辽东湾北部浅海区底泥镉元素形态特征   总被引：1，自引：0，他引：1  

刘明华 《地质与资源》2010,19(2):123-126,104

依据辽东湾浅海区底泥的52件样品中镉元素全量和各形态的测试数据,研究了镉元素存在形态的分布特征和相关性,并探讨了底泥镉形态的环境因素和生态效应.结果表明,底泥中的镉含量为较高水平,非残渣态含量极高,占总量的90%.非残渣态镉主要为离子交换态（44.38%）和碳酸盐结合态（21.38%）.镉的全量与各种形态都有极显著的相关性,并且分布特征一致,最高样点都分布在锦州湾.底泥镉的各种形态与底泥的有机质和海水环境中镉存在显著的相关性.底泥的离子交换态镉与脉红螺的镉有正相关关系.  相似文献   

长江宜昌段水系沉积物镉高值带成因   总被引：3，自引：0，他引：3  

夏锦霞  李方林  杨东 《吉林大学学报(地球科学版)》2009,39(2):305

应用贡献因子和富集因子等方法对长江宜昌段水系沉积物Cd的来源进行研究,结果表明：研究区内地层对宜昌段水系沉积物Cd的贡献由大到小依次为：震旦系>二叠系>泥盆系>志留系;前震旦系、寒武系、奥陶系、三叠系、侏罗系和白垩系地层则对长江宜昌段Cd高值带的形成有一定的削弱作用。利用贡献因子、富集因子和MapGIS空间分析综合研究表明,震旦系和二叠系含矿富Cd地层的风化产物是长江宜昌段Cd高值带的主要自然来源。区内锌矿、煤矿和磷矿开采过程中的尾砂、废水的堆积和排放是长江宜昌段Cd高值带的重要人为污染源。  相似文献   

电容去离子化去除地下水中镉的影响因素     

董军  李文德  陈建隆  吴玥  鹿豪杰 《吉林大学学报(地球科学版)》2019,49(4):1129-1136

以高比表面积活性炭作为吸附剂制备电容电极,研究电容去离子化（CDI）对地下水中镉的吸附性能。分别探讨了镉初始质量浓度、体系供电电压、地下水中常见阳离子种类对CDI去除镉的影响。结果表明,CDI吸附镉符合准二级吸附动力学、满足Langmuir等温吸附方程,CDI对镉的吸附为单分子层吸附。吸附量随镉初始质量浓度的升高而增加;在低质量浓度时,较高的供电电压会提高初始阶段的吸附速率,但对电极的最终吸附量无显著影响;地下水中主要阳离子的存在增加了体系的电导率,从而促进了CDI对镉的吸附,提高了镉的吸附速率和去除率。  相似文献   

牛角塘伴生型镉矿床特殊的成矿环境     

谷团 《吉林大学学报(地球科学版)》2017,47(2)

牛角塘伴生型镉矿床镉的富集程度高,比克拉克值高4~5个数量级,比工业品位高十几倍至上百倍。早寒武世清虚洞期牛角塘地区处于台缘滩丘环境,在清虚洞组中上部形成了藻丘建造,发育了含藻类、藻球粒、藻鲕粒、核形石和生物碎屑的白云岩,是该矿床最主要的容矿岩性单元。矿体普遍呈似层状、透镜状和脉状产出,矿体产状与容矿围岩的产状基本一致,矿体的分布受清虚洞组藻丘建造以及有利岩性组合的联合控制,具明显的层控、相控、岩控的特点。藻丘建造还可能提供了部分矿源。镉的超常富集、成矿与麻江古油藏的成藏演化具有一定的关系:一是牛角塘矿床成矿年龄为433~510 Ma,即加里东运动的中晚期,而加里东运动中晚期是麻江古油藏的油气活动时期,麻江古油藏的早期演化阶段与牛角塘镉矿的成矿期大体是重合的,成藏应略早于成矿,成矿是在古油藏液态烃仍然存在的情况下进行的,且成矿期有可能一直延伸至油藏被破坏以后;二是油藏流体为成矿提供具还原性质的成矿流体和部分硫源。特殊的岩相古地理环境和古油藏为牛角塘矿床镉的富集和成矿提供了有利条件。  相似文献   

