三种扇贝挥发性风味物质指纹图谱分析     

崔明仙  李妍  付睛睛  景福涛  陈希盼  张恩烁  李赞  徐晓辉  冯艳微  孙国华  李彬  王卫军  杨建敏 《海洋与湖沼》2022,53(3):743-758

为探究海湾扇贝(Argopecten irradians)、栉孔扇贝(Chlamys farreri)、虾夷扇贝(Patinopecten yessoensis)三种扇贝闭壳肌的挥发性风味物质差异,采用气相色谱-离子迁移谱(gas chromatography-ion mobility spectroscopy,GC-IMS)技术,对三种扇贝闭壳肌在新鲜(40℃)和加热(100℃)情况下进行挥发性成分分析。结果表明:在新鲜状态下,海湾扇贝(HWSB-F)、栉孔扇贝(ZKSB-F)、虾夷扇贝(XYSB-F)闭壳肌中,共定性出27种挥发性风味物质,其中醛类8种,醇类5种,酮类5种,酯类3种,以及醚类、苯类、酸类、烯类和噻唑等。在加热情况下,海湾扇贝(HWSB-C)、栉孔扇贝(ZKSB-C)、虾夷扇贝(XYSB-C)闭壳肌中共定性出52种挥发性风味物质,其中醛类20种,酯类5种,酮类7种,醇类8种,烯类4种,酸类2种,醚类2种,还包括吡嗪、胺类、苯类、含氧杂环等物质。对三种扇贝闭壳肌新鲜组和加热组指纹图谱进行分析,发现新鲜扇贝原有的挥发性风味物质加热后减少,且产生了新的其他种类的挥发性风味物质。扇贝闭壳肌加热组的挥发性风味物质种类较多,组成比较复杂,新鲜组的扇贝闭壳肌挥发性风味物质种类较少,组成简单。通过主成分分析,可在新鲜状态和加热状态下,有效区分三种扇贝闭壳肌组织。三种扇贝闭壳肌挥发性风味物质指纹图谱的建立,丰富了不同扇贝呈味物质的组成成分研究内容,证明GC-IMS技术可快速鉴别三种去壳扇贝闭壳肌的种类,为不同种扇贝闭壳肌以次充好提供检测依据。  相似文献   

新疆阿尔泰伟晶岩中绿柱石拉曼光谱特征研究——以可可托海3号脉与阿祖拜328、528号脉为例     

周天怡  陈衍景  张辉 《岩石矿物学杂志》2014,33(S2):77-84

本文对新疆可可托海3号伟晶岩脉中的绿柱石与阿祖拜328、528号伟晶岩脉中的宝石级绿柱石开展拉曼光谱对比研究,获得以下主要结论: ① 阿祖拜328、528号伟晶岩脉中宝石级绿柱石以富含Ⅰ型H₂O为特征,可可托海3号脉早期形成的结构带(Ⅰ-Ⅱ带)中绿柱石以及相对富H₂O岩浆体系中形成的绿柱石(Ⅳ带)以存在Ⅰ型H₂O为主,演化程度相对较高,岩浆体系中结晶的结构带(Ⅲ带)以及岩浆-热液过渡阶段体系形成的结构带(Ⅴ带)中绿柱石以含有Ⅱ型H₂O为特征; ② 在可可托海3号脉以及阿祖拜328号、528号脉绿柱石矿物中均发现冰晶石矿物包体,指示伟晶岩岩浆含有较高的F含量;③ 绿柱石通道水类型(Ⅰ型H₂O、Ⅱ型H₂O)及相对比例,是伟晶岩岩浆-热液演化过程及其形成条件的响应,在相对氧化的岩浆体系中主要形成绿柱石矿物,而相对还原的富H₂O岩浆体系更有利于海蓝宝石形成.  相似文献   

