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1.
Lallan Prasad Gupta Hodaka Kawahata Mio Ltakeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2006,56(2):191-196
Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions. 相似文献
2.
Lallan Prasad Gupta Hodaka Kawahata Mio Takeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2005,55(4):357-372
Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws. 相似文献
3.
Huillca Yoshiro Silva Matías Ovalle Carlos Quezada Juan Carlos Carrasco Sergio Villavicencio Gabriel Eduardo 《Acta Geotechnica》2021,16(3):699-709
Empirical evidence has shown that particle breakage affects the mechanical behaviour of granular materials. The source of this mechanism takes place at the particle scale, and the main consequence on the macromechanical behaviour is increasing compressibility. Due to the inverse correlation between particle size and particle crushing strength, coarse rockfill materials are particularly vulnerable to mechanical degradation due to particle breakage. However, such coarse materials do not fit in standard laboratory devices, and the alternative of large sample testing is usually unavailable or too expensive. Alternatively, recent works have proposed multi-scale approaches using the discrete element method (DEM) to carry out numerical testing of coarse crushable materials, although few studies have focused on size effects. This article presents the application of a DEM bonded-cell model to study particle size-strength correlation on angular rock aggregates. Each particle is modelled by a cluster of perfectly rigid polyhedral cells with Mohr–Coulomb contact law. Constant cell density within particles implies that the presence of potential fragmentation planes increases with size. Therefore, particle strength decreases with size. A comprehensive sensitivity analysis was carried out through 1477 particle crushing simulations in a given particle size. Based on published experimental data on calcareous rock aggregates, part of the simulations were used for calibration, and 97 additional simulations of a coarser size fraction were performed for validation. The results show a good agreement with the empirical data in terms of size effect and data scatter through Weibull statistics.
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5.
Seasonal variations of ozone are studied by taking into consideration both photochemical and dynamical processes. Assuming that the seasonal variations of total ozone amounts are linear combinations of photochemical equilibrium variations and those due to atmospheric motions, the observed variations of the total ozone amount seem reasonably to be explained.The concept mentioned above implies that the time scale of ozone might be rather short in the lower stratosphere. The order of the half restoration time was estimated to be 10 to 102 days in the lower stratosphere. Thus the estimated time scale of ozone must be somewhat longer than that of the temperature in the lower stratosphere, of which variation usually shows its maximum in the midwinter in middle latitudes, while that of ozone shows its maximum in the late winter or early spring. As the maximum values of both quantities would appear in the early summer without air motions, the similarity in the phase differences of temperature and ozone suggests the validity of the concept of this paper. 相似文献
6.
Labradorite was altered artificially by HC1 solution ranging from M = 1 to M = 0.003 at 245 and 230°C. The products of alteration were examined by X-ray diffraction, electron microscopy, electron diffraction, infrared spectroscopy and the electron microprobe and the solution was analyzed chemically.Amorphous silica only was formed in solutions with MHCl = 1 and MHCl = 0.3. In a solution with MHCl = 0.2, amorphous silica was initially formed, later dissolved and replaced by kaolinite. A mixture of microcrystalline boehmite and amorphous aluminosilicate was formed, altering to kaolinite in solutions with MHCl = 0.1 and 0.3. Small amounts of kaolinite were initially formed but the alteration soon stopped in solution with MHCl = 0.003. Relationships between the alteration processes and pH of the solutions can be roughly explained by using solubility diagrams assuming the congruent dissolution of labradorite and precipitation of the products in partial equilibrium. However, these assumptions are not valid with strongly acid solutions.The rate of dissolution of labradorite is controlled not only by its surface area, but also by the diffusion of matter through the layer of alteration products. 相似文献
7.
Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal 总被引：4，自引：4，他引：0
Akihiro Hachikubo Oleg Khlystov Alexey Krylov Hirotoshi Sakagami Hirotsugu Minami Yutaka Nunokawa Satoshi Yamashita Nobuo Takahashi Hitoshi Shoji Shin’ya Nishio Masato Kida Takao Ebinuma Gennadiy Kalmychkov Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329
We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ13C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ13C signatures at two sites where ethane δ13C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which 13C and deuterium were both highly depleted (mean δ13C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C2 δ13C–δD classification for hydrate-bound gas in either freshwater or marine environments. 相似文献
8.
LIU Chunlin ZHANG Chi TIAN Yongjun WANG Liangming LIN Longshan LI Yuan WATANABE Yoshiro 《中国海洋大学学报(英文版)》2022,21(1):236-242
After decades of low year classes,the stock of Japanese sardine(Sardinops melanostictus)has begun to recover since the mid-2000s.The hatch dates and otolith growth rates of age-0 juvenile sardine,which were collected in the subarctic Oyashio waters in autumn 2018,were determined from an otolith microstructure analysis.The sardines were hatched from late January to late April,while mostly in February and March.The otolith growth rate increased continuously up to 60 d after hatching and thereafter de-creased.The revealed growth rate in a crucial growth period is faster than that reported for juvenile sardines collected in the 1990s,which is coincided with the recent recovery trend of the sardine stock.Two groups with different hatch dates,growth histories,and migration routes were identified using unsupervised random forest clustering analysis.They were considered inshore and offshore migration individuals in accordance with recent researches.In the offshore group,a high proportion of sardine juveniles hatched late and grew faster in the Kuroshio-Oyashio transitional waters,a finding consistent with the hypothesis of growth-rate-dependent re-cruitment.This finding on the population composition and growth rate of juvenile sardine in the Oyashio waters can be a basis for an improved prediction of their survival and provides us with valuable information on the recruitment processes of this stock during the period of stock recovery. 相似文献
9.
Jeffrey Poort Oleg M. Khlystov Lieven Naudts Albert D. Duchkov Hitoshi Shoji Shin’ya Nishio Marc De Batist Akihiro Hachikubo Masato Kida Hirotsugu Minami Andrey Y. Manakov Marina V. Kulikova Alexey A. Krylov 《Geo-Marine Letters》2012,32(5-6):407-417
Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano. 相似文献
10.
Nakamura K. Wakabayashi H. Uto S. Ushio S. Nishio F. 《Geoscience and Remote Sensing Letters, IEEE》2009,6(2):277-281
To investigate the suitability of synthetic aperture radar (SAR) polarization data to estimate the sea-ice thickness in early summer in Lutzow-Holm Bay, Antarctica, we compared in situ ice thicknesses with the corresponding backscattering co-efficient for each polarization and the VV-to-HH backscattering ratio. The VV-to-HH backscattering ratio was derived from data acquired by ENVISAT Advanced SAR (ASAR). This ratio is related to the near-surface dielectric constant of the sea ice, which is, in turn, related to the developing process of ice and, thus, its thickness via changes in the near-surface sea-ice salinity. The sea ice encountered in the study area is close first-year pack ice and fast ice. For these old and relatively rough sea-ice types, the VV-to-HH backscattering ratio can be expected to depend on salinity-driven changes in the near-surface dielectric constant rather than changes of the surface roughness. We applied the empirical relationships between the ice thickness and the VV-to-HH backscattering ratio with the linear and logarithm fits to ASAR data. The linear fit gave the reliable result, with an rms error being 0.08 m and a correlation coefficient being 0.91, when compared to in situ fast-ice thickness. 相似文献