Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

Finding KBO Flyby Targets for New Horizons     

Spencer  John  Buie  Marc  Young  Leslie  Guo  Yanping  Stern  Alan 《Earth, Moon, and Planets》2003,92(1-4):483-491

Development of the New Horizons mission to Pluto and the Kuiper Belt is now fully funded by NASA (Stern and Spencer, this volume). If all goes well, New Horizons will be launched in January 2006, followed by a Jupiter gravity assist in 2007, with Pluto arrival expected in either 2015 or 2016, depending on the launch vehicle chosen. A backup launch date of early 2007, without a Jupiter flyby, would give a Pluto arrival in 2019 or 2020. In either case, a flyby of at least one Kuiper Belt object (KBO) is planned following the Pluto encounter, sometime before the spacecraft reaches a heliocentric distance of 50 AU, in 2021 or 2023 for the 2006 launch, and 2027 or 2029 for the 2007 launch. However, none of the almost 1000 currently-known KBOs will pass close enough to the spacecraft trajectory to be targeted by New Horizons, so the KBO flyby depends on finding a suitable target among the estimated 500,000 KBOs larger than 40 km in diameter. This paper discusses the issues involved in finding one or more KBO targets for New Horizons. The New Horizons team plans its own searches for mission KBOs but will welcome other U.S, or international team who wish to become involved in exchange for mission participation at the KBO.  相似文献   

Three Super Active Regions in the Descending Phase of Solar Cycle 23   总被引：2，自引：0，他引：2  

Hong-Qi Zhang  Xing-Ming Bao  Yin Zhang  Ji-Hong Liu  Shu-Dong Bao  Yuan-Yong Deng  Wei Li  Jie Chen  Jin-Ping Dun  Jiang-Tao Su  Juan Guo  Xiao-Fan Wang  Ke-Liang Hu  Gang-Hua Lin  Dong-Guang WangNational Astronomical Observatories  Chinese Academy of Sciences  Beijing   《中国天文和天体物理学报》2003,3(6):491-494

We analyze the magnetic configurations of three super active regions, NOAA 10484, 10486 and 10488, observed by the Huairou Multi-Channel Solar Telescope (MCST) from 2003 October 18 to November 4. Many energetic phenomena, such as flares (including a X-28 flare) and coronal mass ejections (CMEs), occurred during this period. We think that strong shear and fast emergence of magnetic flux are the main causes of these events. The question is also of great interest why these dramatic eruptions occurred so close together in the descending phase of the solar cycle.  相似文献   

ELECTROCHEMICAL CORROSION BEHAVIOR OF STEEL IN THE JUNCTURE AREA OF SEA CLAY AND SAND     

张经磊  侯保荣  郭公玉  杨芳英  谢肖勃 《中国海洋湖沼学报》1993,11(2):171-175

Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed.  相似文献   

在社会发展的层面上认识“数字地球”   总被引：1，自引：0，他引：1  

郭仁忠  林亨贵 《地球信息科学学报》2001,3(1):50-53

 本文讨论了“数字地球”的有关问题。指出“数字地球”是人类社会及其活动在网络空间的延伸和拓展,是信息技术带来的社会发展趋势。关于“数字地球”的讨论不应局限在空间信息技术领域,而应该在社会发展的层面上认识它  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

天文光干涉与综合孔径技术的发展     

郭红锋 《紫金山天文台台刊》2003,(1)

本文简单介绍了光干涉与综合孔径技术发展的历史、国际上用于天文观测的一些著名光干涉仪的技术特点和进展、以及近年来我国开展的与光干涉 ,综合孔径技术有关的工作 ,最后简要介绍了在光学综合孔径技术领域所发展的光纤与集成光学等新技术  相似文献   

EFFECT OF SULPHATE-REDUCING BACTERIA ON ELECTRO-CHEMICAL CORROSION BEHAVIOR OF 16Mn STEEL IN SEA MUD     

张经磊  侯保荣  郭公玉  孙虎元  徐岩 《中国海洋湖沼学报》2001,19(1):87-90

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｗａｓｇｅｎｅｒａｌｌｙｃｏｎｓｉｄｅｒｅｄｐｒｅｖｉｏｕｓｌｙｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｏｆｓｔｅｅｌｉｎｓｅａｍｕｄｗａｓｎｏｔｓｅｒｉｏｕｓ.Ｈｏｗｅｖｅｒ,ｉｔｗａｓｌａｔｅｒｆｏｕｎｄｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒａｔｅｏｆｓｔｅｅｌｉｎｓｏｍｅｓｅａｍｕｄｗａｓｈｉｇｈｅｒｔｈａｎｔｈａｔｉｎｓｅａｗａｔｅｒ(Ｋｉｎｇ,1980;Ｓｅｈｍｉｄｅ,1982;Ｇｕｏｅｔａｌ.,1997;Ｈｏｕ,1998).Ｔｈｅｒｅａｒｅｓｏｍｅｒｅｐｏｒｔｓｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒ…  相似文献   

Automated Separation of Stars and Normal Galaxies Based on Statistical Mixture Modeling with RBF Neural Networks     

Dong-Mei Qin  Ping Guo  Zhan-Yi Hu  Yong-Heng ZhaoNational Laboratory of Pattern Recognition Laboratory  Institute of Automation  Chinese Academy of Sciences  Beijing  dmqin@nlpr.ia.ac.cnDepartment of Computer Sciences  Beijing Normal University  Beijing National Astronomical Observatories  Chinese Academy of Sciences  Beijing 《中国天文和天体物理学报》2003,3(3)

For LAMOST, the largest sky survey program in China, the solution of the problem of automatic discrimination of stars from galaxies by spectra has shown that the results of the PSF test can be significantly refined. However, the problem is made worse when the redshifts of galaxies are not available. We present a new automatic method of star/(normal) galaxy separation, which is based on Statistical Mixture Modeling with Radial Basis Function Neural Networks (SMM-RBFNN). This work is a continuation of our previous one, where active and non-active celestial objects were successfully segregated. By combining the method in this paper and the previous one, stars can now be effectively separated from galaxies and AGNs by their spectra-a major goal of LAMOST, and an indispensable step in any automatic spectrum classification system. In our work, the training set includes standard stellar spectra from Jacoby's spectrum library and simulated galaxy spectra of EO, SO, Sa, Sb types with redshift ranging from 0 to 1  相似文献