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1.
青龙岩体位于冈底斯带北麓,是班戈-嘉黎岩浆岩带的重要组成部分。该岩体主要岩性为花岗闪长岩,形成于白垩纪早期,SHRIMP锆石U-Pb 206Pb/238U年龄加权平均值为123.1Ma±3.4Ma,该年龄反映了青龙花岗闪长岩体的侵位或结晶年龄。花岗闪长岩地球化学数据表明,该岩体具有正常的SiO2含量,较低的K2O/Na2O比值,为弱过铝质岩石。该岩体轻稀土元素较重稀土元素富集,负Eu异常较弱。在微量元素蛛网图上,该岩体表现出强烈的Nb、Ta、Ti、Y负异常,具有岛弧花岗岩的地球化学特征。通过初步研究,认为青龙花岗闪长岩形成于俯冲背景,为与板片俯冲作用有关的同熔型花岗岩。  相似文献   

2.
内蒙古狼山山脉西侧分布有大面积的晚古生代岩浆岩,时代集中在早石炭世—晚二叠世,早石炭世角闪辉长岩、花岗闪长岩体出露于潮格温都尔镇西侧。角闪辉长岩体呈岩滴状产出,被花岗闪长岩体侵入,LA-ICP-MS锆石U-Pb年龄显示,角闪辉长岩的~(206)Pb/~(238)U加权平均年龄为329.0±2.3 Ma,花岗闪长岩的~(206)Pb/~(238)U加权平均年龄为331.1±0.9 Ma~330.0±4.2 Ma。花岗闪长岩暗色矿物以角闪石为主,富钠(Na2O=3.48%~4.46%),高钠钾比值(Na2O/K2O=1.03~2.39),钙碱性系列,P2O5-SiO_2之间存在较好的负相关性,岩石地球化学特征具Ⅰ型花岗岩的特点。Hf同位素及元素地球化学特征指示了角闪辉长岩及花岗闪长岩均来自于受地壳混染的亏损地幔,为同源岩浆演化的产物。角闪辉长岩及花岗闪长岩稀土元素配分型式一致,均为轻稀土元素富集,重稀土元素亏损,具弱的负Eu异常;角闪辉长岩富集Ba、Sr,亏损Nb、Ta、Zr、Hf;花岗闪长岩富集大离子亲石元素Rb、K、Pb、Sr,不同程度地亏损高场强元素Nb、Ta、P、Ti,总体反映了岩浆弧的地球化学特征。结合区域地质背景,早石炭世狼山地区侵入岩岩石组合为角闪辉长岩(闪长岩)+石英闪长岩+花岗闪长岩,认为狼山地区早石炭世处于大陆边缘弧构造背景。  相似文献   

3.
李浩  李勇  马双  王鹏  魏巍  樊金虎  郑军  刘怀金 《地质通报》2019,38(9):1543-1555
大东沟金矿位于华北克拉通北缘东段。对矿区内的岩浆岩进行了锆石U-Pb年代学和岩石地球化学研究。用LAICP-MS方法,测得花岗闪长岩和石英闪长岩中锆石207Pb/206Pb年龄加权平均值分别为2147±10Ma和140.8±1.2Ma,花岗闪长岩经历了1874±18Ma的后期热液活动事件。元素地球化学测试结果显示,两者均为高钾钙碱性I型花岗岩类。石英闪长岩稀土元素配分模式为明显的右倾模式,具有弱负Eu异常,而花岗闪长岩为平坦的右倾模式,具有明显的正Eu异常,两者呈现轻稀土相对富集的特征。微量元素均富集Rb、Ba、K等大离子亲石元素。石英闪长岩表现为亏损Nb、Ta、Zr、Hf、Ti等高场强元素,而花岗闪长岩表现为Th、Nb、Ta、Ti等高场强元素亏损。结合区域大地构造背景及相关研究认为,花岗闪长岩形成于大陆弧后盆地的构造背景,主要是由约2.2Ca的岩浆底侵加热导致下地壳基性火成岩部分熔融而成;石英闪长岩形成于伊佐奈岐板块向华北板块斜向俯冲的构造背景,具有壳幔混合的特征,为俯冲带流体交代地幔,使其部分熔融,形成基性岩浆与地壳熔融物质混合而成的产物。  相似文献   