泥蚶(Tegillarca granosa)重组铁蛋白富集重金属离子的特性及化学传感器的研究     

张涛  苏倡  刘艳  张迪骏  周君  芦晨阳  明庭红  司开学  苏秀榕 《海洋与湖沼》2017,48(4):870-876

利用泥蚶(Tegillarca granosa)铁蛋白原核表达工程菌获得的重组铁蛋白,通过圆二色光谱分析蛋白二级结构,扫描电镜和电感耦合等离子质谱研究重组铁蛋白富集Fe~(2+)、Mn~(2+)、Cd~(2+)、Cr~(3+)、Hg~(2+)、Pb~(2+)和As~(3+)等7种重金属离子的特性,同时探索利用重组铁蛋白修饰丝网印刷电极,设计和制备重组铁蛋白检测Pb~(2+)和Cd~(2+)浓度的电化学生物传感器。结果表明复性成功的铁蛋白多为完整的?-螺旋结构,而复性不成功的蛋白聚集体则多为无规卷曲。重组铁蛋白的直径和形态与富集的离子种类有关。泥蚶铁蛋白对单一金属离子Fe~(2+)和Mn~(2+)的富集凸显优势。对两种混合金属离子的富集大多表现为竞争关系。但重组铁蛋白对Hg~(2+)和As~(3+)混合组的富集量明显高于单一金属离子组的富集量,对Hg~(2+)和As~(3+)混合组的富集表现出协同促进作用。重组铁蛋白传感器对Pb~(2+)和Cd~(2+)溶液的最低检测限为10μg/L。  相似文献   

辽河流域土壤酸化与作物籽实镉生物效应的地球化学预警     

成杭新  杨晓波  李括  刘飞  杨柯  聂海峰  彭敏  赵传冬  刘英汉 《吉林大学学报(地球科学版)》2012,42(6):1889-1895

土壤酸化及其引发的生态安全问题是公众广泛关注、全球研究的热点。辽河流域多目标区域地球化学调查结果显示：当土壤中的w(CaO+K2O)≥3.86%时,土壤对酸性沉降物具有缓冲能力;当w(CaO+K₂O)<3.86%时,则土壤对酸性沉降物的缓冲能力显著下降。利用土壤酸化缓冲能力的地球化学预测模型,对全流域土壤酸化的缓冲能力进行了预测,指出辽河流域东部,即营口-鞍山-辽阳-沈阳-抚顺-铁岭-开源的广大区域内既是土壤酸化的脆弱区,也是作物籽实Cd超标的预警区,辽河流域土壤酸化区域将进一步扩大。  相似文献   

Survival,growth and shell deformities of copper- and cadmium-exposed mussels (Mytilus edulis L.) in brackish water     

Inke Sunila  Reijo Lindström 《Estuarine, Coastal and Shelf Science》1985,21(4):555-565

Mussels, Mytilus edulis L., were exposed to elevated concentrations of copper or cadmium in the laboratory, then placed in cages in the sea (salinity 7‰). One year later maximum lengths of the mussels were measured and shells screened for deformities. Growth was 0·6 cm year^?1 in the control cages and retarded in cages of exposed mussels. A total of 63% of cadmium-exposed and 46% of copper-exposed mussels had shell deformities. In the control cages 26% were deformed while in a natural population only 3% were deformed. The proportion of deformities to growth was inversely related. Low concentrations showed their injuriousness in this long-term test, probably due to the closing of the valves during exposure to high concentrations.  相似文献   

Accumulation of Zn,Cu and Cd by crabs and barnacles     

P.S. Rainbow 《Estuarine, Coastal and Shelf Science》1985,21(5):669-686

The crab Carcinus maenas (L.) and the barnacle Elminius modestus Darwin were exposed to a range of dissolved concentrations of Zn, Cu and Cd for 21 days in artificial seawater. Accumulation of Zn and Cu by crabs has been interpreted in terms of the presence of a regulation mechanism to maintain constant body concentrations (83·2 ± 19·4 μg Zn g^?1 dry wt.; 39·8 ± 9·8 μg Cu g^?1 dry wt.) under varying external dissolved metal levels, until a threshold dissolved metal concentration (c. 400 μg Zn l^?1; c. 170 μg Cu l^?1) beyond which net accumulation of metal begins. Cadium appears to be accumulated by C. maenas at all exposures with no evidence for regulation of body cadmium concentrations. Exposure of E. modestus to Zn, Cu or Cd caused net accumulation of the respective metal in the bodies of the barnacles, with no evidence for regulation of body metal concentrations.  相似文献   

SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA   总被引：3，自引：0，他引：3  

ZHANG Lei SONG Feng-bin 《中国地理科学(英文版)》2005,15(4):343-347

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…  相似文献   

Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China     

Hang Li  Dahua Li  Tangfu Xiao  Libin He  Zengping Ning  Jialong Sun  Changsheng Zhu  Yan Shuang 《中国地球化学学报》2008,27(1):21-27

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.  相似文献