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1.
The 33 086 ha mixed land use Fall Creek watershed in upstate New York is part of the Great Lakes drainage system. Results from more than 3500 water samples are available in a data set that compiles flow data and measurements of various water quality analytes collected between 1972 and 1995 in all seasons and under all flow regimes in Fall Creek and its tributaries. Data is freely accessible at https://ecommons.cornell.edu/handle/1813/8148 and includes measurements of suspended solids, pH, alkalinity, calcium, magnesium, potassium, sodium, chloride, nitrate nitrogen (NO3-N), sulphate sulphur (SO4-S), phosphorus (P) fractions molybdate reactive P (MRP) and total dissolved P (TDP), percent P in sediment, and ammonium nitrogen (NH4-N). Methods, sub-watershed areas, and coordinates for sampling sites are also included. The work represented in this data set has made important scientific contributions to understanding of hydrological and biogeochemical processes that influence loading in mixed use watersheds and that have an impact on algal productivity in receiving water bodies. In addition, the work has been foundational for important regulatory and management decisions in the region.  相似文献   
2.
Wildfire increases the potential connectivity of runoff and sediment throughout watersheds due to greater bare soil, runoff and erosion as compared to pre-fire conditions. This research examines the connectivity of post-fire runoff and sediment from hillslopes (< 1.5 ha; n = 31) and catchments (< 1000 ha; n = 10) within two watersheds (< 1500 ha) burned by the 2012 High Park Fire in northcentral Colorado, USA. Our objectives were to: (1) identify sources and quantify magnitudes of post-fire runoff and erosion at nested hillslopes and watersheds for two rain storms with varied duration, intensity and antecedent precipitation; and (2) assess the factors affecting the magnitude and connectivity of runoff and sediment across spatial scales for these two rain storms. The two summer storms that are the focus of this research occurred during the third summer after burning. The first storm had low intensity rainfall over 11 hours (return interval <1–2 years), whereas the second event had high intensity rainfall over 1 hour (return interval <1–10 years). The lower intensity storm was preceded by high antecedent rainfall and led to low hillslope sediment yields and channel incision at most locations, whereas the high intensity storm led to infiltration-excess overland flow, high sediment yields, in-stream sediment deposition and channel substrate fining. For both storms, hillslope-to-stream sediment delivery ratios and area-normalised cross-sectional channel change increased with the percent of catchment that burned at high severity. For the high intensity storm, hillslope-to-stream sediment delivery ratios decreased with unconfined channel length (%). The findings quantify post-fire connectivity and sediment delivery from hillslopes and streams, and highlight how different types of storms can cause varying magnitues and spatial patterns of sediment transport and deposition from hillslopes through stream channel networks.  相似文献   
3.
Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   
4.
Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   
5.
基于地缘政治视角,分析本世纪初发生在原苏联地区“颜色革命”的诱发因素,认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性,国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上,结合中亚五国形势,从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判,得出1) 整体来看,中亚近期内爆发“颜色革命”可能性较小,但从长远来看不能掉以轻心。2)土、乌未来稳定可期,塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   
6.
首先利用ALOS PALSAR数据,通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场,然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布,最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明,形变主要集中在西盘,最大视线向形变量为51.6 cm;反演得到的震源位置为23.05°N、101.02°E,深度3 km,断层走向145°,倾向49.5°,平均滑动角153°,发震断层为NNW向普洱断裂,断层活动以右旋走滑为主,兼具逆冲分量;断层面最大滑动量为1.2 m,反演得到的震级为MW619。基于库仑应力场发现,磨黑断裂处于库仑应力增加区域,而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明,宁洱地震为浅源地震,但断层并未出露地表。  相似文献   
7.
将微粒群算法与位错理论模型相结合,采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据,通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演,并与蚁群算法反演结果进行对比。结果表明,微粒群算法收敛速度快、稳定性高,结合经典位错理论模型,是一种可以有效求解断层三维滑动速率反演问题的优化算法,在大地测量反演领域极具应用潜力。  相似文献   
8.
烃源岩中的有机酸来源于有机质,但有机质具有不同的赋存形式,有机酸具有不同性质,这将影响有机酸与不同赋存有机质的关系,进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上,提出烃源岩中的有机酸并以非单一的形式存在,具有水溶性、脂溶性和难溶性有机酸三种类型,游离有机质中存在水溶性和脂溶性有机酸,而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法,且根据有机酸的性质选取合适的检测方法,即水溶性有机酸利用离子色谱检测,索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测,通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测,全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律,深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   
9.
针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10-3μm2)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。  相似文献   
10.
为实现钻井指挥部对各钻井站点钻采工艺的远程监控,在前期钻井工艺参数自动实时监测的单机研发基础上,本文应用TIA portal软件进行主站从站组网监控研究,实验设备用Siemens1200PLC做主控机,用Siemens200PLC做从站控制机监控钻采现场工艺参数,通过主控机与各从站点组态,实现主控机对从站主从控制。装机后在钻采现场进行了无线网传输实验,实验结果表明:应用互联网通信技术解决无线网断点续传问题,能够实现了钻采实时监控数据短距离传输。  相似文献   
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