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1.
近几年笔者等在贵南的罗甸玉矿区发现了较多中酸性岩脉和岩囊。应用LA-ICPMS U-Pb法测定其中的二长闪长岩的锆石年龄为255.2 Ma±3.1 Ma,为晚二叠世吴家坪晚期。中酸性岩的年龄与罗甸辉绿岩及区域上峨眉山大岩浆岩省岩浆侵位年龄一致,因而共同形成于拉张构造环境,可能是基性岩浆结晶分异的产物。  相似文献   

2.
川西金口河地区中元古代峨边群中发育大量基性侵入岩,其具体侵位时间对厘定峨边群的时限、研究扬子西缘前寒武纪构造属性具有重要意义。对峨边群枷担桥组层型剖面中一条辉绿岩脉进行了SHRIMP锆石U-Pb定年。结果表明,该辉绿岩脉的锆石发育清楚且宽缓的内部环带结构,具有较高的Th/U比值,属典型基性岩浆成因的锆石,其206Pb/238U年龄加权平均值为(813.4±8.2)Ma(MSWD=0.56),代表了该辉绿岩脉的侵位时间,也限定了峨边群枷担桥组的上限年龄。综合扬子西缘新元古代中期基性岩浆活动的最新同位素年龄,证实存在2个主要的活动期:830~800Ma和780~745Ma,且830~800Ma期间基性岩浆活动的峰值年龄为(821±2)Ma。这与前人总结的华南和澳大利亚同期基性岩浆活动的年龄分布特征完全一致,暗示川西金口河辉绿岩脉的形成可能与新元古代导致Rodinia超大陆裂解的地幔柱幕式活动有关。  相似文献   

3.
陈娟 《地质与勘探》2015,51(1):133-142
龙门山北段的四川广元水磨地区零星分布北东-南西向的基性岩脉,主要侵位于中生代。前人对龙门山地区的基性岩脉研究较少,更缺乏高精度的年龄数据及地球化学报道。研究区辉绿岩锆石SHRIMP U-Pb年龄数据具双峰特点,结合区域构造及岩浆事件分析,采用185.7Ma为本区辉绿岩的成岩年龄。对于49.8±0.7Ma(MSWD=0.83)的年龄数据,可能指示了在喜山运动50Ma左右,本区经历过一次较强的热事件致锆石变质结晶。辉绿岩的Si O2含量相对较低,Ti O2含量较高。稀土元素总含量高,轻稀土元素相对富集,轻重稀土分异明显,配分模式为向右陡倾型。微量元素Zr/Y-Zr和2Nb-Zr/4-Y图解亦指示其具板内拉张环境特征。结合前人研究,认为水磨地区基性岩脉为印支运动后的晚三叠世-侏罗纪,由于后造山期挤压应力的逐渐消退,该区域曾一度进入挤压造山后的松弛调整阶段,致使幔源基性岩浆沿张性构造裂隙侵位而成。  相似文献   

4.
夏菲 《地质与勘探》2017,53(1):109-123
作者对广东平远县278铀矿床的流纹岩、次流纹斑岩和辉绿岩进行了高精度锆石LAICP-MS U-Pb同位素测年,获得流纹岩、次流纹斑岩和辉绿岩单颗粒锆石的加权平均年龄分别为:93.5±1.6Ma、95.1±1.1Ma、96.2±2.8Ma,属晚白垩世早期,且三者在误差范围内具有同期性,表明该区在晚白垩世早期既有幔源的基性岩浆活动,又有壳源的酸性岩浆活动,这为该区当时处于拉张的构造环境提供了佐证。  相似文献   

