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41.
Francesco Di Benedetto Francesco D’Acapito Gabriele Fornaciai Massimo Innocenti Giordano Montegrossi Luca A. Pardi Silvia Tesi Maurizio Romanelli 《Physics and Chemistry of Minerals》2010,37(5):283-289
An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO2) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe2+ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell: = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe3+ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe4+ is stabilised by the favourable local structural arrangement. 相似文献
42.
In recent years, debris flows have represented a severe natural hazard in South-Gargano watersheds (Puglia Region, Southern Italy). Hill slopes erosion, caused by the inadequate protection of the degraded forests, produces large amounts of soil and debris that are conveyed downstream during heavy rainstorms. The involved material is characterized by limestone fragments and blocks in a sandy-silt matrix. In this paper, the rheological properties of such debris-flow materials have been investigated. Eight specimens of particulated sediments of particle diameter of d ≤ 4 mm have been analysed using a rheometric tool for large particle suspensions, the ball measuring system (BMS). The influence of sediment concentration on the bulk rheological behaviour has been evaluated at concentrations by volume obtained in fully water-saturated conditions (volumetric sediment concentration C V ~ 0.8) and with fixed water content (C V = 0.42). The rheological data were fitted to the Bingham, Herschel–Bulkley, and O’Brien and Julien models to define viscosity and yield stress dependency on sediment concentration, to provide viscosity information for hazard mitigation as well as for comparison to other debris-flow events. 相似文献
43.
The relation between karst spring discharge and rainfall by cross-correlation analysis (Campania, southern Italy) 总被引:4,自引:2,他引:2
The relation between rainfall and the discharge from two springs, located at the base of different karst massifs in southern Italy, is investigated by cross-correlation analyses. Data are derived from a continuous time window of 13 years. The input signal involves multiple rainfall time series (cumulative rainfall over varying time windows), while the time series of daily spring discharges are used as the output signal. Analyses were first conducted on the unprocessed data and then on data for which linear trends and seasonal components had been removed, the latter by a spectral analysis. Analyses contributed to the investigation of the time required for water to flow through the karst aquifers at the two sites. Long time intervals of the cumulative rainfall (>60 days) appear to be the main component affecting the spring discharge hydrographs; shorter time intervals seem to be related to quick-flow paths. Some statistics about the linear regression and the meaning of the cross-correlation analysis are discussed. Cross-correlation analysis can provide strong support for identification of the main rainfall contribution and the travel time through the main infiltration pathways in aquifers. 相似文献
44.
Water quality and relationship between superficial and ground water in Rome (Aniene River basin,central Italy) 总被引:1,自引:1,他引:0
Francesco La Vigna Simone Ciadamidaro Roberto Mazza Laura Mancini 《Environmental Earth Sciences》2010,60(6):1267-1279
Chemical, physical, and biological features of streams and ground water of the North-Eastern area of Rome are jointly analyzed
in order to assess the status of water resources. Ground water was investigated with classical survey methods (pH, temperature,
and electric conductivity). Microbiological pollution, faunal composition, and stream surrounding area conditions of surface
waters were studied, in order to quantify the residual value of these ecosystems from both a human and an environmental point
of view. Results show a general impairment of the system and the comparison between superficial waters and shallow ground
waters makes it possible to detect the presence of a connection between the two levels. This relationship occurs as an exchange
from superficial waters (streams and rivers) to the shallow aquifers. Where superficial waters are contaminated, as in the
Tor Sapienza stream, pollutants move to the shallow aquifers too, due to the decreased pressure of the over-exploited aquifer.
Moreover, uncontrolled drilling activity, diffused in urban areas, makes it possible the connection between shallow and deep
ground water. Notwithstanding this, the mixing between superficial and deep ground water system in Rome is not very widespread
and, apparently, limited to restricted areas. 相似文献
45.
A numerical Round Robin on tunnels under seismic actions 总被引:3,自引:0,他引:3
Emilio Bilotta Giovanni Lanzano S. P. Gopal Madabhushi Francesco Silvestri 《Acta Geotechnica》2014,9(4):563-579
Although the seismic behaviour of shallow circular tunnels in soft ground is generally safer than aboveground structures, some tunnels were recently damaged during earthquakes. In some cases, damage was associated with strong ground shaking and site amplification, which increased the stress level in the tunnel lining. Pseudo-static and simplified dynamic analyses enable to assess transient changes in internal forces during shaking. Nevertheless, experimental evidences of permanent changes in internal loads in the tunnel lining would suggest that a full dynamic analysis including plastic soil behaviour should be performed when modelling the dynamic interaction between the tunnel and the ground. While sophisticated numerical methods can be used to predict seismic internal forces on tunnel structures during earthquakes, the accuracy of their predictions should be validated against field measurements, but the latter are seldom available. A series of centrifuge tests were therefore carried out at the University of Cambridge (UK) on tunnel models in sand, in the framework of a research project funded by the Italian Civil Protection Department. A numerical Round Robin on Tunnel Tests was later promoted among some research groups to predict the observed behaviour by means of numerical modelling. In this paper, the main results of five selected numerical predictions are summarized and compared with the experimental results. 相似文献
46.
