Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process     

K. G. Heumann  G. Rdlinger  M. Erbes  I. Heiber  U. Obst  Z. Filip  H. Claus 《洁净——土壤、空气、水》2000,28(4):193-201

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.  相似文献   

Coordinated Ocean-ice Reference Experiments (COREs)     

Stephen M. Griffies  Arne Biastoch  Claus Böning  Frank Bryan  Gokhan Danabasoglu  Eric P. Chassignet  Matthew H. England  Rüdiger Gerdes  Helmuth Haak  Robert W. Hallberg  Wilco Hazeleger  Johann Jungclaus  William G. Large  Gurvan Madec  Anna Pirani  Bonita L. Samuels  Markus Scheinert  Alex Sen Gupta  Camiel A. Severijns  Harper L. Simmons  Jianjun Yin 《Ocean Modelling》2009,26(1-2):1-46

Coordinated Ocean-ice Reference Experiments (COREs) are presented as a tool to explore the behaviour of global ocean-ice models under forcing from a common atmospheric dataset. We highlight issues arising when designing coupled global ocean and sea ice experiments, such as difficulties formulating a consistent forcing methodology and experimental protocol. Particular focus is given to the hydrological forcing, the details of which are key to realizing simulations with stable meridional overturning circulations.The atmospheric forcing from [Large, W., Yeager, S., 2004. Diurnal to decadal global forcing for ocean and sea-ice models: the data sets and flux climatologies. NCAR Technical Note: NCAR/TN-460+STR. CGD Division of the National Center for Atmospheric Research] was developed for coupled-ocean and sea ice models. We found it to be suitable for our purposes, even though its evaluation originally focussed more on the ocean than on the sea-ice. Simulations with this atmospheric forcing are presented from seven global ocean-ice models using the CORE-I design (repeating annual cycle of atmospheric forcing for 500 years). These simulations test the hypothesis that global ocean-ice models run under the same atmospheric state produce qualitatively similar simulations. The validity of this hypothesis is shown to depend on the chosen diagnostic. The CORE simulations provide feedback to the fidelity of the atmospheric forcing and model configuration, with identification of biases promoting avenues for forcing dataset and/or model development.  相似文献   

Volcanic stratigraphy of a high-altitude Mammuthus columbi (Tlacotenco,Sierra Chichinautzin), Central México     

Marie-Noelle Guilbaud  Lilia Arana-Salinas  Claus Siebe  Luis Alberto Barba-Pingarrón  Agustín Ortiz 《Bulletin of Volcanology》2015,77(3):1-16

  相似文献   

A high-resolution stellar library for evolutionary population synthesis     

Lucimara P. Martins  Rosa M. González Delgado  Claus Leitherer  Miguel Cerviño  Peter Hauschildt 《Monthly notices of the Royal Astronomical Society》2005,358(1):49-65

We present a library of 1654 high-resolution stellar spectra, with a sampling of 0.3 Å and covering the wavelength range from 3000 to 7000 Å. The library was computed with the latest improvements in stellar atmospheres, incorporating non-local thermodynamic equilibrium (non-LTE) line-blanketed models for hot, massive  ( T _eff≥ 27 500 K)  and line-blanketed models for cool  (3000 ≤ T _eff≤ 4500 K)  stars. The total coverage of the grid is  3000 K ≤ T _eff≤ 55 000 K  and  −0.5 ≤ log g ≤ 5.5  , for four chemical abundance values: twice solar, solar, half solar and 1/10 solar. Evolutionary synthesis models using this library are presented in a companion paper. We tested the general behaviour of the library by calculating and comparing equivalent widths of numerous H and He  i lines, and some of the commonly used metallic indices. We also compared the library with the empirical libraries STELIB and Indo-US. The full set of the synthetic stellar spectra is available from our websites ( http://www.iaa.csic.es/~rosa and http://www.astro.iag.usp.br/~lucimara/library.htm ).  相似文献   

南极中山站至Dome A剖面表面雪样氧同位素组成          下载免费PDF全文

阎明  李院生  谭德军  温家洪  汪大立  Claus U.Hammer  孙波  康建成  刘雷保 《极地研究》2001,13(3):159-164

运用质谱技术 ,测定了南极中山站至 Dome A剖面 1 998/1 999年度表面雪样氧同位素组成。结果表明 ,表面雪样氧同位素组成变化范围相当大 (- 2 2 .5 1‰ - - 5 0 .6 7‰ ) ,且具有随距中山站距离逐渐增大、海拔高度逐渐增加而逐渐减小的趋势。线性回归分析显示表面雪样氧同位素组成与距中山站距离、海拔高度和纬度存在着很好的相关性 ,这实际上反映出稳定同位素组成和温度之间的密切联系  相似文献   