5.
内蒙古贺根山蛇绿岩形成时代及构造启示   总被引:16,自引:5,他引:11  
贺根山蛇绿岩位于兴蒙造山带北缘,发育完整的地幔橄榄岩、堆晶岩和基性熔岩组合,伴生有放射虫硅质岩,但贺根山蛇绿岩的形成时代一直存在争议,给兴蒙造山带北部构造演化阶段划分造成了很大障碍。锆石U-Pb年代学研究表明,贺根山蛇绿岩中辉长闪长岩(341±3Ma)和玄武岩(359±5Ma)结晶年龄为早石炭世早期,同时玄武岩继承锆石峰值年龄为晚泥盆世早期(375±2Ma),这些继承锆石呈短柱状、棱角状,生长环带宽缓,多为补丁状、平坦状,为典型的基性岩浆锆石,表明最迟在晚泥盆世早期洋壳物质已经开始形成。上石炭统格根敖包组火山岩与蛇绿岩局部呈喷发不整合接触,该组的晶屑凝灰岩夹层时代为晚石炭世(323±3Ma),提供了蛇绿岩构造侵位年龄的上限。因此,将贺根山蛇绿岩形成时代定为晚泥盆世-早石炭世,侵位时代为晚石炭世。侵入地幔橄榄岩中的部分基性岩脉时代为早白垩世(132±1Ma、139±3Ma和120±1Ma),它们含有大量继承锆石(144±1Ma~2698±25Ma),继承锆石峰值年龄密切响应了兴蒙造山带北部早白垩世之前复杂的岩浆及构造事件,这些基性岩脉是燕山期伸展环境下的岩浆产物,并非早白垩世蛇绿岩。结合前人的工作成果和区域岩浆岩、地层时空分布特征,建立了兴蒙造山带北部晚古生代构造演化历程:二连贺根山一线早泥盆世处于剥蚀阶段,中泥盆世陆壳拉张出现新生洋盆,晚泥盆世早期洋盆持续扩张形成新生洋壳,早石炭世晚期洋壳开始向北俯冲消减,并持续增生至西伯利亚活动陆缘,晚石炭世洋盆陆续闭合,部分已经构造侵位的蛇绿岩被晚石炭世火山岩不整合覆盖,贺根山蛇绿岩正是该洋盆的残余产物。  相似文献   

6.
测定了闽西南地区5件基性岩脉的全岩主微量元素,锆石U-Pb年龄和Hf,O同位素。5件岩脉主要为辉绿岩,其全岩SiO_2含量为45%~53%,稀土元素显示轻稀土富集的右倾配分模式。基性岩脉中大部分锆石具明显振荡环带和扇状环带,为典型岩浆结晶锆石特征。锆石U-Pb年龄(96~2 400 Ma)分布较为分散。除少量锆石年龄(96~142 Ma)可能指示岩脉形成年龄外,其余均为捕获锆石。捕获锆石年龄主要分布在4个范围:早元古代(2 467~1 796 Ma),中晚元古代—震旦纪(1 343~647 Ma),志留纪—晚三叠世(427~225 Ma),晚侏罗世(159~140 Ma)。Hf-O同位素显示早元古代锆石来源于接近球粒陨石均一储库的地幔。中晚元古代以后年龄的锆石其Hf-O同位素均具有亏损地幔岩浆与地壳组分混合的特征;志留纪—晚侏罗世锆石主要来源于S型壳源花岗岩的重熔;早白垩世晚期的锆石ε_(Hf)(t)值与δ~(18)O值清晰地显示出亏损地幔与地壳岩浆混合的趋势。闽西南基性岩脉中锆石的二阶段Hf亏损地幔模式年龄(TDM2)峰值主要分布在1.6~1.9 Ga,说明早元古代晚期幔源岩浆作用形成的基性岩地壳可能是形成后期花岗岩的主要源区。  相似文献   

7.
内蒙古林西县大井矿床是与次火山岩有关的热液脉型矿床,矿体受NW向、NWW向断裂控制,产出在二叠系林西组中。用LA-ICP-MS技术,测得成矿前的霏细岩脉和安山玢岩脉中的锆石~(206P)b/~(238)U年龄分别为164.1±0.8Ma(MSWD=0.60,n=16)和253.8±1.1Ma(MSWD=0.96,n=14)。其中霏细岩锆石年龄表明,其形成可能与西伯利亚板块和蒙古-华北板块之间的鄂霍茨克洋碰撞造山有关;安山玢岩可能与华北板块与西伯利亚板块碰撞造山有关。通过成矿前脉岩的锆石年龄,可以限定大井矿床的成矿时代晚于164Ma。结合前人研究结果,推测大井铜多金属矿床的形成主要受控于晚侏罗世—早白垩世岩浆活动。  相似文献   

