Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   

利用InSAR资料反演宁洱Ms6.4地震震源参数及库仑应力变化     

陈晨月  冯光财  高华  杨怀宁 《大地测量与地球动力学》2019,39(3):295-301

首先利用ALOS PALSAR数据，通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场，然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布，最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明，形变主要集中在西盘，最大视线向形变量为51.6 cm；反演得到的震源位置为23.05°N、101.02°E，深度3 km，断层走向145°，倾向49.5°，平均滑动角153°，发震断层为NNW向普洱断裂，断层活动以右旋走滑为主，兼具逆冲分量；断层面最大滑动量为1.2 m，反演得到的震级为MW619。基于库仑应力场发现，磨黑断裂处于库仑应力增加区域，而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明，宁洱地震为浅源地震，但断层并未出露地表。  相似文献   

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率     

刘杰 《大地测量与地球动力学》2019,39(9):906-909

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

BDS卫星差分码偏差稳定性分析及其短期预报     

梅登奎  闻德保 《大地测量与地球动力学》2020,40(7):746-750

利用MGEX(multi-GNSS experiment)发布的BDS卫星差分码偏差(differential code bias, DCB)产品，比较分析不同太阳活动水平下BDS卫星DCB产品的稳定性变化特性，并采用差分自回归移动平均(auto-regressive integrated moving average, ARIMA)时间序列预测模型，实现不同太阳活动水平下BDS卫星DCB的短期预报。结果表明，在太阳活动高年，BDS卫星DCB日解值稳定度、月稳定性均明显低于太阳活动低年，且不同卫星星座类型的BDS卫星DCB稳定性也存在差异；ARIMA时间序列预报结果与MGEX发布值符合程度较好，优于多项式拟合法预测结果。  相似文献   

Effect of Caliche Nodules on Soil Water Storage in the Northern Loess Plateau of China     

Tiexiong Gong  Yuanjun Zhu  Yunqiang Wang  Wei Hu  Ming'an Shao 《洁净——土壤、空气、水》2019,47(7)

  相似文献   

浅析广安华蓥山区山水林田湖综合治理措施——以高顶山矿区为例     

李飞  裴云婧  王维  李德星  张春茂 《四川地质学报》2020,40(1):80-85

高顶山矿区位于广安华蓥市城区东南约5km处。长期的采矿活动,导致区内矿山地质环境问题突出,严重影响华蓥山地区人民的生命财产安全。矿山地质环境问题亟待解决。本文通过分析区内主要存在的矿山地质环境问题,提出通过矿山地质灾害、矿山土地恢复、矿山地形地貌景观恢复治理,河道综合整治、道路修复、生态保育、产业提升等措施;消除安全隐患,保障区内人民生命财产安全;改善生态环境,实现华蓥山地区生态环境全面恢复,生态环境质量提升,提高环境承载力,实现区内"山青、水秀、林美、田良"的目标。并对区内的产业转型升级进行了探讨,提出将高顶山矿区建设成具有科普和教育价值的旅游景观目的地;利用矿区独具特色工业人文景观和别致的自然景观,将高顶山矿区建设成集"科普、休闲、康养、户外、探秘"五大功能于一体的矿山公园,推动矿业经济转型升级,促进产业结构转型和经济社会可持续发展。  相似文献   

北大巴山早古生代辉绿岩地球化学特征及其地质意义     

张方毅  赖绍聪  秦江锋  朱韧之  杨航  朱毓 《岩石矿物学杂志》2020,39(1):35-46

对南秦岭北大巴山地区广泛分布的一套基性岩墙群中的辉绿岩进行采样,并进行了锆石U-Pb年代学、全岩地球化学分析。结果显示,岩石形成年龄为435~433 Ma,为早志留世晚期岩浆活动产物。这些辉绿岩具低硅、高碱、高钛的碱性岩特征。岩石微量及稀土元素具板内玄武岩特征,轻稀土元素相对富集,轻重稀土元素分异明显,富集不相容元素Ba、Nb、Ta,而K、Y、Yb相对亏损;K及Rb的负异常表明岩石源区残留角闪石或金云母,部分熔融模拟结果显示岩石起源于尖晶石角闪石岩高程度部分熔融。综合地球化学特征及前人研究结果,认为北大巴山地区在早古生代处于大规模伸展裂陷背景下,岩石圈的拉张诱发了低熔点的交代岩石圈地幔熔融,进而形成了这条碱性岩浆带。  相似文献