Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

Late Holocene changes in vegetation and atmospheric circulation at Lake Uddelermeer (The Netherlands) reconstructed using lipid biomarkers and compound‐specific δD analysis          下载免费PDF全文

《第四纪科学杂志》2018,33(1):100-111

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一套具有更高时空分辨率的全球海洋叶绿素浓度遥感融合产品数据集     

肖艳芳  张杰  崔廷伟  孙凌 《海洋学报(英文版)》2018,37(7):118-130

认识海洋在全球碳循环中的作用及其对环境变化的响应，需要高时空分辨率的观测数据。由于轨道宽度、云雨天气、太阳耀斑等的影响，单一的水色传感器的观测能力十分有限，将多源海洋水色卫星进行融合是提高水色数据时空覆盖的一种有效途径。SeaWiFS和MERIS分别于2010年12月11日和2012年5月9日停止运行，在很大程度上降低了水色融合产品时空覆盖的提升。我们在融合过程中加入了FY-3 MERSI数据，生成了全球海洋叶绿素浓度遥感融合产品数据集。数据源包括SeaWiFS、MERIS、MODIS-Aqua、VIIRS和MERSI。结果表明：加入MERSI后，融合产品的日平均有效空间覆盖提高了9%；采样频率（同一区域一年中获取有效数据的次数）由57天/年提高到109天/年。利用实测数据和国外同类融合产品（ESA GlobColour和NASA MEaSUREs）对新的数据集进行了质量评价。与实测数据相比，加入MERSI的融合产品精度与未加入MERSI的融合产品基本一致；与国外同类融合产品的偏差小于10%。新数据集的时间序列特性与未加入MERSI的融合产品以及单传感器的一致。  相似文献   

江苏重点海域绿潮漂移扩散数值模拟   总被引：1，自引：0，他引：1  

吉会峰  刘吉堂  莫旭冬  高鑫鑫  杨波 《海洋科学》2018,42(5):82-91

江苏海域是绿潮灾害的多发海域,本文利用MIKE3模型建立了江苏辐射沙洲重点海域三维水动力模型,并采用实测资料对模型进行验证和率定;在水动力模型的基础上建立绿潮漂移扩散模型,对江苏海域绿潮漂移路径进行了模拟并与卫星遥感监测的结果进行对比。对比结果表明,模型24 h和48 h模拟结果与卫星遥感图像分析结果较吻合,模型能为江苏海域绿潮的预警预报提供一定参考。  相似文献   

Response and capacity of monopod caisson foundation under eccentric lateral loads     

Tanmoy Kumar Deb  Baleshwar Singh 《Marine Georesources & Geotechnology》2018,36(4):452-464

Monopod caisson foundation is a viable alternative for supporting offshore wind turbines located at shallow water depths. This foundation system has to resist overturning moment generated due to resultant lateral load, arising from wind and water wave action, that can act at any loading height above the seabed. This paper presents results of a numerical investigation performed to determine the influence of loading height, caisson geometry and superstructure load on the ultimate lateral capacity, initial stiffness, and soil failure zone of the foundation, when installed in very dense sand. Both the ultimate and serviceable states of the caisson foundation obtained from the analyses are represented in terms of envelopes plotted between lateral load and overturning moment. Simplified expressions, which take into account the influence of caisson geometry, loading height, and soil properties, are also presented to serve as a preliminary base for design of the monopod caisson foundation.  相似文献   

Modelling the effect of changing precipitation inputs on deep soil water utilization          下载免费PDF全文

Ji Qi  Daniel Markewitz  David Radcliffe 《水文研究》2018,32(5):672-686

Forests in the Southeastern United States are predicted to experience future changes in seasonal patterns of precipitation inputs as well as more variable precipitation events. These climate change‐induced alterations could increase drought and lower soil water availability. Drought could alter rooting patterns and increase the importance of deep roots that access subsurface water resources. To address plant response to drought in both deep rooting and soil water utilization as well as soil drainage, we utilize a throughfall reduction experiment in a loblolly pine plantation of the Southeastern United States to calibrate and validate a hydrological model. The model was accurately calibrated against field measured soil moisture data under ambient rainfall and validated using 30% throughfall reduction data. Using this model, we then tested these scenarios: (a) evenly reduced precipitation; (b) less precipitation in summer, more in winter; (c) same total amount of precipitation with less frequent but heavier storms; and (d) shallower rooting depth under the above 3 scenarios. When less precipitation was received, drainage decreased proportionally much faster than evapotranspiration implying plants will acquire water first to the detriment of drainage. When precipitation was reduced by more than 30%, plants relied on stored soil water to satisfy evapotranspiration suggesting 30% may be a threshold that if sustained over the long term would deplete plant available soil water. Under the third scenario, evapotranspiration and drainage decreased, whereas surface run‐off increased. Changes in root biomass measured before and 4 years after the throughfall reduction experiment were not detected among treatments. Model simulations, however, indicated gains in evapotranspiration with deeper roots under evenly reduced precipitation and seasonal precipitation redistribution scenarios but not when precipitation frequency was adjusted. Deep soil and deep rooting can provide an important buffer capacity when precipitation alone cannot satisfy the evapotranspirational demand of forests. How this buffering capacity will persist in the face of changing precipitation inputs, however, will depend less on seasonal redistribution than on the magnitude of reductions and changes in rainfall frequency.  相似文献   

