerouse  William D.A. Rickard  Lucy V. Forman  Alexandre La Fontaine  Julie M. Cairney  Simon P. Ringer  Bruce F. Schaefer  Daniel Schwander 《Geostandards and Geoanalytical Research》2018,42(3):279-299

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   

Community-based responses to climate hazards: typology and global analysis     

Paterson  Barbara  Charles  Anthony 《Climatic change》2019,152(3-4):327-343

Climatic Change - The severity and frequency of climate change hazards are increasing around the world. Because the impacts are most acutely felt in local communities, it is critical to improve...  相似文献   

Modelling and mass balance assessments of nutrient retention in a seasonally-flowing estuary (Swan River Estuary,Western Australia)     

Barbara J. Robson  Paul A. Bukaveckas  David P. Hamilton 《Estuarine, Coastal and Shelf Science》2008

An integrated mass balance and modelling approach for analysis of estuarine nutrient fluxes is demonstrated in the Swan River Estuary, a microtidal system with strong hydrological dependence on seasonal river inflows. Mass balance components included estimation of gauged and ungauged inputs to the estuary and losses to the ocean (outflow and tidal exchange). Modelling components included estimation of atmospheric (N fixation, denitrification) and sediment–water column nutrient exchanges. Gross and net denitrification derived using two independent methods were significantly correlated (r² = 0.49, p < 0.01) with net rates averaging 40% of gross. Annual nitrogen (N) and phosphorus (P) loads from major tributaries were linearly correlated with annual freshwater discharge and were 3-fold higher in wet years than in dry years. Urban drains and groundwater contributed, on average, 26% of N inputs and 19% of P inputs, with higher relative contributions in years of low river discharge. Overall, ungauged inputs accounted for almost 35% of total nitrogen loads. For N, elevated loading in wet years was accompanied by large increases in outflow (7x) and tidal flushing (2x) losses and resulted in overall lower retention efficiency (31%) relative to dry years (70%). For P, tidal flushing losses were similar in wet and dry years, while outflow losses (4-fold higher) were comparable in magnitude to increases in loading. As a result, P retention within the estuary was not substantially affected by inter-annual variation in water and P loading (ca. 50% in all years). Sediment nutrient stores increased in most years (remineralisation efficiency ca. 50%), but sediment nutrient releases were significant and in some circumstances were a net source of nutrients to the water column.  相似文献   

Variation in style of magmatism and emplacement mechanism induced by changes in basin environments and stress fields (Pannonian Basin,Central Europe)     

Attila Petrik  Lszl Fodor  Lszl Bereczki  Zsombor Klembala  Rka Lukcs  Viktria Baranyi  Barbara Beke  Szabolcs Harangi 《Basin Research》2019,31(2):380-404

The development of high‐resolution 3D seismic cubes has permitted recognition of variable subvolcanic features mostly located in passive continental margins. Our study area is situated in a different tectonic setting, in the extensional Pannonian Basin system (central Europe) where the lithospheric extension was associated with a wide variety of magmatic suites during the Miocene. Our primary objective is to map the buried magmatic bodies, to better understand the temporal and spatial variation in the style of magmatism and emplacement mechanism within the first order Mid‐Hungarian Fault Zone (MHFZ) along which the substantial Miocene displacement took place. The combination of seismic, borehole and log data interpretation enabled us to delineate various previously unknown subvolcanic‐volcanic features. In addition, a new approach of neural network analysis on log data was applied to detect and quantitatively characterise hydrothermal mounds that are hard to interpret solely from seismic data. The volcanic activity started in the Middle Miocene and induced the development of extrusive volcanic mounds south of the NE‐SW trending, continuous strike‐slip fault zone (Hajdú Fault Zone). In the earliest Late Miocene (11.6–9.78 Ma), the style of magmatic activity changed resulting in emplacement of intrusions and development of hydrothermal mounds. Sill emplacement occurred from south‐east to north‐west based on primary flow‐emplacement structures. The time of sill emplacement and the development of hydrothermal mounds can be bracketed by onlapped forced folds and mounds. This time coincided with the acceleration of sedimentation producing poorly consolidated, water‐saturated sediments preventing magma from flowing to the paleosurface. The change in extensional direction resulted in change in fault pattern, thus the formerly continuous basin‐bounding strike‐slip fault became segmented which could facilitate the magma flow toward the basin centre.  相似文献   

Solar Microflares Observed by SphinX and RHESSI     

Tomasz Mrozek  Szymon Gburek  Marek Siarkowski  Barbara Sylwester  Janusz Sylwester  Anna Kepa  Magdalena Gryciuk 《Solar physics》2018,293(7):101

In 2009, the Russian Complex Orbital Observations Near-Earth of Activity of the Sun (CORONAS-Photon) spacecraft was launched, carrying the Polish Solar PHotometer In X-rays (SphinX). The SphinX was most sensitive in the spectral range 1.2?–?15 keV, thus an excellent opportunity appeared for comparison with the low-energy end of Ramaty High Energy Solar Spectroscopic Imager (RHESSI) spectra. Common spectral measurements with these instruments cover the range where most of the flare energy is accumulated. We have chosen four consecutive small solar events observed on 4 July 2009 at 13:43 UT, 13:48 UT, 13:52 UT, and 13:55 UT (RHESSI flare peak times) and used them to compare the data and results from the two instruments. Moreover, we included Geostationary Operational Environmental Satellite (GOES) records in our analysis. In practice, the range of comparison performed for SphinX and RHESSI is limited roughly to 3?–?6 keV. RHESSI fluxes measured with a use of one, four, and nine detectors in the 3?–?4 keV energy band agree with SphinX measurements. However, we observed that SphinX spectral irradiances are three times higher than those of RHESSI in the 4?–?6 keV energy band. This effect contributes to the difference in obtained emission measures, but the derived temperatures of plasma components are similar. RHESSI spectra were fitted using a model with two thermal components. We have found that the RHESSI hot component is in agreement with GOES, and the RHESSI hotter component fits the SphinX flaring component well. Moreover, we calculated the so-called thermodynamic measure and the total thermal energy content in the four microflares that we studied. The results obtained show that SphinX is a very sensitive complementary observatory for RHESSI and GOES.  相似文献   