4.
青龙岩体位于冈底斯带北麓,是班戈-嘉黎岩浆岩带的重要组成部分。该岩体主要岩性为花岗闪长岩,形成于白垩纪早期,SHRIMP锆石U-Pb 206Pb/238U年龄加权平均值为123.1Ma±3.4Ma,该年龄反映了青龙花岗闪长岩体的侵位或结晶年龄。花岗闪长岩地球化学数据表明,该岩体具有正常的SiO2含量,较低的K2O/Na2O比值,为弱过铝质岩石。该岩体轻稀土元素较重稀土元素富集,负Eu异常较弱。在微量元素蛛网图上,该岩体表现出强烈的Nb、Ta、Ti、Y负异常,具有岛弧花岗岩的地球化学特征。通过初步研究,认为青龙花岗闪长岩形成于俯冲背景,为与板片俯冲作用有关的同熔型花岗岩。  相似文献   

5.
西秦岭早子沟金矿是与岩浆活动有关的特大型金矿床,矿区中酸性侵入岩集中发育,主要有闪长玢岩、黑云石英闪长玢岩、花岗斑岩、石英闪长岩4种岩石类型。岩石微量元素均表现出富集大离子亲石元素Rb、K,亏损高场强元素Nb、Ta、P、Ti的特征。稀土元素总量整体上黑云石英闪长玢岩>闪长玢岩>石英闪长岩,闪长玢岩、黑云母石英闪长玢岩、花岗斑岩具有弱-中等的负铕异常(δEu=0.60~0.89),深部石英闪长岩以不具Eu异常(δEu=0.96~1.07)、“Nb-Ta谷”较深明显区别于浅部脉岩。石英闪长岩锆石U-Pb年龄为230 Ma,晚于浅部脉岩10~20 Ma,与蚀变矿物绢云母年龄基本一致,推测金成矿可能始于230 Ma,主成矿期为230~211 Ma,深部石英闪长岩为早子沟金矿的成矿地质体。  相似文献   

6.
天宫尼勒铜金矿床位于冈底斯成矿带北部,是与花岗闪长岩关系密切的矽卡岩型矿床。花岗闪长岩锆石ICP-MSU-Pb年龄加权平均值为102.6±1.8Ma,指示该矿床形成于早白垩世。元素地球化学数据表明,花岗闪长岩具有高Al2O3,富Na2O,低TiO2等特点,属于准铝质、钙碱性岩石系列,微量元素富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素,显示Nb和Ta的负异常,具有明显的岛弧型岩石的地球化学特征,岩石成因可能与班公湖-怒江洋壳板片俯冲所诱发的岩浆活动有关。结合区域构造演化,天宫尼勒铜金矿床形成于班公湖-怒江洋向南(即冈底斯地块)俯冲碰撞闭合之前的岛弧环境。  相似文献   

7.
彭游博  宋淑娥  刘锦  张文静  王恩德  赵辰 《地质通报》2017,36(10):1698-1707
宝兴岩体位于华北板块北缘陆缘活动带东段,岩性为花岗闪长岩,LA-ICP-MS锆石~(206)Pb/~(238)U年龄加权平均值为235.0±1.3Ma,属于中三叠世。岩石的K_2O/Na_2O平均值为1.07,属高钾钙碱性系列;富集大离子亲石元素,亏损高场强元素,具有活动陆缘钙碱性岩系特征;稀土元素总量平均值为147×10~(-6),稀土元素配分曲线右倾,属具中等负Eu异常的轻稀土元素富集、重稀土元素亏损型。通过岩石学、岩石地球化学及年代学研究,结合邻区构造演化研究,认为中三叠世研究区在伸展作用下岩石圈进行拆沉,从而形成大规模的岩浆活动。  相似文献   

