Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

HELCOM Baltic Sea Action Plan - A regional programme of measures for the marine environment based on the Ecosystem Approach   总被引：1，自引：0，他引：1  

Hermanni Backer  Juha-Markku Leppänen  Kaj Forsius  Jukka Mehtonen  Minna Pyhälä  Hanna Paulomäki  Tarja Haaranen 《Marine pollution bulletin》2010,60(5):642-649

The Helsinki Commission (HELCOM) Baltic Sea Action Plan, adopted by the coastal countries of the Baltic Sea and the European Community in November 2007, is a regional intergovernmental programme of measures for the protection and management of the marine environment explicitly based on the Ecosystem Approach. The Action Plan is structured around a set of Ecological Objectives used to define indicators and targets, including effect-based nutrient input ceilings, and to monitor implementation. The Action Plan strongly links Baltic marine environmental concerns to important socio-economic fields such as agriculture and fisheries and promotes cross-sectoral tools including marine spatial planning. Due to complementarities with the European Union (EU) Marine Strategy Framework Directive, the Action Plan is in essence a pilot for this process without neglecting the important role of the Russian Federation - the only Baltic coastal country not a member of the EU.  相似文献   

Kandidater udgået fra Københavns Universitets Geografiske Institut 1966–71     

Viggo Hansen  Niels Nielsen  Ruth Helkiær Jensen  Kaf Hansen  Kaj Hansen  Johannes Krüger 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(1):91-100

Christensen, Leif: Faststående og omlejrede Saale-morånelersaflejringer. Et eksempel fra Szdding-området, Vestjylland. Geografisk Tidsskrift 82: 91–94. Copenhagen, Dec. 1, 1982.

In situ clayey till materials on the Skovbjerg Bakkea, western Jutland can be recognized by crop-marks revealing pseudomorphs of ice-wedge polygons in orthogonal, random orthogonal and hexagonal patterns. The tills inside these polygonal patterns have high shear-strength values as measured by vane tests. Remoulded fossil solifluction deposits of till origin reveal stripes and deformed polygonal patterns in the crops. High strength as measured by vane are encountered below fossil solifluction deposits 4 meters below ground.  相似文献   

Anmeldelser     

Niels Nielsen  Viggo Hansen  Kaj Hansen  Kr. M. Jensen  Sten Folving  Sofus Christiansen 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(1):101-118

Meyer, Marlene: Settlement Patterns and Land-use in Northern Ghana—A Study of the Changes during the period 1963–1991 based on Historical Surveys and recent SPOT-images. Geografisk Tidsskrift 92:101–104. Copenhagen 1992.

A study by Hunter (1966) describes how large areas along the Red Volta River bank, have been abandoned due to river blindness. The mapping of current land-use status and settlements patterns, using multispectral SPOT-satellite images, shows how the border of settlements continue to retreat, whereas new land is being reclaimed for bush fields in the abandoned areas.  相似文献   

Hafnium isotopic variations in East Atlantic intraplate volcanism     

Jörg Geldmacher  Kaj Hoernle  Barry B. Hanan  Janne Blichert-Toft  F. Hauff  James B. Gill  Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》2011,162(1):21-36

The broad belt of intraplate volcanism in the East Atlantic between 25° and 37° N is proposed to have formed by two adjacent hotspot tracks (the Madeira and Canary tracks) that possess systematically different isotopic signatures reflecting different mantle source compositions. To test this model, Hf isotope ratios from volcanic rocks from all individual islands and all major seamounts are presented in this study. In comparison with published Nd isotope variations (6 εNd units), ¹⁷⁶Hf/¹⁷⁷Hf ratios span a much larger range (14 εHf units). Samples from the proposed Madeira hotspot track have the most radiogenic Hf isotopic compositions (¹⁷⁶Hf/¹⁷⁷Hf_m up to 0.283335), extending across the entire field for central Atlantic MORB. They form a relatively narrow, elongated trend on the Nd vs. Hf isotope diagram (stretching over > 10 εHf units) between a depleted N-MORB-like endmember and a moderately enriched composition located on, or slightly below, the Nd–Hf mantle array, which overlaps the proposed “C” mantle component of Hanan and Graham (1996). In contrast, all samples from the Canary hotspot track plot below the mantle array (¹⁷⁶Hf/¹⁷⁷Hf_m = 0.282943–0.283067) and form a much denser cluster with less compositional variation (~4 εHf units). The cluster falls between (1) a low Hf isotope HIMU-like endmember, (2) a more depleted composition, and (3) the moderately enriched end of the Madeira trend. The new Hf isotope data confirm the general geochemical distinction of the Canary and Madeira domains in the East Atlantic. Both domains, however, seem to share a common, moderately enriched endmember that has “C”-like isotope compositions and is believed to represent subducted, <1-Ga-old oceanic lithosphere (oceanic crust and possibly minor sediment addition). The lower ¹⁷⁶Hf/¹⁷⁷Hf ratio of the enriched, HIMU-like Canary domain endmember indicates the contribution of oceanic lithosphere with somewhat older recycling ages of ≥1 Ga.  相似文献   