This paper deals with the effects of thermal stresses on selected carbonate rocks used as dimension stones. They are Mesozoic calcareous and dolomitic rocks cropping out in Apulia (southern Italy) that, for their physico-mechanical and aesthetic properties, have always been finding a large application both as ornamental stones and as simple construction materials; their use is attested not only in Italy, in works of archaeological, historical and artistic interest too. The cause–effect relationships of thermal degradation were studied by means of an artificial accelerated ageing test, in order to provide a perspective about the decay of carbonate stones due to diurnal and seasonal temperature fluctuations, as well as thermal shocks during events of fire development. The stone samples were subjected to thermal cycles in a muffle furnace, ranging from 100 to 700 °C; after each cycle, several non-destructive and semi-destructive tests were carried out: mass and volume measurements, mercury intrusion porosimetry, sclerometer tests, ultrasonic tests, thin-section observations and determination of chromatic alterations through image analysis and Munsell charts method. In this way, the qualitative and quantitative modifications induced in fabric, physical and mechanical properties were discussed. The results highlight the fundamental role of depositional and diagenetic fabric that, together with mineralogical composition, represents the most significant discriminating factor in the response of the stone to thermal stresses. 相似文献
47.
Pieralberto Maianti Marco Rusmini Riccardo Tortini Giorgio Dalla Via Federico Frassy Andrea Marchesi Francesco Rota Nodari Marco Gianinetto 《Natural Hazards》2014,73(2):473-492
Accidental release of crude oil into the sea due to human activity causes water pollution and heavy damages to natural ecosystems killing birds, fish, mammals and other organisms. A number of monitoring systems are used for tracking the spills and their effects on the marine environment, as well as for collecting data for feeding models. Among them, Earth observation technologies play a crucial role and moderate spatial resolution satellite systems are able to collect images with a very short revisit time or even daily. This paper describes the use of Moderate-Resolution Imaging Spectroradiometer data for monitoring large oil slicks with the fluorescence/emissivity index and object-based image analysis. Two case studies are presented: the Deepwater Horizon (2010) and the Campos Basin (2011) oil spill accidents. Results show that it is possible to track the dynamics of the slick both for massive and long-lasting accidents and for smaller and very quick accidents. The main advantages of the method proposed are a straightforward implementation, a fast and semi-automated data processing and the capability of integration of daytime and nighttime acquisitions, as well as its adaptability to different sensors. 相似文献
48.
Filippo Santucci de Magistris Anna d’Onofrio Augusto Penna Rodolfo Puglia Francesco Silvestri 《Natural Hazards》2014,74(3):2005-2035
The prediction of the variability of the seismic ground motion in a given built-up area is considered an effective tool to plan appropriate urban development, to undertake actions on seismic risk mitigation and to understand the damage pattern caused by a strong-motion event. The procedures for studying the seismic response and the seismic microzonation of an urban area are well established; nevertheless, some controversial points still exists and are discussed here. In this paper, the selection of a reference input motion, the construction of a subsoil model and the seismic response analysis procedures are discussed in detail, based on the authors’ experience in two Italian case histories: the seismic microzonation of the city of Benevento, which was a predictive study, and the simulation of seismic response and damage distribution in the village of San Giuliano di Puglia, which was a retrospective analysis. 相似文献
49.
50.
Francesco Haardt Emanuele Ripamonti Monica Colpi Andrea Ferrara 《Astrophysics and Space Science》2002,281(1-2):479-482
We simulate the collapse of a primordial protostellar cloud by means of a 1D hydrodynamics code accounting for chemical evolution,
radiative transfer and radiation pressure. We find that the role of radiation pressure is negligible throughout the whole
simulations, i.e. Until shortly after the formation of a central hydrostatic core. We also estimate the luminosity and the
spectrum of such collapsing clouds. The luminosity is initially due to a number of H2 lines and is of the order of 1033-34 erg s-1. It then grows to values ≳1036 erg s-1 by the time the core forms, and results from both HH lines and continuum radiation.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献