“Galileo Galilei” (GG) a small satellite to test the equivalence principle of Galileo, Newton and Einstein     

Anna M. Nobili  Gian Luca Comandi  Suresh Doravari  Donato Bramanti  Rajeev Kumar  Francesco Maccarrone  Erseo Polacco  Slava G. Turyshev  Michael Shao  John Lipa  Hansjoerg Dittus  Claus Laemmerzhal  Achim Peters  Jurgen Mueller  C. S. Unnikrishnan  Ian W. Roxburgh  Alain Brillet  Christian Marchal  Jun Luo  Jozef van der Ha  Vadim Milyukov  Valerio Iafolla  David Lucchesi  Paolo Tortora  Paolo De Bernardis  Federico Palmonari  Sergio Focardi  Dino Zanello  Salvatore Monaco  Giovanni Mengali  Luciano Anselmo  Lorenzo Iorio  Zoran Knezevic 《Experimental Astronomy》2009,23(2):689-710

“Galileo Galilei” (GG) is a small satellite designed to fly in low Earth orbit with the goal of testing the Equivalence Principle—which is at the basis of the General Theory of Relativity—to 1 part in 10¹⁷. If successful, it would improve current laboratory results by 4 orders of magnitude. A confirmation would strongly constrain theories; proof of violation is believed to lead to a scientific revolution. The experiment design allows it to be carried out at ambient temperature inside a small 1-axis stabilized satellite (250 kg total mass). GG is under investigation at Phase A-2 level by ASI (Agenzia Spaziale Italiana) at Thales Alenia Space in Torino, while a laboratory prototype (known as GGG) is operational at INFN laboratories in Pisa, supported by INFN (Istituto Nazionale di fisica Nucleare) and ASI. A final study report will be published in 2009.  相似文献   

P_n anisotropy studies in northern Britain and the eastern and western United States     

David Bamford  Martin Jentsch  Claus Prodehl 《Geophysical Journal International》1979,57(2):397-429

Summary. Available seismic refraction data from three different continental areas, northern Britain and the eastern and western United States, has been studied for possible P_n , velocity anisotropy using the methods described by Bamford. There are various deficiencies in the time—distance data used in each case but, while the uppermost mantle beneath northern Britain and the eastern United States seems to be isotropic within the limits of measurement error, there is a small but significant anisotropy beneath the western United States.
Both the amount (up to 3 per cent) and the direction (70–80° east of north) of this anisotropy are very similar to the results obtained in the Pacific Ocean off California. We tentatively conclude that this anisotropy is present as a consequence of the subduction of oceanic lithosphere beneath the western United States.  相似文献   

Impact of partial steps and momentum advection schemes in a global ocean circulation model at eddy-permitting resolution   总被引：4，自引：6，他引：4  

Barnier Bernard  Gurvan Madec  Thierry Penduff  Jean-Marc Molines  Anne-Marie Treguier  Julien Le Sommer  Aike Beckmann  Arne Biastoch  Claus Böning  Joachim Dengg  Corine Derval  Edmée Durand  Sergei Gulev  Elizabeth Remy  Claude Talandier  Sébastien Theetten  Mathew Maltrud  Julie McClean  Beverly De Cuevas 《Ocean Dynamics》2006,56(5-6):543-567

Series of sensitivity tests were performed with a z-coordinate, global eddy-permitting (1/4°) ocean/sea-ice model (the ORCA-R025 model configuration developed for the DRAKKAR project) to carefully evaluate the impact of recent state-of-the-art numerical schemes on model solutions. The combination of an energy–enstrophy conserving (EEN) scheme for momentum advection with a partial step (PS) representation of the bottom topography yields significant improvements in the mean circulation. Well known biases in the representation of western boundary currents, such as in the Atlantic the detachment of the Gulf Stream, the path of the North Atlantic Current, the location of the Confluence, and the strength of the Zapiola Eddy in the south Atlantic, are partly corrected. Similar improvements are found in the Pacific, Indian, and Southern Oceans, and characteristics of the mean flow are generally much closer to observations. Comparisons with other state-of-the-art models show that the ORCA-R025 configuration generally performs better at similar resolution. In addition, the model solution is often comparable to solutions obtained at 1/6 or 1/10° resolution in some aspects concerning mean flow patterns and distribution of eddy kinetic energy. Although the reasons for these improvements are not analyzed in detail in this paper, evidence is shown that the combination of EEN with PS reduces numerical noise near the bottom, which is likely to affect current–topography interactions in a systematic way. We conclude that significant corrections of the mean biases presently seen in general circulation model solutions at eddy-permitting resolution can still be expected from the development of numerical methods, which represent an alternative to increasing resolution.  相似文献   

