碘化氨除锡后封闭酸溶-电感耦合等离子体质谱测定锡矿石中的共生和伴生元素   总被引：1，自引：1，他引：0  

马生凤  赵文博  朱云  孙红宾  王蕾  温宏利 《岩矿测试》2018,37(6):650-656

锡矿石是难分解的矿物,主要存在形式是锡石(SnO_2),且共生和伴生元素多,常用的酸溶方法几乎不能溶解SnO_2,从而给锡矿石中的共生与伴生元素的准确测定带来困难。本文基于碘化氨在较低温度下熔融可产生无水状态的碘化氢,利用碘化氢的酸性和氨的还原性分解SnO_2,使Sn呈SnI_4升华分离的原理处理锡矿石。实验中以高纯铂丝作催化剂,加入碘化铵在450℃的马弗炉中分解锡矿石30 min,使得Sn以SnI_4形式挥发,除锡率达到98%以上,再用2 mL氢氟酸和1 mL硝酸封闭溶解残渣,电感耦合等离子体质谱测定钴镍铜铌钽钍铀等24个共生和伴生元素。元素检出限在0. 001～2. 9μg/g之间,90%以上元素的相对标准偏差(RSD)小于5%,相对误差小于10%。本方法解决了锡矿石难分解的问题,可测定共存金属元素,也适合测定Sn含量在1. 27%～62. 49%之间的锡矿石中的微量和痕量元素及锡精矿中的微量元素。  相似文献   

Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)   总被引：4，自引：0，他引：4  

D. L. Savoie  J. M. Prospero  R. J. Larsen  F. Huang  M. A. Izaguirre  T. Huang  T. H. Snowdon  L. Custals  C. G. Sanderson 《Journal of Atmospheric Chemistry》1993,17(2):95-122

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.  相似文献   

Aspects of the cycle of inorganic nitrogen compounds in the tropical rain forest of the Ivory Coast     

Jean Servant  Robert Delmas  Jacques Rancher  Marcel Rodriguez 《Journal of Atmospheric Chemistry》1984,1(4):391-401

A partial balance of mineral N is given for the basins of two coastal rivers in a forest zone in the Ivory Coast. The dry and wet depositions on the basin surfaces is given for particulate matter (NO₃ ^–, NH₄ ⁺). The quantity of mineral N washed away in the rivers is evaluated. The losses from leaching of the soils by rainwater are about 0.33 to 1.0% of the atmospheric depositions for NH₄ ⁺–N and 2.2 to 5.8% for NO₃ ^––N. The yearly atmospheric input of N compounds to the ecosystem, about 1.4 g N m^–2 y^–1, is at least 14% of mineral N formed in the soils and is therefore quite significant.  相似文献   

A Basic Water Quality Model for the River Neckar: Part 2 – model‐based analysis of the oxygen budget and scenarios     

Ingo Haag 《洁净——土壤、空气、水》2006,34(6):549-559

In this paper the Basic Water Quality Model (BWQM) for the central part of River Neckar is used to analyse the oxygen budget and to assess the potentials of various measures to prevent or mitigate critical dissolved oxygen (DO) declines. It is shown that the oxygen budget is mainly governed by phytoplankton dynamics. The excessive growth of algae and the sudden break down of the resulting algal blooms may cause episodic DO depressions. Therefore, to stabilise the oxygen budget in a sustainable way, eutrophication has to be controlled within the central part of River Neckar and the upstream regions. The only feasible way to reach this goal appears to be a further drastic reduction of phosphorus emissions. In addition, it is indispensable to hold the very high standards of biochemical oxygen demand and ammonium retention at the wastewater treatment plants. A worse performance of the treatment plants would dramatically aggravate critical DO declines which may be caused by algae dynamics. As long as the oxygen budget is not completely stabilised, weir and turbine aeration can be used to mitigate DO depressions. It could be shown that the potentials of these measures suffice to keep DO at a tolerable level. However, due to the long travel times in River Neckar, it is important to start aeration up to several days before the DO minimum is reached.  相似文献   

Nitrification in Kochi backwaters     

Joereen Miranda  K.K. Balachandran  R. Ramesh  Mohideen Wafar 《Estuarine, Coastal and Shelf Science》2008

Nitrification rates, as oxidation of ¹⁵N-labelled ammonium and loss of nitrite from N-Serve treated samples, were measured in Kochi backwaters during three seasons. Nitrification rates ranged from undetectable to 166 nmol N L⁻¹ h⁻¹ in the water column and up to 17 nmol N (g wet wt)⁻¹ h⁻¹ in sediments. Nitrification rates were higher in intermediate salinities than in either freshwater or seawater end. Within this salinity range, nitrification rates could be related to ammonium concentrations. As shown by the relation between ammonification and nitrification rates, it is also likely that nitrification is more regulated by renewal rates, rather than by in situ concentrations, of substrate. Among other environmental parameters, temperature and pH may have an influence on nitrification. Potential nitrification rates calculated from loss of nitrite from N-Serve treated, nitrite-enriched samples were about 800 nmol N L⁻¹ h⁻¹ in the water column and 40 nmol N (g wet wt)⁻¹ h⁻¹ in sediments. While these rates are in balance with those of biological ammonium production they may be inadequate to mitigate ammonium pollution in this estuary.  相似文献   