微波消解—冷原子荧光光谱法测定植物样品中的汞     

陈海杰  于兆水  邢夏 《物探与化探》2014,(2):393-395,401

为了简化测量植物中汞含量的方法,提高灵敏度及结果的可信度,实验采用微波消解植物样品的办法,使样品经氯化亚锡还原,再用冷原子荧光测定出植物样品中汞的含量。确定了消解样品的方法和微波消解样品的条件,优化了仪器的最佳工作参数。方法检出限0.30×10-9(稀释因子100倍),精密度(n=12)在2.09%~6.05%,加标回收率94.1%~105.5%,方法经生物国家一级标准物质验证方法准确可靠。  相似文献   

Experimental determination of the surface photometric contribution in the spectral reflectance deconvolution processes for a simulated martian crater-like regolithic target     

Aurélien M. Cord  Patrick C. Pinet  Yves Daydou  Serge D. Chevrel 《Icarus》2005,175(1):78-91

  相似文献   

Raman spectroscopic analysis of cyanobacterial colonization of hydromagnesite, a putative martian extremophile     

Howell G.M. Edwards  Caroline D. Moody  Susana E. Jorge Villar  Michael J. Russell 《Icarus》2005,175(2):372-381

Raman spectra of an extremophile cyanobacterial colony in hydromagnesite from Lake Salda in Turkey have revealed a biogeological modification which is manifest as aragonite in the stratum associated with the colony. The presence of key spectral biomarkers of organic protectant molecules such as β-carotene and scytonemin indicate that the survival strategy of the cyanobacteria is significantly one of UV-radiation protection. The terrestrial location of this extremophile is worthy of consideration further because of its possible putative link with the “White Rock” formations in Sabaea Terra and Juventae Chasma on Mars.  相似文献   

RESOLUTION OF MULTICOMPONENT FLUORESCENT MIXTURES BY ANALYSIS OF THE EXCITATION-EMISSION-FREQUENCY ARRAY     

DONALD S.BURDICK XIN M.TU Institute of Statistics  Decision Sciences  Department of Mathematics Duke University  Durham  NC  U.S.A.LINDA B.MCGOWN DAVID W.MILLICAN Department of Chemistry  Drake University  Durham  NC  U.S.A. 《地理学报(英文版)》1990,(1)

Fluorescence lifetime provides a third independent dimension of information for the resolution of totalluminescence spectra of multicomponent mixtures.The incorporation of this parameter into theexcitation-emission matrix(EEM)by the phase modulation technique results in a three-dimensionalexcitation-emission-frequency array (EEFA).Multicomponent analysis based on the three-dimensionalEEFA brings a qualitative change for the resolved spectra,i.e.individual spectra can be uniquely resolved,which is impossible with any two-dimensional analysis.In this paper we present a method for analyzingthe EEFA.We show mathematically that with the three-dimensional analysis of the EEFA individualspectra and lifetimes can be obtained.Our algorithm is developed in mathematical detail and isdemonstrated by its application to a two-component mixture.  相似文献   

Characterization of a chalcopyrite from Brazil by Mössbauer spectroscopy and other physicochemical techniques     

W. N. Mussel  E. Murad  J. D. Fabris  W. S. Moreira  J. B. S. Barbosa  C. C. Murta  W. P. Abrahão  J. W. V. De Mello  V. K. Garg 《Physics and Chemistry of Minerals》2007,34(6):383-387

