利用稳定同位素(15N)示踪技术研究浮游藻类氮素吸收速率特征     

韩菲尔  赵中华  李大鹏  张路 《海洋与湖沼》2019,50(4):811-821

浮游藻类对溶解态氮的吸收同化是湖泊氮生物循环和水体富营养化发生机制探讨的关键环节。本文通过~(15)N稳定同位素添加实验以铜绿微囊藻(Microcystis aeruginosa)、海链藻(Thalassiosira sp.)、卡德藻(Tetraselmis sp.)、剧毒卡尔藻(Karlodinium veneficum)以及盐水隐藻(Rhodomonas salina)为研究对象,从浮游藻类氮素吸收时间、营养盐基质以及藻种差异三个方面研究五种藻类对铵氮(NH_4~+-N)、硝氮(NO_3~--N)、尿素氮(Urea-N)三种形态氮的吸收特征。研究发现:(1)浮游藻类对三种形态氮的吸收均在1h时吸收速率最高,其氮素吸收过程为快速吸收。(2)浮游藻类优先吸收还原态氮,其中NH_4~+-N吸收速率最高,当培养周期为1d和4d时浮游藻类对NH_4~+-N吸收速率的均值分别为4.05和4.15μmol/(L·h);浮游藻类对Urea-N吸收相对偏好系数为25.18—713.42,表现出对小分子溶解态有机氮的特定偏好性。(3)不同藻种对氮素吸收具有不同特征,其中,剧毒卡尔藻对三种形态氮的吸收速率均为最高,而铜绿微囊藻的吸收速率均为最低;不同藻种不同培养时间氮素吸收速率差异与浮游藻类生长周期等特性有关。不同浮游藻类对不同形态氮素表现出吸收特异性,对水体氮负荷和浮游藻类水华优势种形成将产生重要影响。  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

地幔上涌对鄂尔多斯西缘岩石圈的改造:来自远震多尺度层析成像的证据   总被引：4，自引：1，他引：3       下载免费PDF全文

高翔  郭飚  陈九辉  刘启元  李顺成  李昱 《地球物理学报》2018,61(7):2736-2749

本文利用喜马拉雅二期科学探测台阵的678个地震台站及26个固定台站记录到的9，641个地震共约160000条远震P波走时数据，采用基于稀疏约束的多尺度层析成像方法，获得了鄂尔多斯西缘及邻区上地幔800 km深度范围内P波速度结构.结果显示，在东经104°附近阿拉善地块与鄂尔多斯盆地间存在岩石圈深度的构造边界，这表明阿拉善地块与鄂尔多斯可能分别从属于不同的大地构造单元.以北纬38°线为界，鄂尔多斯地块西缘在岩石圈范围内南北存在明显的速度差异，鄂尔多斯南部上地幔200~300 km深度范围显示为高速异常，而鄂尔多斯北部上地幔显示大面积的低速异常.这一现象表明，鄂尔多斯地块南北两部分经历了不同的构造演化过程.根据本文的结果可以进一步推断，由于青藏高原、阿拉善地块向东北方向推挤以及岩石圈的拆离引起的上地幔扰动导致了地幔上涌，上涌的热物质改造了鄂尔多斯西北缘地区的岩石圈，并使该区的岩石圈减薄.地幔上涌也可能是东经104°边界带和北纬38°构造带形成的深部动力学因素.  相似文献   

滇池沉水植物生长过程对间隙水氮、磷时空变化的影响   总被引：4，自引：0，他引：4  

张云  王圣瑞  段昌群  焦立新  王一茹  高秋生 《湖泊科学》2018,30(2):314-325

2015年6-10月通过原位采集滇池沉水植物分布区和无植物对照区柱状沉积物间隙水,分析其溶解性总氮(DTN)和溶解性总磷(DTP)、溶解性无机氮(DIN)和溶解性无机磷(DIP)及溶解性有机氮(DON)和溶解性有机磷(DOP)浓度的时空变化,探讨沉水植物分布对间隙水氮、磷浓度、形态贡献及氮磷比的影响.结果表明:滇池沉水植物生长过程显著影响间隙水氮、磷浓度.与无植物对照区相比,沉水植物生长过程对间隙水氮浓度的削减主要发生在6、8月,而对间隙水磷浓度的削减主要发生在7月,反映了沉水植物对氮、磷两种元素的生物地球化学循环作用机制不同;间隙水氮形态贡献受季节性影响较大,6-7月以DON贡献为主,沉水植物分布区和无植物对照区分别达到61%和84%;而8-10月以DIN贡献为主,沉水植物分布区和无植物对照区分别为76%和75%;沉水植物分布区磷形态贡献随季节波动变化,沉水植物分布区以DOP贡献为主(63%),无植物对照区以DIP贡献为主(62%);沉水植物生长对沉积物间隙水各形态氮磷比影响显著.沉水植物生长显著增加间隙水DTN/DTP比,尤其是DIN/DIP比,相反降低DON/DOP比.沉水植物对间隙水氮、磷吸收及转化过程改变了沉积物氮、磷释放机制,从而影响上覆水氮、磷组成及氮磷比,很可能会影响到浮游植物生长及藻类水华过程,这对于湖泊水质管理具有重要意义.  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

