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Sr- and Ca-rich waylandite, $ {\left( {{\hbox{B}}{{\hbox{i}}_{0.{54}}}{\hbox{S}}{{\hbox{r}}_{0.{31}}}{\hbox{C}}{{\hbox{a}}_{0.{25}}}{{\hbox{K}}_{0.0{1}}}{\hbox{B}}{{\hbox{a}}_{0.0{1}}}} \right)_{\Sigma 1.12}}{{\hbox{H}}_{0.{18}}}{\left( {{\hbox{A}}{{\hbox{l}}_{{2}.{96}}}{\hbox{C}}{{\hbox{u}}_{0.0{2}}}} \right)_{\Sigma 2.98}}{\left[ {{{\left( {{{\hbox{P}}_{0.{97}}}{{\hbox{S}}_{0.0{3}}}{\hbox{S}}{{\hbox{i}}_{0.0{1}}}} \right)}_{\Sigma 1.00}}{{\hbox{O}}_4}} \right]_2}{\left( {\hbox{OH}} \right)_6} $ , from Wheal Remfry, Cornwall, United Kingdom has been investigated by single-crystal X-ray diffraction and electron microprobe analyses. Waylandite crystallises in space group R $ \overline 3 $ ? m, with the cell parameters: a?=?7.0059(7) Å, c?=?16.3431(12) Å and V?=?694.69(11) Å3. The crystal structure has been refined to R 1?=?3.76%. Waylandite has an alunite-type structure comprised of a rhombohedral stacking of (001) composite layers of corner-shared AlO6 octahedra and PO4 tetrahedra, with (Bi,Sr,Ca) atoms occupying icosahedrally coordinated sites between the layers.  相似文献   
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This paper provides insight into the quality of groundwater used for public water supply on the territory of Kikinda municipality (Vojvodina, Serbia) and main processes which control it. The following parameters were measured: color, turbidity, pH, KMnO4 consumption, TDS, EC, NH4 +, Cl?, NO2 ?, NO3 ?, Fe, Mn, total hardness, Ca2+, Mg2+, SO4 2+, HCO3 ?, K+, Na+, As. The correlations and ratios among parameters that define the chemical composition were determined aiming to identify main processes that control the formation of the chemical composition of the analyzed waters. Groundwater from 11 analyzed sources is Na–HCO3 type. Intense color and elevated organic matter content of these waters originate from humic substances. The importance of organic matter decay is assumed by positive correlation between organic matter content and TDS, HCO3 content. There is no evidence that groundwater chemistry is determined by the depth of captured aquifer interval. The main processes that control the chemistry of all analyzed water are cation exchange and feldspar weathering.  相似文献   
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The effect of climate change on maize production in the semi-humid and semi-arid, agro-climatic zones III-IV of Kenya was evaluated using two General Circulation Models (GCMs): the Canadian Climate Center Model (CCCM) and the Geophysical Fluid Dynamics Laboratory (GFDL), as well as the CERES-Maize model. Long-term climate data was obtained from three meteorological stations situated in eastern, central and western regions of Kenya, while maize data was obtained from six sites within the regions. The climate scenarios were projected to the year 2030. Temperature increases of 2·29 and 2·89°C are predicted by the CCCM and GFDL, respectively. Rainfall levels are predicted to remain unchanged, but there are thought to be shifts in distribution. It is predicted that the short-rains season (October–January) will experience some increased rainfall, while the long-rains season (April–July) will show a decrease. Maize yields are predicted to decrease in zone III areas, while an increase is predicted in zone IV areas. However, the predicted changes in yields are low since they all fall below 500 kg ha−1, except the Homa Bay site. Thus, to counter the adverse effects of climate change on maize production, it may be necessary to use early maturing cultivars, practice early planting, and in eastern Kenya, shift to growing maize during the short-rains season.  相似文献   
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Artisanal fisheries throughout the Mediterranean region are managed mostly by applying gear specific regulations. The data about the extent and dynamics by which littoral fish resources respond to commonly proposed changes of such regulations are lacking. Here the results of a 15 year (1995–2009) monitoring programme of littoral fish resources in a pilot region of island Vis aquatorium, central Adriatic Sea, are reported with the scope of investigating whether a more restrictive fishing regime (encompassing an increase in minimum inner layer mesh size of trammel net from 28 to 40 mm and excluding the trammel net from subsistence artisanal fishing) that has progressively been put in place during the study period has been accompanied by expected positive changes of littoral fish resources’ abundance, biomass and structure. Significant increases over time were observed in most of the community indices analyzed (abundance and biomass catch per unit effort, diversity indices) as well as a directional change in abundance and biomass catch composition of littoral fish resources. Positive responses were, however, primarily related with a recovery of Mullus surmuletus stock. Additionally, time-series analysis of ABC curves and their corresponding W index revealed that fish community in the study area was still moderately disturbed. Limited extent of conventional management restorative potential is further exacerbated by social issues – noncompliant behavior mainly among subsistence artisanal fishers and consequent resentment of commercial artisanal fishers. In order to improve further the state of the resources a more comprehensive set of management measures incorporating closed areas and a new approach actively involving fishers in the management process should be adopted.  相似文献   
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Summary The position of the high-latitude boundary for electrons of Ee>40 keV and Ee>1 MeV on a low-altitude satellite is studied. An assymetry of this boundary with respect to magnetic local time has been detected. This assymetry depends on geomagnetic activity. Changes of boundary position are more pronounced for lower energies than for higher. The boundary positions obtained by Intercosmos-13 are compared with those obtained by the OGO-6 and AZUR satellites.  相似文献   
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The Global Imager (GLI) aboard the Advanced Earth Observing Satellite-II (ADEOS-II) made global observations from 2 April 2003 to 24 October 2003. In cooperation with several institutes and scientists, we obtained quality controlled match-ups between GLI products and in-situ data, 116 for chlorophyll-a concentration (CHLA), 249 for normalized water-leaving radiance (nLw) at 443 nm, and 201 for aerosol optical thickness at 865 nm (Tau_865) and Angstrom exponent between 520 and 865 nm (Angstrom). We evaluated the GLI ocean color products and investigated the causes of errors using the match-ups. The median absolute percentage differences (MedPD) between GLI and in-situ data were 14.1–35.7% for nLws at 380–565 nm, 52.5–74.8% nLws at 625–680 nm, 47.6% for Tau_865, 46.2% for Angstrom, and 46.6% for CHLA, values that are comparable to the ocean-color products of other sensors. We found that some errors in GLI products are correlated with observational conditions; nLw values were underestimated when nLw at 680 nm was high, CHLA was underestimated in absorptive aerosol conditions, and Tau_865 was overestimated in sunglint regions. The error correlations indicate that we need to improve the retrievals of the optical properties of absorptive aerosols and seawater and sea surface reflection for further applications, including coastal monitoring and the combined use of products from multiple sensors.  相似文献   
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