Properties of geogrid-reinforced marine slope due to the groundwater level changes     

Ramin Vali  Jie Li  Gholamreza Shams  Pieter van Gelder 《Marine Georesources & Geotechnology》2018,36(6):735-748

Evaluation of slope stability, especially in the absence of a proper bed such as marine soils, is one of the most important issues in geotechnical engineering. Using geogrid layers to enhance the strength and stability of embankments is regarded as a commendable stabilization method. On the other hand, groundwater level erratically fluctuates in coastal areas. Therefore, the aim of this research is to study the effects of groundwater level changes on stability of a geogrid-reinforced slope on loose marine soils in Qeshm Island, Iran. At first, geotechnical properties of the site were obtained by comprehensive series of geotechnical laboratory and in situ tests. Then, by simultaneous changes of groundwater level and several parameters such as embankment slope, loading, geogrid length, geogrid number, and tensile strength of geogrid, different characteristics such as embankment safety factor (SF), vertical and horizontal displacements at embankment top and embankment base were studied. It was observed that groundwater level had significant effects on behavior of the embankment. For most of the observations, by decreasing the groundwater level, the displacements decreased and consequently safety factor increased. Increasing the length, number, and tensile strength of geogrid led to the reduction of displacements and an increase in the safety factor.  相似文献   

基于圆柱多段拟合的隧道中轴线提取方法研究     

荆海峰  李广云  王力  杨文锋 《大地测量与地球动力学》2018,38(2):211-215

提出基于圆柱多段拟合的隧道中轴线提取方法。首先对隧道点云数据进行预处理，并将点云按隧道走向分成不同区段；然后对各区段依据轴线与表面点云法线垂直关系，提取精度较低的中轴线；最后对各区段利用圆柱多段拟合，提取精度较高的中轴线。实验表明，隧道中轴线的提取在一定的采样区间具有较高的稳定性，对直线和弯曲的圆形隧道有良好的适用性，算法可靠，精度较高。  相似文献   

关于地震科学实验场的一些思考——地下云图     

陈颙  徐逸鹤  蔡辉腾  李稳 《中国地震》2018,34(2):165-171

由中国地震局和美国国家科学基金委、地质调查局合作建立的地震预报研究实验场为中国早期地震工作的发展起到了良好的推动作用。由于种种客观原因,地震预报实验场的多数预想目标未能达成,发展受到了阻碍。最近几年,实验场重新受到重视,并更名为"地震科学实验场"。结合目前地震学发展的前沿和防震减灾事业的实际需求,本文提出增加"地下云图"作为实验场的新方向。利用高重复性、环境友好、安全性高的气枪震源,持续激发地震信号,实现对地下介质速度变化的连续监测;结合背景噪声成像获得的高分辨率3维地壳结构,构建4维(三维空间+一维时间)地下结构成像。"地下云图"可以反映地下速度和应力变化,为全国范围的地震监测预测提供新的业务手段,推动地震预测从经验预测到物理预测的转换。  相似文献   

鄱阳湖湿地典型植被群落地下水—土壤—植被—大气系统界面水分通量及水源组成     

许秀丽  李云良  谭志强  张奇 《湖泊科学》2018,30(5):1351-1367

地下水-土壤-植被-大气系统(GSPAC)界面水分传输是湿地生态水文过程研究的关键.本文选取鄱阳湖湿地高位滩地的2种典型植被群落:茵陈蒿(Artemisia capillaris)和芦苇(Phragmites australis)群落为研究对象,运用HYDRUS-1D垂向一维数值模拟,量化了湿地GSPAC系统界面水分通量,阐明了典型丰水年(2012年)和枯水年(2013年)鄱阳湖湿地植被群落的蒸腾用水规律和水源组成.结果表明:(1)茵陈蒿和芦苇群落土壤-大气界面的年降水入渗量为1570~1600 mm,主要集中在雨季4-6月,占年总量的60%;植物-大气界面的年蒸腾总量分别为346~470 mm和926~1057 mm,其中7-8月植被生长旺季最大,占年总量的40%~46%;地下水-根区土壤界面的向上补给水量受不同水文年水位变化的影响显著,地下水年补给量分别为15~513 mm和277~616 mm,主要发生在蒸散发作用强烈和地下水埋深较浅的时段.(2)植被蒸腾用水分为生长初期(4-6月)和生长旺季(7-10月)2个阶段,丰水年植被的整个生长期蒸腾用水充足,枯水年植被生长旺季的蒸腾用水受到严重水分胁迫,实际蒸腾量仅为潜在蒸腾量的一半左右.(3)不同水文年湿地植被生长旺季的水源贡献不同:丰水年茵陈蒿群落以地下水补给为主,芦苇群落以湖水和地下水补给为主;枯水年茵陈蒿群落以降水和前期土壤水储量为主,芦苇群落以地下水补给为主.本研究结果有助于揭示湿地植被的水分利用策略,为阐明湖泊水情变化与植被演替的作用机理提供参考依据.  相似文献