预测细粒酒精模型冰物理和力学参数的实验关系     

李志军  RISKA Kaj 《海洋与湖沼》2001,32(2):221-224

依据模型冰物理性质控制其力学性质的原则 ,利用能量平衡观点建立了冰内未冻结液体含量同制冰过程中的冰池温度、降温及升温时间、模型冰厚度 (喷雾时间×流量 )的理论关系 ,以其量纲表达式作为预测模型冰物理和力学参数的综合控制指标 ;通过系统测量酒精溶液冰点温度、冰池大厅气温、模型冰温度、冰内未冻液含量、冰密度、冰压缩强度、冰弯曲强度和冰变形模量 ,获得了不同冰点温度模型冰的物理和力学参数同该综合控制指标的实验关系 ;实现了用人为可控制因子定量控制模型冰物理和力学参数的目的  相似文献   

Source components of the Gran Canaria (Canary Islands) shield stage magmas: evidence from olivine composition and Sr–Nd–Pb isotopes     

Andrey A. Gurenko  Kaj A. Hoernle  Alexander V. Sobolev  Folkmar Hauff  Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》2010,159(5):689-702

The Canary Island primitive basaltic magmas are thought to be derived from an HIMU-type upwelling mantle containing isotopically depleted (NMORB)-type component having interacted with an enriched (EM)-type component, the origin of which is still a subject of debate. We studied the relationships between Ni, Mn and Ca concentrations in olivine phenocrysts (85.6–90.0 mol.% Fo, 1,722–3,915 ppm Ni, 1,085–1,552 ppm Mn, 1,222–3,002 ppm Ca) from the most primitive subaerial and ODP Leg 157 high-silica (picritic to olivine basaltic) lavas with their bulk rock Sr–Nd–Pb isotope compositions (⁸⁷Sr/⁸⁶Sr = 0.70315–0.70331, ¹⁴³Nd/¹⁴⁴Nd = 0.51288–0.51292, ²⁰⁶Pb/²⁰⁴Pb = 19.55–19.93, ²⁰⁷Pb/²⁰⁴Pb = 15.60–15.63, ²⁰⁸Pb/²⁰⁴Pb = 39.31–39.69). Our data point toward the presence of both a peridotitic and a pyroxenitic component in the magma source. Using the model (Sobolev et al. in: Science 316:412–417, 2007) in which the reaction of Si-rich melts originated during partial melting of eclogite (a high pressure product of subducted oceanic crust) with ambient peridotitic mantle forms olivine-free reaction pyroxenite, we obtain an end member composition for peridotite with ⁸⁷Sr/⁸⁶Sr = 0.70337, ¹⁴³Nd/¹⁴⁴Nd = 0.51291, ²⁰⁶Pb/²⁰⁴Pb = 19.36, ²⁰⁷Pb/²⁰⁴Pb = 15.61 and ²⁰⁸Pb/²⁰⁴Pb = 39.07 (EM-type end member), and pyroxenite with ⁸⁷Sr/⁸⁶Sr = 0.70309, ¹⁴³Nd/¹⁴⁴Nd = 0.51289, ²⁰⁶Pb/²⁰⁴Pb = 20.03, ²⁰⁷Pb/²⁰⁴Pb = 15.62 and ²⁰⁸Pb/²⁰⁴Pb = 39.84 (HIMU-type end member). Mixing of melts from these end members in proportions ranging from 70% peridotite and 30% pyroxenite to 28% peridotite and 72% pyroxenite derived melt fractions can generate the compositions of the most primitive Gran Canaria shield stage lavas. Combining our results with those from the low-silica rocks from the western Canary Islands (Gurenko et al. EPSL 277:514–524, 2009), at least four distinct components are required. We propose that they are (1) HIMU-type pyroxenitic component (representing recycled ocean crust of intermediate age) from the plume center, (2) HIMU-type peridotitic component (ancient recycled ocean crust stirred into the ambient mantle) from the plume margin, (3) depleted, MORB-type pyroxenitic component (young recycled oceanic crust) in the upper mantle entrained by the plume, and (4) EM-type peridotitic component from the asthenosphere or lithosphere above the plume center.  相似文献   

Importance of diffuse nutrient loading and lake level changes to the eutrophication of an originally oligotrophic boreal lake: a palaeolimnological diatom and chironomid analysis     

Jarmo J. Meriläinen  Juhani Hynynen  Arja Palomäki  Pasi Reinikainen  Anssi Teppo  Kaj Granberg 《Journal of Paleolimnology》2000,24(3):251-270

