污水可生化性及其影响因素研究   总被引：1，自引：0，他引：1  

刘颖  张朝辉  张焕胜  谢想海 《中国海洋大学学报(自然科学版)》2005,35(6):1029-1032,1036

以自行设计的生化呼吸线测定装置研究了印染污水的可生化性,该装置通过反应体系的溶解氧浓度跟踪生物降解过程.采用本文设计的模拟污水处理装置探讨了污泥驯化时间、污水投加量等对污水可生化性的影响.测定了污水经可生化性调控后的处理效果.结果表明,生化呼吸线法判断污水处理体系的可生化性是1种可靠易行的方法,提高体系的可生化性是增加污水处理效果的关键因素.  相似文献   

稠油成因研究综述   总被引：5，自引：0，他引：5  

胡守志  张冬梅  唐静  顾军 《地质科技情报》2009,28(2)

在阐述稠油地球化学特征基础上,对稠油的成因及其判识的最新研究进展进行了综述,稠油成因类型分原生型和次生型,其中,次生型稠油主要由生物降解、水洗和氧化作用分解、消耗或氧化原油中的烃类组分,使非烃和沥青质含量相对增加,致使原油密度和黏度增大,油质变稠.最后指出了目前稠油成因机制研究中存在的问题以及今后发展的方向.  相似文献   

多氯联苯湿地生物降解规律预测及污染风险分析   总被引：8，自引：0，他引：8       下载免费PDF全文

刘凌  陆桂华 《水科学进展》2003,14(1):79-84

建立了一个数学模型来预测多氯联苯湿地生物降解过程。该模型全面考虑了多氯联苯湿地生物降解的各子过程,包括:吸附/解吸、土壤屏蔽、扩散和生物降解,利用模型,预测了多氯联苯湿地生物降解的规律性及处理时间、处理终点;利用Monte-Carlo法,进行了多氯联苯湿地生物降解污染风险分析,结果表明,在采用基地现有处理方式的情况下,经过8年处理,土壤中4-Cl-PCBs不低于69.4%被降解的可能性为75%,此时土壤中能够继续污染外部环境的4-Cl-PCBs部分不超过10.9%的可能性为75%;土壤中4-Cl-PCBs全部生物降解完毕所需处理时间不超过16.20年的可能性为75%,最后被土壤不可逆屏蔽的残余物不超过20.9%的可能性为75%。  相似文献   

Relationship between rank and distribution of methylaromatic hydrocarbons for condensates of different origins     

P. Garrigues  J. Connan  E. Parlanti  J. Bellocq  M. Ewald 《Organic Geochemistry》1988,13(4-6)

Aromatic hydrocarbon fractions from thirty gas condensates have been analysed by capillary GC and high resolution Shpol'skii spectroscopy for the determination of the relative distribution in methylphenanthrene (MP), dimethylphenanthrene (DMP) and methylpyrene (MPy) series. The measured maturity indices, MPI, DMPI and MPyI which appeared previously suitable for rocks, coals and crude oils have been tested for the recognition of rank levels of condensates. MPI and DMPI exhibit a remarkedly similar evolution which allows the differentiation of the samples analysed in these works. Such studies extend the applicability of alkylaromatic hydrocarbon ratios to the characterization of maturity level of condensates which range from immature-marginally mature to overmature samples, partially biodegraded or not.  相似文献   

Non-aromatic biomarkers associated with a Palaeogene salt formation (Bresse, France)     

P. Baranger  J.R. Disnar   《Organic Geochemistry》1988,13(4-6)

This study provides information on non-aromatic hydrocarbons contained in thick Palaeogene halite sequences in the Bresse region (France). The presence of almost uniquely biological markers and the absence of thermogenic compounds denote the low maturity of the corresponding samples consistent with Rock-Eval pyrolysis data. The distribution of n-alkanes enables the distinction of three main biological signatures: algal (mode in nC17–nC18); terrestrial (mode in nC29–nC31) and bacterial (mode in nC25–nC26 with no odd-even carbon number predominance). As to the cyclic biomarkers, hopanes and hopenes are largely predominant over steranes and diasterenes in samples having received appreciable amounts of terrestrial inputs (Type B) and conversely for the samples containing high proportions of algal debris (Type A, Type C).  相似文献   

Biomarker characterisation and hydrous pyrolysis of bitumens from Tertiary volcanics, queen Charlotte islands, British Columbia, Canada     

M.G. Fowler  L.R. Snowdon  P.W. Brooks  T.S. Hamilton 《Organic Geochemistry》1988,13(4-6)