Aspects of the structural evolution of the Lusitanian Basin in Portugal and the shelf and slope area offshore Portugal     

Erik S. Rasmussen  Steen Lomholt  Claus Andersen  Ole V. Vejbk 《Tectonophysics》1998,300(1-4):199-225

The study provides a regional seismic interpretation and mapping of the Mesozoic and Cenozoic succession of the Lusitanian Basin and the shelf and slope area off Portugal. The seismic study is compared with previous studies of the Lusitanian Basin. From the Late Triassic to the Cretaceous the study area experienced four rift phases and intermittent periods of tectonic quiescence. The Triassic rifting was concentrated in the central part of the Lusitanian Basin and in the southernmost part of the study area, both as symmetrical grabens and half-grabens. The evolution of half-grabens was particularly prominent in the south. The Triassic fault-controlled subsidence ceased during the latest Late Triassic and was succeeded by regional subsidence during the early Early Jurassic (Hettangian) when deposition of evaporites took place. A second rift phase was initiated in the Early Jurassic, most likely during the Sinemurian–Pliensbachian. This resulted in minor salt movements along the most prominent faults. The second phase was concentrated to the area south of the Nazare Fault Zone and resulted here in the accumulation of a thick Sinemurian–Callovian succession. Following a major hiatus, probably as a result of the opening of the Central Atlantic, resumed deposition occurred during the Late Jurassic. Evidence for Late Jurassic fault-controlled subsidence is widespread over the whole basin. The pattern of Late Jurassic subsidence appears to change across the Nazare Fault Zone. North of the Nazare Fault, fault-controlled subsidence occurred mainly along NNW–SSE-trending faults and to the south of this fault zone a NNE–SSW fault pattern seems to dominate. The Oxfordian rift phase is testified in onlapping of the Oxfordian succession on salt pillows which formed in association with fault activity. The fourth and final rift phase was in the latest Late Jurassic or earliest Early Cretaceous. The Jurassic extensional tectonism resulted in triggering of salt movement and the development of salt structures along fault zones. However, only salt pillow development can be demonstrated. The extensional tectonics ceased during the Early Cretaceous. During most of the Cretaceous, regional subsidence occurred, resulting in the deposition of a uniform Lower and Upper Cretaceous succession. Marked inversion of former normal faults, particularly along NE–SW-trending faults, and development of salt diapirs occurred during the Middle Miocene, probably followed by tectonic pulses during the Late Miocene to present. The inversion was most prominent in the central and southern parts of the study area. In between these two areas affected by structural inversion, fault-controlled subsidence resulted in the formation of the Cenozoic Lower Tagus Basin. Northwest of the Nazare Fault Zone the effect of the compressional tectonic regime quickly dies out and extensional tectonic environment seems to have prevailed. The Miocene compressional stress was mainly oriented NW–SE shifting to more N–S in the southern part.  相似文献   

On the hydrodynamics of flotation machines     

Heinrich Schubert  Claus Bischofberger 《International Journal of Mineral Processing》1978,5(2):131-142

Flotation is realized under highly turbulent flow conditions, so that turbulence may be process-determining, too. Because the principles of turbulent multi-phase flow have still not been fully worked out, one needs integral quantities to characterize the state of turbulence indirectly.To show the hydrodynamic conditions diagrams are introduced in which the power intensity $\text{P}\text{V}{}_{\mathrm{<mtext>t</mtext>}}$ is a function of air flow number c_L; impeller rotational speed n and specific air rate q_L are additional parameters. Diagrams of this kind are also useful for the characterization of the optimum operation conditions. For the flotation of different particle sizes the realization of closely defined power inputs is an important condition to obtain an optimum recovery.  相似文献