The recent environmental history of Lake Lappajärvi in western Finland (63°00 N, 23°30 E, area 149 km²), a humic, brown water lake with an average phosphorus content of ca. 20 g l^–1, was studied from short core sediment samples taken from the two main basins of the lake. Based on the stratigraphy of diatoms and chironomids and the sediment quality it was possible to distinguish four developmental stages during the past century: (1) a pre-industrial stage covering the time up to about 1935; (2) a stage of increasing nutrient loading (ca. 1936–1960); (3) a stage of pronounced erosion from lake level regulation and extensive ditching of the catchment area (ca. 1960–1970); and (4) a meso-eutrophic stage from ca. 1970 onwards.Acidophilous Aulacoseira distans coll. and other species typical of dystrophic, nutrient-poor lakes characterized the diatom assemblages during the first stage, and the profundal zoobenthic assemblages, characterized by Heterotrissocladius subpilosus and Micropsectra, indicated good hypolimnetic oxygen conditions and a low sedimentation of organic matter (approx. less than 50 g m^–2 a^–1). The increased loading rapidly led to changes both in diatoms and chironomids (e.g., to an early extinction of H. subpilosus in the 1950s). The process finally led to eutrophication with a successive proliferation of diatom species such as Asterionella formosa followed by Aulacoseira ambigua, Fragilaria crotonensis, and finally Melosira varians. The relative proportion of alkaliphilous species reached a maximum in the final stage and the original profundal chironomid fauna was replaced by Chironomus anthracinus gr. and C. plumosus which are typical of profundal areas suffering from temporal oxygen deficit. It is notable that the considerable decrease in waste water loading from the point sources (80–86% ) during the past two decades has not led to a recovery in the lake. This highlights the importance of diffuse loading from agriculture, forestry and other human activities even to this comparatively large lake.  相似文献   

The age of Earth’s largest volcano: Tamu Massif on Shatsky Rise (northwest Pacific Ocean)   总被引：1，自引：0，他引：1  

Jörg Geldmacher  Paul van den Bogaard  Ken Heydolph  Kaj Hoernle 《International Journal of Earth Sciences》2014,103(8):2351-2357

This study presents laser step-heating ⁴⁰Ar/³⁹Ar age determinations of basaltic lava samples from Tamu Massif, the oldest and largest edifice of the submarine Shatsky Rise in the northwest Pacific and Earth’s proposed largest volcano. The rocks were recovered during Integrated Ocean Drilling Program Expedition 324, which cored 160 m into the igneous basement near the summit of Tamu Massif. The analyzed lavas cover all three major stratigraphic groups penetrated at this site and confirm a Late Jurassic/Early Cretaceous age for the onset of Shatsky Rise volcanism. Lavas analyzed from the lower and middle section of the hole yield plateau ages between 144.4 ± 1.0 and 143.1 ± 3.3 Ma with overlapping analytical errors (2σ), whereas a sample from the uppermost lava group produced a significantly younger age of 133.9 ± 2.3 Ma suggesting a late or rejuvenated phase of volcanism. The new geochronological data infer minimum (average) melt production rates of 0.63–0.84 km³/a over a time interval of 3–4 million years consistent with the presence of a mantle plume.  相似文献   

Optical Changes in a Eutrophic Estuary During Reduced Nutrient Loadings     

Troels Møller Pedersen  Kaj Sand-Jensen  Stiig Markager  Søren Laurentius Nielsen 《Estuaries and Coasts》2014,37(4):880-892

Loss of water clarity is one of the consequences of coastal eutrophication. Efforts have therefore been made to reduce external nutrient loadings of coastal waters. This paper documents improvements to water clarity between 1985 and 2008–2009 at four stations in the microtidal estuary Roskilde Fjord and find significant relationships to freshwater nutrient loadings. The paper then investigates to which extent changes in phytoplankton biomass (chlorophyll a (Chl a)), non-algal particulate organic matter (POM*), and residual attenuation in the water (K _b), respectively, can account for this optical improvement. Vertical light attenuation (K _d) declined, on average, by 34 %, accompanying a 71 % reduction of Chl a and an 80 % reduction of POM*. Residual attenuation declined by 26 % over the period in accordance with a measured 34 % decline of dissolved organic nitrogen. Analysis of simultaneous changes in light attenuation and Secchi depth also suggested a reduction of the scatter-to-absorption ratio over time. Considering the stronger reductions of particle concentrations than dissolved organic matter, the contribution of residual attenuation to vertical attenuation increased from 54 to 74 % in 1985 to 78 to 85 % in 2008–2009. Overall, efforts to reduce nutrient loading and improve water clarity appeared to have had a larger impact on POM* than on Chl a and colored dissolved organic matter concentrations in the estuary, which can account for the decrease in the scatter-to-absorption ratio. These optical changes lead to larger improvements of Secchi depth than of vertical light attenuation. The consequence of this is an overestimation (0.45–1.48 m) of the predicted increase of potential seagrass depth limits when based on Secchi depth rather than K _d.  相似文献