A number of bitumen samples have been recovered from vugs and fractures in outcropping Tertiary basalts of the Queen Charlotte Islands off the west coast of British Columbia, Canada. n-Alkanes and acyclic isoprenoids are not present and the polycyclic biomarker distribution of the four samples analyzed by GC and GC-MS has been altered. One sample contains no remaining recognizable biomarkers. Two bitumens were also obtained from Lower Jurassic potential source rocks, including one from the Sandilands Formation, which was considered previously to be the most likely source of the Tertiary bitumens. Although these two bitumens were also taken from outcrops, they are considerably less biodegraded. The Sandilands Formation bitumen contains 28, 30-bisnorhopanes and since these compounds were not detected in the Tertiary bitumens, there is no evidence from the initial results for a Sandilands Formation contribution to the hydrocarbons in the Tertiary basalts. The presence of 18α(H)-oleanane in the saturate fraction of two of the Tertiary bitumens from widely separated locations indicates that they are at least partially sourced from Tertiary organic matter.Because the distribution of biomarkers in some samples has been severely affected by biodegradation, the asphaltenes of the bitumens were hydrously-pyrolysed and the saturate fractions of the resulting pyrolysates analysed for possible additional information on the origin of the bitumens. The pyrolysates from the more degraded samples contain compounds not detected in the saturate fractions of the original bitumen and show some of the expected characteristics of the original non-degraded bitumen. However, the compounds most useful for correlation are not present in the pyrolysates apparently due to their non-incorporation into the kerogen macromolecule. Our results suggest that hydrous-pyrolysis of asphaltenes is of limited use in the correlation of biodegraded samples and in determining their origins.  相似文献   

Degradation of Tetrachloroethene by Several Co-metabolism Substrates in Groundwater          下载免费PDF全文

SHI Jinghua LIU Fei CHEN Honghan LI Ye 《《地质学报》英文版》2007,81(5):827-832

Tetrachloroethene （PCE） is biodegraded by reductive dechlorination with co-metabolism substrates under anaerobic conditions. By inoculating sludge from an anaerobic pool, a biodegradation test of PCE is conducted in the anaerobic condition. In the test, several substrates including methanol, ethanol, formate, acetate, lactate and glucose, are conducive to the conversion from PCE to TCE and 1,1-DCE. The results show the microbe can be cultivated well under the anaerobic circumstances of mixture of sewage （sludge） and soil with the index of COD after eleven days. Degradation of PCE accords with one order reaction kinetics equation. The sequence of the reaction rate constant is Kacetate 〉Kglucose 〉 Klactate 〉 Kethanol 〉 Kformate 〉 Kmethanol, and acetate is an outstanding co-metabolism substratum whose reaction rate constant is 0.6632d^-1.  相似文献   

Preliminary study on PAH degradation by bacteria from contaminated sediments in Xiamen Western Sea,Fujian, China   总被引：1，自引：0，他引：1  

哈里德郑天凌  洪华生俞志明  袁建军胡忠 《中国海洋湖沼学报》2004,22(4):431-435

In order to estimate the biodegradation of three polycyclic aromatic hydrocarbons (PAHs) compounds, bacterial strains were isolated from marine sediments in three heavily contaminated sites (Yuandang Lake, Dongdu Port and Aquacultural zones in Maluan Bay) in Xiamen Western Sea. The results show three bacterial strains, which used pyrene as the sole carbon source, were identified as strains of Aureobacterium sp.,Arthrobacter sp., Rhodococcus sp. The PAH-degrading bacteria isolated had a strong ability to degrade phenanhrene, fluoranthene and pyrene at different degradation rates. The highest degradation rate was observed when three PAH compounds were mixed with an individual strain in the medium. The three PAHs were degraded after one week with a degradation rate of 89.94 % for phenanthrene and 93.4 % for both of fluoranthene and pyrene.In addition, after 25 days of incubation, the degradation rate was 99.98 % for phenanthrene and 99.97 % for both of fluoranthene and pyrene. Optical density was measured to estimate bacterial growth during the degradation of PAHs. Highest levels of bacterial growth were observed with a three PAH mixture in the culture, suggesting that the concentration of PAHs influenced bacterial growth and the highest levels of degradation for most series were detected after one week of incubation.  相似文献   

吸附对土壤水环境中有机污染物生物降解过程的影响研究   总被引：11，自引：1，他引：10  

刘凌  崔广柏 《水科学进展》2000,11(4):401-407

在土壤水环境系统中,吸附作用是影响有机污染物生物降解过程的主要制约因素。污染物的吸附性越强,则其存在于土壤水溶液的重量百分比就越小,生物降解可能性也就越低。本文建立了定量描述吸附作用对有机污染物在土壤颗粒内部传输过程影响的数学模型。通过模型计算发现,有机污染物的土壤-水吸附分配系数Kd越大,则其从土壤颗粒内部传输到外部水溶液的速率就越小,总的降解速率也就越低。  相似文献   

地质微生物作用与油气资源     

王万春  陶明信 《地质通报》2005,(Z1)

地质微生物作用与油气资源的生成、保存、破坏、开采和勘探的各个环节都有着密切的联系。微生物(细菌)本身不仅是良好的成烃母质,还是促使有机物转化为石油烃的主要营力。微生物作用使沉积有机质向更有利于生烃的物质转化,并使有机质中表征成熟度的一些指标在尚未受热成熟作用前就显示成熟特征。沉积环境中微生物的发育对有机质的贡献与保存有积极作用,细菌对有机质的降解也有利于有机质中成烃组分的保存与富集。微生物作用生成的天然气、煤层气和甲烷水合物在世界各地已成为有商业开采价值的资源。然而,微生物对已成藏的油气资源又具有破坏作用。储层中喜氧与厌氧菌的存在,不仅破坏石油储量,还使原油质量明显下降。  相似文献