We studied a chalcopyrite from a Cu ore deposit in Rio Grande do Sul, Brazil, by Mössbauer spectroscopy at room temperature and 110 K. Supporting methods to check for sample purity and to characterize further sample properties were slow-scanning X-ray powder diffraction and optical and microprobe analyses of polished sections of selected grains. Chemical analyses obtained using a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer showed the sample to consist of homogeneous and essentially stoichiometric chalcopyrite (CuFeS₂). Mössbauer spectra taken at both the above temperatures consist of asymmetric magnetically ordered patterns with unequal intensities of the line pairs 1–6 and 2–5, pointing to the existence of non-equivalent or multiple Fe sites. Least-squares fittings evidenced that the resonance intensity ratio of subspectrum with lower quadrupole shift (indicative of a more symmetric environment) to that with higher shift is 69:31, at room temperature, and 68:32, at 110 K. Rietveld refinement of the XRD data indicates the existence of tetragonal [a = 0.52855(1) and c = 1.0412(1) nm] and cubic [a ₀ = 0.5273(2) nm] modifications in a proportion of 74:26, in good agreement with the Mössbauer data. The saturation magnetization of the sample was 32.7 J/(T kg), confirming the oxidation state of Fe as trivalent and pointing to little to no spin canting.  相似文献   

可见光波段灰度熵和热红外亮温差的沙尘遥感判识   总被引：1，自引：0，他引：1  

李彬  卢士庆  孙小龙  高健  孟翔晨  赵悦晨  吕迪波 《遥感学报》2018,22(4):647-657

沙尘作为对流层气溶胶的主要成分,对气候系统有许多影响;同时,作为环境污染物,对人类健康危害也很大。沙尘天气一般在春季爆发,对中国北方大部分区域的生产和生活有较大影响。以往针对沙尘遥感监测人们开展了许多研究,取得了一定的效果。但对于一些云和沙尘混合的复杂状况,传统方法识别效果较差,几乎不能有效识别出沙尘。采用葵花8号(Himawari-8)卫星数据,提出一种针对性的识别方法。引入了0.46μm和0.51μm反射率差值RDI,统计发现该指数在一定范围内可以表现出沙尘连续性特征,并有效地将中高云和大部分地表与沙尘区分开来。碎积云的RDI值分布与沙尘的较为相似,为此进一步引入了灰度熵方法来滤除。例举了3次沙尘过程的判识结果,并结合地面观测数据进行了验证。其中对2017年5月4日沙尘的地面验证表明,位于云沙混合区的27个站中有22个站的地面观测与判识相一致。对于一些复杂条件下的沙尘,该方法是对分裂窗亮温差的有效补充。  相似文献   

Calibration of Infrared Absorption Coefficients for Structural Hydroxyl in Garnet by a Combined Study of Isotope Ratio Spectrometry and Vibrational Spectroscopy     

Lin Zhu  Ren-Xu Chen  Yong-Fei Zheng  Jing Wang  Bing Gong 《Geostandards and Geoanalytical Research》2023,47(1):105-124

An accurate determination of water content in garnet is critical to quantify the transport of water to the deep mantle by the subducted oceanic crust beyond the breakdown of hydrous phases. Fourier transform infrared spectroscopy (FTIR) is the most widely used approach to determine the species and contents of water in garnet. Accurate quantification of OH in garnet requires independent calibration using an external method, as OH absorbance is mineral and composition specific. To obtain the infrared absorption coefficients of structural hydroxyl in garnet, a combined study of spectrometric analyses by FTIR and a method combining a thermal conversion elemental analyser with isotope ratio mass spectrometry (TC/EA-MS) was carried out for fourteen gem-quality natural garnet crystals with variable compositions. The obtained molar absorption coefficients were 9322 ± 338 and 240 ± 26 l mol⁻¹ cm⁻² for grossular- and spessartine-rich garnet and pyrope-almandine garnet, respectively. These results are within the range of previous studies. A new molar absorption coefficient of 689 ± 177 l mol⁻¹ cm⁻² was obtained for pyrope-spessartine garnet. The large variation in the absorption coefficient indicates it is controlled by both garnet composition and OH-absorption bands. The obtained absorption coefficients are only appropriate for certain types of eclogitic garnet, and more studies should be carried out on eclogitic garnets.  相似文献   

放射性元素在测井解释中的应用进展及分析     

王敏  李菲 《地质论评》2023,69(Z1):423-424

  相似文献