不同氮磷比值下浒苔与石莼的竞争作用研究     

杨雪  林锟  谭丽菊  王江涛 《海洋学报》2020,42(8):50-58

近年来，海水富营养化导致近海海域大型海藻过量繁殖，成为世界性的环境问题。自2007年以来，浒苔绿潮在黄海海域连续暴发，造成巨大经济损失。为探究浒苔大规模暴发与氮磷比值(N/P)的关系，及其与其他大型绿藻在不同N/P下的竞争机制，研究了浒苔(Ulva prolifera)与石莼(Ulva lactuca)在不同N/P下单独培养和共培养时的生长情况，探究了浒苔及石莼生长的变化；结合苏北浅滩海域现场N/P的调查结果，分析了浒苔绿潮暴发的可能机制。研究结果表明:(1)浒苔单独培养时，在一定范围内高N/P能促进浒苔的生长，氮对于浒苔的影响大于磷。(2)石莼单独培养时，低N/P下石莼长势最好，但改变N/P对石莼的影响并不显著。(3)浒苔和石莼共培养时，浒苔生长受到了一定限制，低N/P下浒苔生长受限更显著。(4)苏北浅滩海域高N/P更适合浒苔的生长，可能是浒苔绿潮能够大规模暴发的原因之一。  相似文献   

二维小波变换与中值滤波联合去噪方法研究     

张胤彬  张华  刘松 《中国煤炭地质》2011,(5):38-41,48

由于随机噪声是一种频带较宽的干扰波,因此依靠单一的去噪处理方式往往难以获得清晰反映目标体的地震信息。小波变换能够较好的去除高斯噪声,保留有效波中、高频成分,提高记录的信噪比,但去除脉冲噪声的效果却并不理想;中值滤波具有良好的边缘保持特性,虽低频去噪声效果有限,但去除脉冲噪声效果明显。因此可利用二维小波变换与中值滤波优势互补的方法,进行叠前去噪处理,达到去除宽频随机噪声的目的。首先运用二维小波变换的理论,采用自适应门限阀值方法进行去噪,同时结合中值滤波方法联合去噪。模型与实际数据的应用效果表明,联合去噪方法可有效压制噪声能量、保留高频有效信号、提高地震记录信噪比与分辨率。  相似文献   

注入速率对CO_2地质储存封存潜力的影响分析     

李采  张可霓  许雅琴  何庆成 《上海国土资源》2011,32(1):24-27,32

国内某著名煤炭企业计划实施每年10万吨的CO2地质储存（CCS）项目,拟选了5组地层做为目标储层。但所选封存层平均渗透率在0.15~0.6mD,平均孔隙度在2~6%,属于低渗低孔地层,如不进行人工压裂提高注入层渗透率,要实现预定存储目标尚有一些困难。笔者在研究中发现,除对目标层进行一定的水裂酸化处理提高地层渗透特性可以显著提高注入性和存储能力外,CO2注入速率的变化对地层的封存能力和注入性也有明显影响。运用TOUGH2-ECO2N软件分别模拟了无水裂及水裂情况下8种不同注入速率下这些目标存储层的压力变化及CO2封存状态比例及理论最大封存能力。模拟结果表明使用水裂酸化方法对储层进行处理后,不仅可以使注入总量达到项目要求,还可使系统理论最大储存能力提高55%;并且在灌注过程中采用变速灌注方式,可以有效控制系统压力积聚,对将来实际灌注压力控制具有重要意义。  相似文献   

Swashed away? Storm impacts on sandy beach macrofaunal communities     

Linda Harris  Ronel Nel  David Schoeman 《Estuarine, Coastal and Shelf Science》2011,94(3):210-221

  相似文献   

Feeding strategies of deep-sea sub-Arctic macrofauna of the Faroe-Shetland Channel: Combining natural stable isotopes and enrichment techniques     

E. Gontikaki  D.J. MayorB.E. Narayanaswamy  U. Witte 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(2):160-172

The response of a sub-arctic, deep-sea macrofaunal community to a simulated food sedimentation event was studied by means of a stable isotope “pulse-chase” experiment. A food pulse was simulated by adding 500 mg C m⁻² of ¹³C-labelled diatoms, Chaetoceros radicans, to sediment cores retrieved from 1080 m in the Faroe-Shetland Channel. Carbon uptake by specific macrofaunal groups was quantified after 3 and 6 days of incubation. The carbon uptake of the dominant taxon (Polychaeta) was quantified at the genus-, and where possible, species-level, representing a data resolution that is rare in deep-sea tracer studies. The macrofaunal community reacted rapidly to the diatom addition, with 47% and 70% of the animals illustrating ¹³C-enrichment after 3 and 6 days, respectively. Approximately 95% of C uptake was located in the upper 2 cm due to the particularly shallow vertical distribution of the macrofaunal community and the nonexistent tracer subduction by burrowing species. Polychaetes of the families Ampharetidae and Cirratulidae were among the most heavily labelled with above background enrichment reaching 1300‰. Approximately 0.8 and 2.0 mg C m⁻² were processed by the macrofauna after 3 and 6 days, representing 0.2% and 0.4% of the added carbon, respectively. It was not possible to differentiate sub-surface deposit-feeding polychaetes from predator/scavenger- and omnivorous polychaetes using their natural ??¹⁵N signatures. However, the combination of natural abundance ??¹⁵N data and ¹³C-labelling experiments proved to be useful for elucidating trophic relations in deep-sea food webs. This study confirms that macrofauna play an active role in the short-term carbon cycling at bathyal depths even at sub-zero temperatures and highlights the need for detailed knowledge of the community structure in understanding carbon processing patterns and early diagenesis of organic matter in marine sediments.  相似文献