Growth of marine bacteria and ammonium regeneration from substrates in different C: N ratios     

WANG Jiangtao  YIN Xiaonan 《海洋学报(英文版)》2009,28(3):59-64

Natural assemblages of marine bacteria were chosen in a batch culture experiments. The impact of varying nitrogen substrate concentrations and the substrate C:N ratios (C:N_S) on the bacterial C:N ratio (C:N_B), the bacterial growth efficiency (BGE) and ammonium regeneration was mainly examined. The C:N_S ratios varied from 5:1 (carbon limitation) to 40:1 (nitrogen limitation) with varying combinations of glucose and NO₃^-. The C:N_B ratio had positive relationship with the C:N_S ratio (r=0.93, n=8), whose value was 3.77 when the C:N_S ratio was 5:1 but increased to 6.47 when the C:NS ratio was 40:1. These results indicate that the C:N_B ratio is a potential diagnostic tool for determining the bacterial growth in natural waters controlled by either, carbon or nitrogen. BGE decreased with the declining nitrate concentration and negatively related to C:N_s (r=-0.51, n=8). The average value of BGE was 0.20. This value was a little lower than other reports, which could be induced by the nitrogen source used in our experiments. Finally, regeneration time of ammonium delayed with the increasing C:N_S ratio, which indicates that there were different metabolism mechanisms when bacterial growth was limited by carbon source and nitrogen source.  相似文献   

海黍子(Sargassum muticum)池塘养殖及对氮磷去除效果的研究     

王翔宇  王志刚  吴海一 《海洋湖沼通报》2015,(1):91-95

初步研究了在海参养殖池塘中,不同养殖方式下,大型海藻海黍子(Sargassum muticum)的生长特性及对水体中氨氮和活性磷的去除作用。2012年3~5月,在山东莱州试验养殖海黍子60d,结果发现其长度最大从43.8cm增长到81.3cm,增长85.6%,日增长率(SGR)在14℃时最大,达到5.0%;每绳的平均质量从0.74kg增到2.59kg,增长3.5倍,SGR在12℃时最大,达4.3%;水体氨氮平均下降了25.9%,活性磷下降了37.5%。实验证明海黍子能在适合的池塘中养殖,并且能有效的去除水体中的氨氮和活性磷,是有效的近海生境修复大型工具种海藻。  相似文献   

沂源县田庄水库农业面源氮素淋滤行为研究   总被引：1，自引：0，他引：1  

宋辉  刘庆福 《地下水》2010,32(2):71-73

受农业面源影响,典型山区水库-田庄水库氮素超标,通过模拟土壤在不同降雨强度与不同降雨类型下的淋滤行为,探讨氮素淋溶释放规律,并对田庄水库农业面源氮素入库量进行了计算。结果表明,降雨类型和降雨强度只影响土壤中氨氮峰值浓度出现的时间,对其数值影响不大,由于土壤中硝氮含量较高,使降雨强度和类型对其淋出液中的硝氮峰值浓度产生的时间和数值都有所影响;农业面源氮污染通过田庄水库四条入库河流年均排入水库中的硝氮总量高达604．49t,氨氮为23．85t。  相似文献   

沼泽湿地土壤中硝态氮和铵态氮物理运移研究进展   总被引：1，自引：0，他引：1  

牟晓杰  孙志高  王玲玲 《海洋湖沼通报》2010,(1)

沼泽湿地土壤是氮的重要储库,发挥着源、汇和转化器的重要功能。湿地土壤中无机氮的物理运移不但影响着植物的养分供给状况,而且其对于湿地生态系统的结构、功能及健康状况等也有着深刻影响。综述了沼泽湿地土壤无机氮物理运移及影响因素的研究动态。当前湿地土壤无机氮物理运移的研究主要集中在硝态氮和铵态氮(特别是硝态氮)物理运移规律及部分影响因素(如水分条件、土壤物理性质等)的探讨上,缺乏无机氮物理运移的动力学、热力学机制与模型表征研究。鉴于当前研究中存在的问题,指出天然沼泽湿地是研究的薄弱点,其在今后应亟需加强的领域包括:①无机氮物理运移的驱动机制;②动力学、热力学与环境效应模型表征;③人类活动和全球变化对无机氮物理运移的影响。  相似文献   

Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil          下载免费PDF全文

Kong Xiang-ke  Zhang Zi-xuan  Wang Ping  Wang Yan-yan  Zhang Zhao-ji  Han Zhan-tao  Ma Li-sha 《地下水科学与工程》2022,10(3):223-232

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.  相似文献