Mixing of magmatic CO₂ into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes     

Makoto Yamada  Shinji Ohsawa  Kohei Kazahaya  Masaya Yasuhara  Hiroshi Takahashi  Kazuhiro Amita  Hideo Mawatari  Shin Yoshikawa 《Journal of Geochemical Exploration》2011

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.  相似文献   

Paleomagnetism of the Middle–Late Jurassic to Cretaceous red beds from the Peninsular Thailand: Implications for collision tectonics     

Itaru Yamashita  Adichat Surinkum  Yutaka Wada  Makoto Fujihara  Masao Yokoyama  Haider Zaman  Yo-ichiro Otofuji 《Journal of Asian Earth Sciences》2011,40(3):784-796

Jurassic to Cretaceous red sandstones were sampled at 33 sites from the Khlong Min and Lam Thap formations of the Trang Syncline (7.6°N, 99.6°E), the Peninsular Thailand. Rock magnetic experiments generally revealed hematite as a carrier of natural remanent magnetization. Stepwise thermal demagnetization isolates remanent components with unblocking temperatures of 620–690 °C. An easterly deflected declination (D = 31.1°, I = 12.2°, α₉₅ = 13.9°, N = 9, in stratigraphic coordinates) is observed as pre-folding remanent magnetization from North Trang Syncline, whereas westerly deflected declination (D = 342.8°, I = 22.3°, α₉₅ = 12.7°, N = 13 in geographic coordinates) appears in the post-folding remanent magnetization from West Trang Syncline. These observations suggest an occurrence of two opposite tectonic rotations in the Trang area, which as a part of Thai–Malay Peninsula received clockwise rotation after Jurassic together with Shan-Thai and Indochina blocks. Between the Late Cretaceous and Middle Miocene, this area as a part of southern Sundaland Block experienced up to 24.5° ± 11.5° counter-clockwise rotation with respect to South China Block. This post-Cretaceous tectonic rotation in Trang area is considered as a part of large scale counter-clockwise rotation experienced by the southern Sundaland Block (including the Peninsular Malaysia, Borneo and south Sulawesi areas) as a result of Australian Plate collision with southeast Asia. Within the framework of Sundaland Block, the northern boundary of counter-clockwise rotated zone lies between the Trang area and the Khorat Basin.  相似文献   

华南中生代岩浆活动研究：现状和前景     

毛建仁  叶海敏  厉子龙  赵希林  刘凯  李寄嵎  Yutaka Takahashi  Weon-Seo KEE 《地质学报》2013,87(Z1):137-138

  相似文献   

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

Seasonal variations of the surface currents in the Tsushima Strait     

Yutaka Yoshikawa  Akira Masuda  Kenichi Marubayashi  Michiyoshi Ishibashi 《Journal of Oceanography》2010,66(2):223-232

Seasonal variations of the surface currents in the Tsushima Strait were investigated by analyzing the monthly mean surface currents measured with HF radar. Several new features of the surface currents have been found. One notable feature is the large, complicated seasonal variation in the current structure in the eastern channel of the strait. For example, in the southeastern and northwestern regions of the channel, southwestward countercurrents are found in summer while southeastward acrossshore currents are found in autumn and winter. The wind-driven flow (Ekman flow) as well as surface geostrophic currents are responsible for these complicated variations of the surface currents. To quantify each variation of the flow and current, the wind-driven flow was calculated from the monthly wind (more precisely, the friction velocity) using the monthly speed factor and deflection angle estimated in our previous study, and the surface geostrophic currents were then estimated by subtracting the wind-driven flow from the measured surface currents. It was found that the acrossshore currents are the wind-driven flow, and that the surface geostrophic currents flow almost in the along-shore direction, indicating the validity of the decomposition of the surface velocity into the wind-driven flow and the geostrophic currents using the speed factor and deflection angle. A real-vector empirical orthogonal function (EOF) analysis of the surface geostrophic currents shows a pair of eddies in the lee of Tsushima and Iki Islands as the first mode, which indicates that the southwestward countercurrents in the eastern channel are formed primarily by the incoming Tsushima Warm Current.  相似文献   

