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1.
Hydrogeochemical based mixing models have been successfully used to investigate the composition and source identification of streamflow. The applicability of these models is limited due to the high costs associated with data collection and the hydrogeochemical analysis of water samples. Fortunately, a variety of mixing models exist, requiting different amount of data as input, and in data scarce regions it is likely that preference will be given to models with the lowest requirement of input data. An unanswered question is if models with high or low input requirement are equally accurate. To this end, the performance of two mixing models with different input requirement, the mixing model analysis (MMA) and the end-member mixing analysis (EMMA), were verified on a tropical montane headwater catchment (21.7 km2) in the Ecuadorian Andes. Nineteen hydrogeochemical tracers were measured on water samples collected weekly during 3 years in streamflow and eight potential water sources or end-members (precipitation, lake water, soil water from different horizons and springs). Results based on 6 conservative tracers, revealed that EMMA (using all tracers) and MMA (using pair-combinations out of the 6 conservative ones), identified the same end-members: rainfall, soil water and spring water., as well as, similar contribution fractions to streamflow from rainfall 21.9% and 21.4%, soil water 52.7% and 52.3%, and spring water 26.1% and 28.7%, respectively. Our findings show that a hydrogeochemical mixing model requiring a few tracers can provide similar outcomes than models demanding more tracers as input data. This underlines the value of a preliminary detailed hydrogeochemical characterization as basis to derive the most cost-efficient monitoring strategy.  相似文献   
2.
Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   
3.
4.
To enhance the utilization efficiency of farmland irrigation water and reduce the leakage of water conveyance channels, the leakage process of channels was simulated dynamically. The simulated results were compared with data measured in laboratory experiments, and the performance of the model was evaluated. The results indicated that the simulated values of the model were consistent with the observation values, and the R2 values varied between 0.91 and 0.99. In addition, based on the laboratory experiments, a water supply system (Mariotte bottles) and soil box were built using plexiglass. Three influencing factors, namely, the channel form, soil texture and channel cross-sectional area, were varied to observe and calculate the resulting cumulative infiltration amount, infiltration rate and wetting front migration distance. HYDRUS-3D software was used to solve the three-dimensional soil water movement equation under different initial conditions. The results demonstrated that the U-shaped channel was more effective than the trapezoidal channel in increasing the utilization efficiency of the water resources. A U-shaped channel with a small channel cross-sectional area should be adopted and the soil particle size should be prioritized in the construction of water conveyance channels for farmlands. The simulation results were in agreement with the observed results, which indicates that HYDRUS-3D is a reliable tool that can accurately simulate the soil moisture movement in water conveyance channels. The research results can provide a reference for the design and operation of farmland irrigation systems.  相似文献   
5.
在太阳大气不同层次连续光谱中叠加有丰富的发射线或吸收线,对这些谱线轮廓进行反演分析可以探测太阳大气的化学成分和物理状态.太阳大气的色球及过渡区由于其密度低难以建立热动平衡,建立相应的大气模型需要采用非局部热动平衡(Non-Local Thermodynamic Equilibrium,N-LTE)理论.根据相对偏离因子计算来研究太阳中低层大气偏离局部热动平衡(Local Thermodynamic Equilibrium,LTE)分布的情况.首先对日全食观测过程中得到色球和过渡区不同高度形成的两条光谱数据进行反演,得到确定观测谱线的参数信息,如连续谱源函数、谱线源函数、多普勒宽度和由此推出的等效动力学温度;根据这些反演出的谱线参量计算出二维视场内每个空间采样点偏离LTE状态的定量结果;其次,根据用于观测的积分视场单元光纤排布阵列重构出辐射强度、等效动力学温度和相对偏离因子二维分布.结果显示:在局部小区域,温度分布和相对偏离因子的分布存在较强相关性,而与辐射强度分布无明显相关.从两条谱线导出的等效温度和相对偏离因子分布存在明显的差异.这两种二维分布揭示出太阳大气某些小尺度区域具有较强的结构性和复杂性,为进一步理解太阳中低层大气物理提供了一种新的视角.  相似文献   
6.
Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   
7.
Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   
8.
基于地缘政治视角,分析本世纪初发生在原苏联地区“颜色革命”的诱发因素,认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性,国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上,结合中亚五国形势,从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判,得出1) 整体来看,中亚近期内爆发“颜色革命”可能性较小,但从长远来看不能掉以轻心。2)土、乌未来稳定可期,塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   
9.
首先利用ALOS PALSAR数据,通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场,然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布,最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明,形变主要集中在西盘,最大视线向形变量为51.6 cm;反演得到的震源位置为23.05°N、101.02°E,深度3 km,断层走向145°,倾向49.5°,平均滑动角153°,发震断层为NNW向普洱断裂,断层活动以右旋走滑为主,兼具逆冲分量;断层面最大滑动量为1.2 m,反演得到的震级为MW619。基于库仑应力场发现,磨黑断裂处于库仑应力增加区域,而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明,宁洱地震为浅源地震,但断层并未出露地表。  相似文献   
10.
将微粒群算法与位错理论模型相结合,采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据,通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演,并与蚁群算法反演结果进行对比。结果表明,微粒群算法收敛速度快、稳定性高,结合经典位错理论模型,是一种可以有效求解断层三维滑动速率反演问题的优化算法,在大地测量反演领域极具应用潜力。  相似文献   
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