8.
甘肃毛藏寺铜钼矿是与花岗质岩石有关的斑岩型矿床,矿区内花岗质岩石类型主要为似斑状二长花岗岩和花岗闪长岩。对矿区岩体进行年龄、地球化学研究,以约束其形成时代,并探讨岩石成因及其与成矿的关系。LA-ICP-MS锆石UPb测年分别获得似斑状二长花岗岩与花岗闪长岩谐和年龄为455.8±3.1Ma和425.0±2.8Ma,属于晚奥陶世和晚志留世岩浆活动的产物。地球化学数据显示,似斑状二长花岗岩属于过铝质钙碱性岩浆系列,花岗闪长岩属于准铝质高钾钙碱性岩浆系列,二者均富集大离子亲石元素,亏损高场强元素,稀土元素配分曲线呈右倾型,轻、重稀土元素分馏明显。似斑状二长花岗岩具有弱正Eu异常(δEu=1.18~1.24),显示埃达克岩的地球化学特征,形成于北祁连洋俯冲消减阶段,由俯冲洋壳(含海洋沉积物)部分熔融形成,源区主要残留物为石榴子石。花岗闪长岩显示弱负Eu异常,形成于碰撞后伸展环境,是洋壳板片断离后软流圈上涌诱发的下地壳玄武质岩石部分熔融的产物。似斑状二长花岗岩符合成矿期埃达克岩特征,具有较好的成矿条件。结合前人资料,在北祁连东段寻找和勘查与埃达克岩有关的铜-钼-金矿可能是一个新的方向。  相似文献   

9.
针对班公湖—怒江中特提斯洋盆闭合的时间问题,选择西藏日土县班公湖畔蛇绿岩中的小型酸性侵入岩体为研究对象,探讨其岩石成因和构造环境。研究区酸性岩体的岩性为斜长花岗斑岩。地球化学分析显示,岩石SiO2含量介于65.78%~68.76%之间,(K2O+Na2O)含量为6.39%~6.86%;具有轻稀土元素富集、分馏程度高、Eu正异常不明显的特点;富集大离子不相容元素Sr、Ba、Rb,亏损高场强元素Ta、Ti、Nb,并有Ta、Nb元素谷形,显示出典型的岛弧岩浆岩特征。2个斜长花岗斑岩体的LA-ICP-MS锆石206Pb/238U年龄加权平均值分别为96.08Ma±0.22Ma和96.05Ma±0.30Ma,均属于中生代晚白垩世。  相似文献   

10.
哈日扎铜钼多金属矿床位于东昆仑成矿带东段,是大型斑岩型铜钼多金属矿床.笔者利用锆石LA-ICP-MS U-Pb法,获得花岗闪长斑岩的成岩年龄为(234.5±4.8) Ma(MSWD=0.24);花岗闪长斑岩为其成矿母岩.对哈日扎花岗闪长斑岩的岩石学和地球化学研究表明,花岗闪长岩富SiO2(70.94%~76.08%)、K2O(4.91% ~6.07%),贫CaO(0.16% ~2.01%)、Na2O(0.24% ~0.78%),属钾玄岩系列及高钾钙碱性系列.稀土元素总量变化较大(124.69×10-6~178.68×10-6),稀土元素配分曲线为平缓的右倾型,轻稀土元素相对富集,重稀土元素相对亏损.δEu变化范围0.26~0.30,具有弱负Eu异常.岩石微量元素相对富集大离子亲石元素(LILE),贫高场强元素(HFSE),即相对富集Rb、U、La和Nd,而亏损Ba、Sr、Nb和Y.花岗闪长斑岩形成于同碰撞构造环境.  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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