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1.
Wildfire increases the potential connectivity of runoff and sediment throughout watersheds due to greater bare soil, runoff and erosion as compared to pre-fire conditions. This research examines the connectivity of post-fire runoff and sediment from hillslopes (< 1.5 ha; n = 31) and catchments (< 1000 ha; n = 10) within two watersheds (< 1500 ha) burned by the 2012 High Park Fire in northcentral Colorado, USA. Our objectives were to: (1) identify sources and quantify magnitudes of post-fire runoff and erosion at nested hillslopes and watersheds for two rain storms with varied duration, intensity and antecedent precipitation; and (2) assess the factors affecting the magnitude and connectivity of runoff and sediment across spatial scales for these two rain storms. The two summer storms that are the focus of this research occurred during the third summer after burning. The first storm had low intensity rainfall over 11 hours (return interval <1–2 years), whereas the second event had high intensity rainfall over 1 hour (return interval <1–10 years). The lower intensity storm was preceded by high antecedent rainfall and led to low hillslope sediment yields and channel incision at most locations, whereas the high intensity storm led to infiltration-excess overland flow, high sediment yields, in-stream sediment deposition and channel substrate fining. For both storms, hillslope-to-stream sediment delivery ratios and area-normalised cross-sectional channel change increased with the percent of catchment that burned at high severity. For the high intensity storm, hillslope-to-stream sediment delivery ratios decreased with unconfined channel length (%). The findings quantify post-fire connectivity and sediment delivery from hillslopes and streams, and highlight how different types of storms can cause varying magnitues and spatial patterns of sediment transport and deposition from hillslopes through stream channel networks.  相似文献   
2.
Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites.  相似文献   
3.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   
4.
The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH4)2SO4] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   
5.

This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.

  相似文献   
6.
Geomagnetism and Aeronomy - The hypothesis put forward by Svensmark and Friis-Christensen (1997), Svensmark (2007), Svensmark et al. (2017), and Stozhkov et al. (2017) assumes while completely...  相似文献   
7.
Understanding what drives farmers’ voluntary adoption of nutrient and soil best management practices has important consequences for many environmental outcomes including water quality. We build on research revealing the need for simultaneous use of multiple nitrogen best management practices to achieve water quality improvement goals. Using social, economic and attitudinal variables we predict the use of multiple nitrogen best management practices at three time points: current use (2013), past use (before 2013), and likelihood of use on their largest field in the next three years. Our empirical analysis uses structural equation modeling with latent variables and 2014 farmer survey data from three Midwestern US states. Most farmers in our sample used at least one of the six best management practices. Our results reveal that farmers’ attitudes, use of information sources, and conservation program participation affect the number of nitrogen best management practices concurrently in use at multiple time points.  相似文献   
8.

Chile has a rich, but poorly known history of placer gold mining. At present, this sector is almost nonexistent and there are some restrictions for its revival: disperse and partial information on existing resources and limited technical expertise to assess the potential of placer gold mine sites. This paper presents the background, methodology and results of the prioritization process of known prospects of this kind in Chile. This research was part of a publicly funded project aimed to incentivize the development of this industry. The ranking was carried out using the analytic hierarchy process, which allowed to include different quantitative and qualitative variables related to the economic potential, technical aspects, contextual viability and socioeconomic factors in the analysis. The results show that, despite the increasing relevance of environmental and community issues in mining development, the business potential and the economic/technical aspects are the main factors in the early selection of a site to advance in exploration and development activities. Both variables represented around 40% and 37% of weights in the final selection, respectively. In contrast, contextual viability and local socioeconomic impacts only accounted for the remaining 23%. This study also shows that the inclusion of experts with different backgrounds in the process enriches the analysis and does not significantly distort the final outcome of the prioritization. Finally, the relevance of using MCDM tools when assessing the attractiveness of mine sites for their development is highlighted, particularly when public funds for subsequent exploration activities are committed.

  相似文献   
9.
Barrier islands are important landforms in many coastal systems around the globe. Studies of modern barrier island systems are mostly limited to those of siliciclastic realms, where the islands are recognized as mobile features that form on transgressive coastlines and migrate landward as sea-level rises. Barrier islands of the ‘Great Pearl Bank’ along the United Arab Emirates coast are the best-known carbonate examples. These Holocene islands, however, are interpreted to be anchored by older deposits and immobile. The mid-Holocene to late-Holocene depositional system at Al Ruwais, northern Qatar, provides an example of a mobile carbonate barrier island system, perhaps more similar to siliciclastic equivalents. Sedimentological and petrographic analyses, as well as 14C-dating of shells and biogenic remains from vibracored sediments and surface deposits, show that after 7000 years ago a barrier system with a narrow back-barrier lagoon formed along what is now an exposed coastal zone, while, contemporaneously, a laterally-extensive coral reef was forming immediately offshore. After 1400 years ago the barrier system was forced to step ca 3 km seaward in response to a sea-level fall of less than 2 m, where it re-established itself directly on the mid-Holocene reef. Since that time, the barrier has retreated landward as much as 1000 m to its current position, exposing previously-deposited back-barrier lagoonal sediment at the open-coast shoreline. In modern neritic warm-water carbonate settings mobile barrier island systems are rare. Their construction and migration may be inhibited by reef formation, early cementation, and the relative inefficiency of sourcing beach sediments from open carbonate shelves. Carbonate barrier island systems likely formed more commonly during geological periods when ramps and unrimmed shelves predominated and in calcite seas, when meteoric cementation was minimized as a result of initial calcitic allochem mineralogy. As with their siliciclastic analogues, however, recognition of the influence of these transient landforms in the rock record is challenging.  相似文献   
10.
Hekla volcano is a major producer of large, widespread silicic tephras. About 3000 years ago, the dominant eruption mode shifted from infrequent large (>1 km3) to more frequent moderate (<1 km3) eruptions. In the following two millennia ≥20 explosive silicic-to-intermediate eruptions occurred, and six or more basaltic. Three categories can be identified with dacite/andesite to basaltic andesite in the oldest eruptions through basaltic andesite to basalt in the youngest eruptions. Ten tephra layers of the first category have distinct field characteristics: a pale lower unit and a dark upper unit (two coloured or TC-layers). Colour separation is sharp indicating a stratified magma chamber origin. The lower unit is dominantly andesitic (61–63% SiO2), while the upper unit is basaltic andesite (53–57% SiO2). Volumes of the eight largest TC-layers range from 0.2 to 0.7 km3 as freshly fallen. Radiocarbon and soil accumulation rate dates constrain the TC-layers to between 3000 and 2200 years ago. Two of these (~2890 and ~2920 b2k) are likely to occur overseas. Low SiO2 in the last erupted tephra of the TC-layers is comparable to that of historical Hekla lavas, implying a final effusive phase. The Hekla edifice may, consequently, be younger than 3000 years.  相似文献   
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