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region     

Hiroshi Ishida  Yutaka W. Watanabe  Joji Ishizaka  Toshiya Nakano  Naoki Nagai  Yuji Watanabe  Akifumi Shimamoto  Nobuhiro Maeda  Michimasa Magi 《Journal of Oceanography》2009,65(2):179-186

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.  相似文献   

Transition from frontal accretion to underplating in a part of the Nankai Trough Accretionary Complex off Shikoku (SW Japan) and extensional features on the lower trench slope     

Jeremy Leggett  Yutaka Aoki  Takefumi Toba 《Marine and Petroleum Geology》1985,2(2):131-141

Migrated multichannel seismic reflection profiles and bathymetry from a 200 × 120 km area of the Nankai Trough inner slope reveal three physiographic-tectonic domains on the lowermost slope. Linear ridges demarking laterally-continuous hangingwall anticlines above ramps in a relatively simple imbricate stack of trench turbidites characterize the western domain. An imbricate fan underlies a relatively flat structural terrace in the east. Between these two domains lies a compound knoll (Minami Muroto Knoll) some 40 km long, opposite which the thrust front pushes some 10 km further seaward than is the case in the domains to east and west. In the western ‘linear-ridge’ domain previous DSDP drilling penetrated turbiditic trench fill uplifted in the lowermost thrust-fold terrace above a decollement within the underthrusting Shikoku Basin (oceanic plate) sequence. The Shikoku Basin sequence in the western domain is divided into an upper, poorly reflective, hemipelagic claystone unit and a lower, strongly reflective, unit comprising Pliocene turbidites. The lower unit is traceable intact up to c.20 km landward below the lower trench slope and in the better resolved profiles the decollement lies along the base of the claystone unit. A similar decollement within the Shikoku Basin sequence in the eastern domain is traceable up to c.22 km landward. A critical seismic record crossing the western part of Minami-Muroto Knoll shows that the decollement is traceable only 8 km landward to a point, under the steep slope at the front of the knoll, landward of which the subducting Shikoku basin sequence is apparently thickened by as much as twice. This thickening, occuring as it does immediately along-strike from a simple imbricate fan to the east of the knoll and a relatively simple imbricate stack to the west (both evidently involving no strata from the lower Shikoku Basin unit) we ascribe to underplating by formation of duplexes of Shikoku Basin strata. Strike-parallel extension, akin to that postulated for high structural levels in certain thrust belts, is caused by uplift of the knoll as a result either of the underplating, or segmentation of the subducting oceanic crust, or both: a normal fault throws to the west off the west flank of the knoll. It bounds a transverse, trough-like, slope-basin with at least 900 m of fill. Upslope from the knoll broadly slope-parallel normal faults cut, and pond, recent slope sediments. The most impressive is a listric growth fault which dips trenchward. Alternative explanations for these involve extensional collapse of this part of the prism resulting from the subduction of a topographic high, or a zone of selective underplating below the trenchward portion of Minami Murato Knoll.  相似文献   

Climate control on Venus: Comparison of the carbonate and pyrite models     

George L. Hashimoto  Yutaka Abe 《Planetary and Space Science》2005,53(8):839-848

We review two models describing the Venus climate system: the carbonate and pyrite models. It has been argued carbonate and pyrite are potentially important minerals controlling the climate of Venus, though existence of either minerals has not been confirmed. Although it used to be proposed that carbonation reaction might explain the Venus’ atmospheric CO₂ abundance, it is unlikely Venus’ surface is reactive enough to control the Venus’ massive CO₂ atmosphere. Venus’ surface carbonate is also able to affect the climate through the reaction with atmospheric SO₂ to form anhydrite. Under the carbonate model the climate state is not in equilibrium and would be unstable due to the reaction between carbonate and SO₂. On the other hand, pyrite-magnetite reaction is proposed to explain the Venus’ atmospheric SO₂ abundance. Under pyrite-magnetite reaction, however, the climate would be stabilized such that the existing climate state is maintained over a geological timescale, while some observational facts such as atmospheric abundance of SO₂ and surface temperature could also be reasonably explained.  相似文献   

