Quantification of river water infiltration in shallow aquifers using acesulfame and anthropogenic gadolinium          下载免费PDF全文

Andrea Bichler  Christian Muellegger  Robert Brünjes  Thilo Hofmann 《水文研究》2016,30(11):1742-1756

This study has investigated the use of the artificial sweetener acesulfame and the magnetic resonance imaging contrast agent gadolinium as quantitative tracers for river water infiltration into shallow groundwater. The influence of a river on alluvial groundwater in a subalpine catchment in western Europe has been assessed using the ‘classical’ hydrochemical tracer chloride and the trace contaminants acesulfame and anthropogenic gadolinium. Mixing ratios for riverine bank filtrate with ambient groundwater and the uncertainties associated with the temporal and spatial tracer variability were calculated using acesulfame and gadolinium and compared with those obtained using chloride. The temporal variability of tracer concentrations in river water of gadolinium (standard deviation SD: 63%) and acesulfame (SD: 71%) both exceeded that of chloride (SD: 27%), and this was identified as the main source of uncertainty in the mixing analysis. Similar spatial distributions were detected in the groundwater for chloride and gadolinium, but not for acesulfame. Mixing analyses using acesulfame resulted in calculated mixing ratios that differed from those obtained using gadolinium and chloride by up to 83% and 92%, respectively. At the investigated site, which had oxic conditions and moderate temperatures, acesulfame was found to be a less reliable tracer than either gadolinium or chloride, probably because of natural attenuation and input from other sources. There was no statistically significant difference between the mixing ratios obtained using chloride or gadolinium, the mixing ratios obtained using gadolinium were 40–50% lower than those obtained using chloride. This is mainly due to a bias of the mean gadolinium concentration in river water towards higher values. In view of the uncertainties of the two tracers, neither could be preferred over the other for the quantification of bank filtrate in groundwater. At this specific site gadolinium was able to reliably identify river water infiltration and was a more precise tracer than chloride at low mixing ratios (<20%), because of the exclusive occurrence of gadolinium in river water and its high dynamic range. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Mauer – the type site of Homo heidelbergensis: palaeoenvironment and age     

Günther A. Wagner  Lutz Christian Maul  Manfred Löscher  H. Dieter Schreiber 《Quaternary Science Reviews》2011,30(11-12):1464-1473

The mandible of Homo heidelbergensis was found 1907 in the sand pit Grafenrain at Mauer in coarse fluvial sands 24 m below the surface, deposited in a former course of the Neckar River. These ‘Mauer sands’ are overlain by a series of glacial-climate loess deposits with intercalated interglacial palaeosols, which can be correlated with Quaternary climate history, thus indicating an early Middle Pleistocene age for H. heidelbergensis. The ‘Mauer sands’ are famous for their rather rich mammal fauna, which clearly indicates interglacial climate conditions. The faunal evidence – in particular the micromammals – place the ‘Mauer sands’ into MIS 15 or MIS 13 although most stratigraphic arguments favour correlation to MIS 15 and therefore to an age of ca 600 ka.  相似文献   

Shallow sediment deformation styles in north-western Campeche Knolls,Gulf of Mexico and their controls on the occurrence of hydrocarbon seepage     

Feng Ding  Volkhard Spiess  Ian R. MacDonald  Markus Brüning  Noemi Fekete  Gerhard Bohrmann 《Marine and Petroleum Geology》2010,27(4):959-972

During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth.  相似文献   

Damaging hailstorms in South Moravia,Czech Republic,in the seventeenth to twentieth centuries as derived from taxation records     

Rudolf Brázdil  Kateřina Chromá  Hubert Valášek  Lukáš Dolák  Ladislava Řezníčková 《Theoretical and Applied Climatology》2016,123(1-2):185-198

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An approach for estimating time-variable rates from geodetic time series   总被引：1，自引：0，他引：1  

Olga Didova  Brian Gunter  Riccardo Riva  Roland Klees  Lutz Roese-Koerner 《Journal of Geodesy》2016,90(11):1207-1221

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Forecasting rock slope failure: how reliable and effective are warning systems?     