8.
冷水坑铅锌银矿田位于扬子地块与华夏地块的江山—绍兴结合带南侧、武夷隆起带西北部的天华山火山盆地内,是武夷山成矿带中生代火山岩带中独具特色的斑岩型矿床。矿田内的火山岩分布广泛,但是区内火山岩系的地质时代归属仍然存在分歧,存在晚侏罗世和早白垩世早期的不同认识,制约了区域地质找矿工作。笔者等在对矿田火山岩系的岩性和岩相特征调查的基础上,对冷水坑矿田内鹅湖岭组流纹岩样品进行了SHRIMP锆石U-Pb测年,结果显示3件样品的锆石n(~(206)Pb)/n(~(238)U)年龄加权平均值分别为139.5±1.1 Ma、137.8±1.3 Ma和139.4±1.2 Ma,地质时代属早白垩世早期,指示流纹岩所在火山岩系地质时代为早白垩世早期。火山喷发有气爆和浆爆等喷发形式,分别表现为普利尼式和斯通博利式、乌尔卡诺式等不同喷发形式,所形成的火山碎屑岩中不同来源的晶屑、岩屑和浆屑各自所占比例不同,导致最小锆石U-Pb年龄的地质含义也不同,不一定都能代表火山碎屑岩的形成年龄。结合前人获得的凝灰岩和晚侏罗世花岗斑岩的锆石U-Pb年龄,推测冷水坑铅锌银矿田早白垩世早期发生了不同形式的火山喷发活动,是否存在晚侏罗世火山岩系仍值得探讨。  相似文献   

9.
用SHRIMP U-Pb和Sm-Nd定年技术,对攀西红格矿区含矿层状辉长岩、碱性正长岩进行了年龄测定。获得红格辉长岩中3种不同晶形锆石的U-Pb年龄分别为258.4±4.1Ma、1841±34Ma、2487±12Ma,由辉长岩、辉石和磷灰石所构成的Sm-Nd等时线年龄为253±14Ma;碱性正长岩中锆石的U-Pb年龄为257.2±1.5Ma。结果表明,红格辉长岩中具有典型基性岩锆石特征的锆石U-Pb年龄(258Ma)与同一地质样品的Sm-Nd年龄(全岩+矿物内部等时线年龄),以及同一矿区的正长岩锆石U-Pb年龄在测定误差范围内一致。鉴于层状辉长岩和碱性正长岩在空间上密切共生,在形成时间上一致,可以认为它们都属于晚二叠世末岩浆活动的产物;而1841Ma和2487Ma的锆石,可能是在基性-超基性岩浆的上侵过程中,从基底所捕获的岩浆锆石和继承锆石,其年龄信息,揭示了康滇地轴岩浆岩带的下部或结晶基底存在元古代甚至新太古代末期的岩石或物质。  相似文献   

10.
黑龙江省岔路口超大型斑岩钼矿床位于大兴安岭北部,是目前我国东北地区最大的钼矿床,矿体赋存于中酸性杂岩体及侏罗系火山-沉积岩内,其中花岗斑岩、石英斑岩、细粒花岗岩与钼矿化关系密切.本文采用LA-ICP-MS锆石U-Pb定年方法,获得了矿区内二长花岗岩、花岗斑岩、石英斑岩、细粒花岗岩、流纹斑岩、闪长玢岩及安山斑岩的结晶年龄分别为162±1.6 Ma、149±4.6 Ma、148±1.6 Ma、148±1.2 Ma、137±3.3 Ma、133±1.7Ma和132±1.6 Ma.岔路口矿区内至少存在3期岩浆活动,其顺序为侏罗纪火山-沉积岩、二长花岗岩→晚侏罗世花岗斑岩、石英斑岩、细粒花岗岩→早白垩世流纹斑岩、闪长玢岩、安山斑岩.岔路口矿床成矿时代为晚侏罗世,是东北亚大陆内部构造-岩浆活化的产物,形成于古太平洋板块俯冲作用引起的挤压向伸展构造体制转折背景,与我国东部大规模钼矿化爆发期相对应.  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

19.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

20.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

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