MTBE, TBA, and TAME Attenuation in Diverse Hyporheic Zones     

by James E. Landmeyer  Paul M. Bradley  Donald A. Trego  Kevin G. Hale  Joseph E. Haas II 《Ground water》2010,48(1):30-41

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- ¹⁴C-MTBE and U-¹⁴C-TBA to ¹⁴CO₂ and the novel biodegradation of U- ¹⁴C-TAME to ¹⁴CO₂ under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.  相似文献   

Transposed Climates for Study of Water Supply Variability on the Laurentian Great Lakes   总被引：2，自引：0，他引：2  

Kenneth E. Kunkel  Stanley A. Changnon  Thomas E. Croley II  Frank H. Quinn 《Climatic change》1998,38(4):387-404

Hydrological models of the Great Lakes basin were used to study the sensitivity of Great Lakes water supplies to climate warming by driving them with meteorological data from four U.S. climate zones that were transposed to the basin. Widely different existing climates were selected for transposition in order to identify thresholds of change where major impacts on water supplies begin to occur and whether there are non-linear responses in the system. The climate zones each consist of 43 years of daily temperature and precipitation data for 1,000 or more stations and daily evaporation-related variables (temperature, wind speed, humidity, cloud cover) for approximately 20–35 stations. A key characteristic of these selected climates was much larger variability in inter-annual precipitation than currently experienced over the Great Lakes. Climate data were adjusted to simulate lake effects; however, a comparison of hydrologic results with and without lake effects showed that there was only minor effects on water supplies.  相似文献   

Wave Reflection Caused by Wave Overtopping and Sloping Top of Spructure     

LI  Yanbao 《中国海洋工程》2002,16(2):211-218

In this paper, the theoretical analysis and experimental studies are employed to investigate the reflection characteris-tics of partial standing waves caused by wave overtopping and sloping top of structures. Based on the principle of conser-vation of wave energy flux, the third-order Stokes wave theory is used to formulate the reflection coefficient at wave overtopping; the calculation results are regressed into an applied expression. A series of experiments of wave reflection for a vertical-wall structure with chamfered and overhanging upper sections are carried out to investigate the influence of top slope on wave reflection. The regularity of variation of wave reflection in this case is analysed based on the experimental results.  相似文献   

The role of sex change, growth and mortality in Pandalus population dynamics and management     

Fu  Caihong; Quinn  Terrance J.  II; Shirley  Thomas C. 《ICES Journal of Marine Science》2001,58(3):607-621

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Preparing Geographers for Interdisciplinary Research: Graduate Training at the Interface of the Natural and Social Sciences     

Russell C. Hedberg II  Arielle Hesse  Doug Baldwin  Jase Bernhardt  David Pahl Retchless  Jamie E. Shinn 《The Professional geographer》2017,69(1):107-116

Recent debates about the state of geography raise valuable questions about how the discipline can and should change in response to shifting institutional realities. Focusing on the breadth and interdisciplinarity of geography, these discussions often overlook the role of pedagogy—particularly graduate training—in adapting the discipline to new institutional landscapes. Drawing on experiences as current and recent geography doctoral students, we identify institutional seedlings of opportunity that can be cultivated toward a spectrum of alternative doctoral training models. These alternatives offer significant opportunities to better prepare early-career geographers for success and to solidify geography's position as a leader in interdisciplinary research.  相似文献   

Safety-enhanced, high-rate, nonmagnetic lithium D-size cells foroceanographic and naval use     

Krehl  P.W. Hornung  H.A.  II 《Oceanic Engineering, IEEE Journal of》1988,13(3):148-154

Tests were conducted to determine the performance and safety characteristics of specially designed, nonmagnetic Li/BrCl in SOCl₂ (Li/BCX) and Li/Cl₂ in SO₂Cl₂ (Li/CSC) battery cells. Discharge tests showed that D-size battery cells yield energy densities of 1.07 Wh/cc³ at currents of 0.17 A. The combination of high energy density and nonmagnetic properties allows smaller, lighter battery packs to be placed in close proximity to guidance systems without magnetic interference to the navigational systems. The safety testing results indicate that these systems possess explosion resistance and other characteristics necessary for a variety of applications  相似文献   

Progress report on the ENDECO free-fall CTD[conductivity-temperature-depth sensor system]     

Brainard  E.C.  II 《Oceanic Engineering, IEEE Journal of》1988,13(3):135-139

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Preface     

Mahlon C. Kennicutt  II  Michael A. Champ 《Marine pollution bulletin》1992,25(9-12):219

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Evidence of polycyclic aromatic hydrocarbon (PAH) exposure in fish from the Antarctic peninsula     

Susanne J. McDonald  Mahlon C. Kennicutt  II  James M. Brooks 《Marine pollution bulletin》1992,25(9-12):313-317

PAH exposure was assessed in fish from Arthur Harbor, Antarctica and sites remote from human activities by measuring the concentrations of polycyclic aromatic hydrocarbon (PAH) metabolites in bile and PAH in tissues and stomach contents. The highest concentrations of biliary metabolites and tissue PAH were present in fish captured near an Argentine supply ship (Bahia Paraiso) that ran aground in Arthur Harbor in 1989. The presence of biliary PAH metabolites in fish collected near Palmer Station, a small US scientific station in Arthur Harbor, suggests low level exposure to contaminants. However, PAH tissue concentrations in fish from Palmer Station were similar to those from remote sites. Both tissue PAH and metabolite concentrations were low in fish captured at sites remote from human activities. The confirmation of PAH metabolites in the bile of fish from Arthur Harbor is direct evidence that the presence of humans has resulted in Antarctic fish being exposed to petroleum-derived PAH.  相似文献   

Evaluating the effect of land development on sediment transport using a probability density function     

T. V. Hromadka II  R. J. Whitely 《Stochastic Environmental Research and Risk Assessment (SERRA)》1993,7(2):102-108

An important problem in sedimentation analysis is the development of a channel section that preserves, as best as possible, the current sedimentation regime even though the flood frequency tendencies have been altered due to land development within the catchment. In order to accomplish this task, a methodology is needed that estimates sediment transport capacity for various channel configurations. Such a procedure is described which allows the computation of the total sediment transport capacity for each of several T-year return frequency runoff hydrographs. This information is used to obtain an approximate probability distribution for the total sediment transport capacity, and the mean and standard deviation of this distribution are computed.Comparing the results for the catchment in its present state with a future developed state, using a selection of new channel parameters, indicates how to improve the channel to control changes in sedimentation due to development. The analysis procedure provides a basis for estimating a new channel configuration such that the new flow conditions retain, as best as possible, the existing condition sedimentation effects, and hence retain the natural sediment supply and transport trends even though runoff flow rates have changed due to land development within the catchment.The results of Wilson Creek are typical of the several sites examined, see Table 3 below. The T=2, T=5, T=25, and T=100 year values for total sediment transport capacity, in kilotons, are 6.9, 39.4, 61.3, and 96.7 with a mean of 17.1 and standard deviation of 19.3. After development with no change in the channel the respective values increase to: 17.9, 84.6, 128.1, and 258.0 with a mean of 39.1 and standard deviation of 44.3. A new channel can be constructed which will reduce these sediment transport capacity values, after development, to 5.2, 41.0, 62.0, and 124.8 with a mean of 17.4 and standard deviation of 22.0.  相似文献