Martina?S?tteleEmail author  Michael?Krautblatter  Michael?Bründl  Daniel?Straub 《Landslides》2016,13(4):737-750

Warning systems are increasingly applied to reduce damage caused by different magnitudes of rockslides and rockfalls. In an integrated risk-management approach, the optimal risk mitigation strategy is identified by comparing the achieved effectiveness and cost; estimating the reliability of the warning system is the basis for such considerations. Here, we calculate the reliability and effectiveness of the warning system installed in Preonzo prior to a major rockfall in May 2012. “Reliability” is defined as the ability of the warning system to forecast the hazard event and to prevent damage. To be cost-effective, the warning system should forecast an event with a limited number of false alarms to avoid unnecessary costs for intervention measures. The analysis shows that to be reliable, warning systems should be designed as fail-safe constructions. They should incorporate components with low failure probabilities, high redundancy, have low warning thresholds, and additional control systems. In addition, the experts operating the warning system should have limited risk tolerance. In an additional hypothetical probabilistic analysis, we investigate the effect of the risk attitude of the decision makers and of the number of sensors on the probability of detecting the event and initiating a timely evacuation, as well as on the related intervention cost. The analysis demonstrates that quantitative assessments can support the identification of optimal warning system designs and decision criteria.  相似文献   

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis          下载免费PDF全文

Lutz Nasdala  Fernando Corfu  John W. Valley  Michael J. Spicuzza  Fu‐Yuan Wu  Qiu‐Li Li  Yue‐Heng Yang  Chris Fisher  Carsten Münker  Allen K. Kennedy  Peter W. Reiners  Andreas Kronz  Michael Wiedenbeck  Richard Wirth  Chutimun Chanmuang  Manuela Zeug  Tamás Váczi  Nicholas Norberg  Tobias Häger  Alfred Kröner  Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   

Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism     

Höhn  Stefan  Koglin  Nikola  Klopf  Lisa  Schüssler  Ulrich  Tragelehn  Harald  Frimmel  Hartwig E.  Zeh  Armin  Brätz  Helene 《International Journal of Earth Sciences》2018,107(1):359-377

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...  相似文献   

Causes and consequences of long-term groundwater overabstraction in Jordan     

Brückner  Florian  Bahls  Rebecca  Alqadi  Mohammad  Lindenmaier  Falk  Hamdan  Ibraheem  Alhiyari  Mohammad  Atieh  Ala’a 《Hydrogeology Journal》2021,29(8):2789-2802

Hydrogeology Journal - In 2017, a comprehensive review of groundwater resources in Jordan was carried out for the first time since 1995. The change in groundwater levels between 1995 and 2017 was...  相似文献   

Heterogeneity of melts in impact deposits and implications for their origin (Ries suevite,Germany)     

Susann Siegert  Lutz Hecht 《Meteoritics & planetary science》2019,54(10):2409-2447

Impact melt‐bearing clastic deposits (suevites) are one of the most important records of the impact cratering process. A deeper understanding of their composition and formation is therefore essential. This study focuses on impact melt particles in suevite at Ries, Germany. Textures and chemical evidence indicate that the suevite contains three melt types that originate from different shock levels in the target. The most abundant melt type (“melt type 1”) represents well‐mixed whole‐rock melting of crystalline basement and includes incompletely mixed mafic melt schlieren (“melt type 1 mafic”). Polymineralic melt type 2 comprises mixes between monomineralic melt types 3 and melt type 1. Melt types 2 and 3 are located within melt type 1 as small patches or schlieren but also isolated within the suevite matrix. The main melt type 1 is heterogeneous with respect to trace elements, varying geographically around the crater: in the western sector, it has lower values in trace elements, e.g., Ba, Zr, Th, and Ce, than in the eastern sector. The west–east zoning likely reflects the heterogeneous nature of crystalline basement target rocks with lower trace element contents, e.g., Ba, Zr, Th, and Ce, in the west compared to the east. The chemical zoning pattern of suevite melt type 1 indicates that mixing during ejection and emplacement occurred only on a local (hundreds of meters) scale. The incomplete larger scale mixing indicated by the preservation of these local chemical signatures, and schlieren corroborate the assumption that mixing, ejection, and quenching were very rapid, short‐lived processes.  相似文献