How U.S. ocean policy and market power can reform the coral reef wildlife trade     

Brian N. Tissot  Barbara A. Best  Eric H. Borneman  Andrew W. Bruckner  Cara H. Cooper  Heather D’Agnes  Timothy P. Fitzgerald  Amanda Leland  Susan Lieberman  Amy Mathews Amos  Rashid Sumaila  Teresa M. Telecky  Frazer McGilvray  Brian J. Plankis  Andrew L. Rhyne  Glynnis G. Roberts  Benjamin Starkhouse  Todd C. Stevenson 《Marine Policy》2010

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.  相似文献   

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>     

Jaroslav Dudík  Elena Dzifčáková  Nicole Meyer-Vernet  Giulio Del Zanna  Peter R. Young  Alessandra Giunta  Barbara Sylwester  Janusz Sylwester  Mitsuo Oka  Helen E. Mason  Christian Vocks  Lorenzo Matteini  Säm Krucker  David R. Williams  Šimon Mackovjak 《Solar physics》2017,292(8):100

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.  相似文献   

Relict sand dredging for beach nourishment in the central Tyrrhenian Sea (Italy): effects on benthic assemblages     

Barbara La Porta  Monica Targusi  Loretta Lattanzi  Paola La Valle  Daniela Paganelli  & Luisa Nicoletti 《Marine Ecology》2009,30(S1):97-104

The aim of this study is to analyse the effects in space and time of relict sand-dredging activities on macrobenthic assemblages, in an area situated offshore Montalto di Castro (central Tyrrhenian Sea, Italy), and to analyse the recolonisation processes of macrobenthos in the dredged areas. The area in question is characterised by relict sand deposits (Holocenic paleo-beaches), used for beach nourishment along the Latium coast. The effects of sand extraction on benthic assemblages were investigated before, during and after three dredging operations. The sites analysed are located within the dredged areas (inside stations) and in neighbouring, not dredged, areas (outside stations). The results showed that the impact of sand extraction was confined to the dredged stations and to the areas in proximity to the dredged areas. During dredging activities, the structure of benthic assemblages within the impacted stations was characterised by low species richness and diversity. Both the direct removal of sediment and the re-suspension and consequent deposition of fine sediment affected benthic assemblages of the impacted stations. A few months after the dredgings, a recolonisation process was still observed at all the impacted stations. A gradual recolonisation process was observed at those stations affected by only one dredging, whereas a different recolonisation was observed at those stations affected by two dredgings over time. This study suggests that differences of re-colonisation processes of benthic assemblages are related to the intensity of dredging operations in terms of dredging frequency.  相似文献   

Vulnerabilities,competition and rights in a context of climate change toward equitable water governance in Peru's Rio Santa Valley     

Barbara Deutsch Lynch 《Global Environmental Change》2012,22(2):364-373

As glacial retreat changes the hydrology of Peru's Rio Santa, water demand is growing, pollution is worsening, and competition for water among economic sectors, political jurisdictions and upstream and downstream water users is intensifying. The vulnerability of highland communities, food producers, and poor urban neighborhoods in the Santa watershed in the face of these changes is magnified by inequities in water governance, giving rise to water conflict. Peru's new water regime defines water as an economic good and seeks to centralize control over water. This article analyzes implications of this regime for ensuring equity and managing conflict. It concludes that Peru's water regime is more likely to address equity issues when faced with concerted citizen action.  相似文献   

Palaeo-environmental and dietary analysis of intestinal contents of a mammoth calf (Yamal Peninsula,northwest Siberia)     

Bas van Geel  Daniel C. Fisher  Adam N. Rountrey  Jan van Arkel  Joost F. Duivenvoorden  Aline M. Nieman  Guido B.A. van Reenen  Alexei N. Tikhonov  Bernard Buigues  Barbara Gravendeel 《Quaternary Science Reviews》2011,30(27-28):3935-3946

Intestinal samples from the one-month-old Siberian mammoth calf ‘Lyuba’ were studied using light microscopy and ancient DNA to reconstruct its palaeo-environment and diet. The palynological record indicates a ‘mammoth steppe’. At least some pollen of arboreal taxa was reworked, and thus the presence of trees on the landscape is uncertain. In addition to visual comparison of 11 microfossil spectra, a PCA analysis contributed to diet reconstruction. This yielded two clusters: one of samples from the small intestine and the other of large-intestine samples, indicating compositional differences in food remains along the intestinal tract, possibly reflecting different episodes of ingestion. Based on observed morphological damage we conclude that the cyperaceous plant remains and some remains of dwarf willows were originally eaten by a mature mammoth, most likely Lyuba’s mother. The mammoth calf probably unintentionally swallowed well-preserved mosses and mineral particles while eating fecal material deposited on a soil surface covered with mosses. Coprophagy may have been a common habit for mammoths, and we therefore propose that fecal material should not be used to infer season of death of mammoths. DNA sequences of trnL and rbcL genes amplified from ancient DNA extracted from intestinal samples confirmed and supplemented plant identifications based on microfossils and macro-remains. Results from different extraction methods and barcoding markers complemented each other and show the value of longer protocols in addition to fast and commercially available extraction kits.  相似文献