Magmatic unmixing in spinel from late Precambrian concentrically-zoned mafic–ultramafic intrusions, Eastern Desert, Egypt     

Ahmed Hassan Ahmed  Hassan Mohamed Helmy  Shoji Arai  Masako Yoshikawa 《Lithos》2008,104(1-4):85-98

Spinel is widespread in the ultramafic core rocks of zoned late Precambrian mafic–ultramafic complexes from the Eastern Desert of Egypt. These complexes; Gabbro Akarem, Genina Gharbia and Abu Hamamid are Precambrian analogues of Alaskan-type complexes, they are not metamorphosed although weakly altered. Each intrusion is composed of a predotite core enveloped by pyroxenites and gabbros at the margin. Silicate mineralogy and chemistry suggest formation by crystal fractionation from a hydrous magma. Relatively high Cr₂O₃ contents are recorded in pyroxenes (up to 1.1 wt.%) and amphiboles (up to 1.4 wt.%) from the three plutons. The chrome spinel crystallized at different stages of melt evolution; as early cumulus inclusions in olivine, inclusions in pyroxenes and amphiboles and late-magmatic intercumulus phase. The intercumulus chrome spinel is homogenous with narrow-range of chemical composition, mainly Fe³⁺-rich spinel. Spinel inclusions in clinopyroxene and amphibole reveal a wide range of Al (27–44 wt.% Al₂O₃) and Mg (6–13 wt.% MgO) contents and are commonly zoned. The different chemistries of those spinels reflect various stages of melt evolution and re-equilibration with the host minerals. The early cumulus chrome spinel reveals a complex unmixing structures and compositions. Three types of unmixed spinels are recognized; crystallographically oriented, irregular and complete separation. Unmixing products are Al-rich (Type I) and Fe³⁺-rich (Type II) spinels with an extensive solid solution between the two end members. The compositions of the unmixed spinels define a miscibility gap with respect to Cr–Al–Fe³⁺, extending from the Fe³⁺–Al join towards the Cr corner. Spinel unmixing occurs in response to cooling and the increase in oxidation state. The chemistry and grain size of the initial spinel and the cooling rate control the type of unmixing and the chemistry of the final products. Causes of spinel unmixing during late-magmatic stage are analogous to those in metamorphosed complexes. The chemistry of the unmixed spinels is completely different from the initial spinel composition and is not useful in petrogenetic interpretations. Spinels from oxidized magmas are likely to re-equilibrate during cooling and are not good tools for genetic considerations.  相似文献   

Seismic behaviour of pile groups by hybrid experiments     

Kenzo Toki  Tadanobu Sato  Junji Kiyono  Nozar Kishi Garmroudi  Susumu Emi  Masaaki Yoshikawa 《地震工程与结构动力学》1991,20(10):895-909

Non-linear seismic soil-pile interaction was studied with a hybrid procedure that used a pseudo-dynamic testing (PDT) method modified to account for frequency dependence and developed for foundation-soil systems. The numerical scheme used in the conventional PDT was improved by the introduction of a time-dependent pseudo-forcing function derived from the frequency-dependent dynamic characteristics of the system by Hilbert transformation in the frequency domain. Single, 2-, 3- and 9-pile group foundation models were used, their mechanical characteristics later being determined from static and forced vibration dynamic tests. Amplitude scaling was used for three recorded accelerograms. Data recorded during an earthquake at the site of the experiments revealed that the proposed methodology predicts well seismic nonlinear interaction and accounts for frequency dependence and non-linearity in the time domain.  相似文献