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1.
北祁连乌鞘岭一带出露一套以玄武质岩石为主的双峰式火山岩组合,火山岩岩石类型以变质玄武岩为主,夹少量的流纹岩。玄武质岩石为蚀变玄武岩,属拉斑玄武岩系列,低SiO2、K2O,高Ti,富Na、Th、U等,轻稀土元素亏损—略富集型,无明显Eu异常,微量元素具Nb、Ta负异常。流纹质岩石属钙碱性系列,高SiO2,低K2O,为钠质系列,大离子亲石元素富集,具明显的Nb、P、Ti、Sr负异常和Th、U正异常,轻稀土元素富集,(La/Yb)N为2.98~11.46,Eu负异常明显,δEu介于0.07~0.60之间。结合区域资料分析,乌鞘岭双峰式火山岩可能形成于弧后盆地环境。 相似文献
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新疆阿尔泰南缘达拉乌兹双峰式火山岩年龄及岩石成因 总被引：4，自引：3，他引：1
阿尔泰南缘达拉乌兹一带出露了一套玄武岩和流纹岩频繁互层的双峰式火山岩组合。该套双峰式火山岩发生了绿片岩相变质作用,其基性端元——变质玄武岩和酸性端元——变质流纹岩具明显的变余斑状结构。利用LA-ICP-MS锆石U-Pb法获得流纹岩的喷发年龄365.6±1.6Ma和捕获的锆石年龄413.5±2.0Ma。变质玄武岩富TiO2、碱(富钠)(Na2O/K2O=4.43～19.33)和FeOT,贫MgO和CaO,轻微富集LILE和LREE,具弱的Nb、Ta和Ti的负异常,具有高于正常弧火山岩但低于OIB的HFSE元素(Nb、Ta、Zr、Hf)的含量,Eu负异常不明显。流纹岩具有高SiO2和全碱,具有低的TiO2、极低的MgO和FeOT,呈现明显的Ti、P、Sr、Ba负异常,Th、U、Pb的正异常,HFSE元素(Zr、Hf)和LREE略富集但Nb、Ta亏损的特征,并显示Eu的明显负异常(δEu=0.21～0.41)。它们均具有相似于N-MORB的较低的Pb同位素组成。玄武岩与流纹岩来自两个不同的岩浆房,玄武岩为受俯冲物质加入的亏损软流圈地幔部分熔融后并发生结晶分异作用的结果,流纹岩为新生的地壳物质受幔源岩浆加热熔融并与之混合后演化的产物。结合阿尔泰南缘地区的构造演化特征,推测该双峰式火山岩俯冲作用引起的局部拉张作用的产物。 相似文献
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4.
松辽盆地长岭断陷营城组火山岩的时代与岩石成因 总被引：1，自引：0，他引：1
对松辽盆地长岭断陷查干花次凹营城组火山岩进行了LA--ICP--MS U--Pb 年代学和岩石地球化学研究。确定研究区内火山岩形成于104 ～ 112 Ma 的早白垩世晚期。营城组火山岩主要由粗面岩、流纹岩、钠闪碱流岩、流纹质岩屑晶屑凝灰岩组成,化学成分显示均为流纹岩,属碱性系列。火山岩高硅富碱、贫铝钙镁; 铕负异常明显( δEu = 0. 16 ～ 0. 65) ,轻重稀土元素分馏较强［( La /Yb) N］ = 7. 15 ～ 10. 38; 富集大离子亲石元素K、Ｒb 和LＲEE。Ba、Sr 出现强烈的负异常,强烈亏损高场强元素P、 Ti,而Nb、Ta 并不亏损。该区中酸性火山岩由玄武质岩浆底侵导致新生地壳岩石部分熔融形成。 相似文献
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阿尔泰南缘冲乎尔盆地康布铁堡组变质酸性火山岩年龄及岩石成因 总被引：3，自引：0，他引：3
冲乎尔盆地是阿尔泰南缘等间斜列的火山沉积盆地之一,盆地内出露有重要的康布铁堡组赋矿地层.本文对该组一个凝灰岩和两个变质流纹岩样品进行了LA-ICP-MS锆石U-Pb年龄测定,获得了385.3±1.2Ma、398.1±1.8Ma和405.6±2.2Ma的结果.变质流纹岩的岩石地球化学分析结果表明,与克朗和麦兹盆地内的酸性火山岩的特征相同,即变质流纹岩属钙碱性低Ti流纹岩;在原始地幔标准化图上显示出Ti、P、Sr、Ba明显负异常,Th、U、Pb的正异常,LREE相对HREE略富集的特征,并显示强的Eu负异常(δEu=0.25 ～0.54).结合其区域地质特征,认为本区变质酸性火山岩形成于活动大陆边缘环境,是下地壳发生了部分熔融后演化的产物.阿尔泰南缘的火山沉积盆地是早—中泥盆世时期在挤压环境中形成的断陷盆地. 相似文献
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通过野外调研和相关地球化学研究,表明出露于阿尔泰造山带南缘富蕴地区喀腊曼哲一带的中泥盆统阿勒泰组火山岩由玄武岩和流纹岩组成,为一套典型的双峰式火山岩组合。其中,玄武岩多变质为钠长阳起片岩、绿帘透闪片岩等,属拉斑玄武岩系列,低SiO2、K2O,高Ti,稀土配分曲线显示轻稀土略富集的平坦型,无明显Eu异常（SEu=0．92～1．08）,富Th、U等,Nb负异常;流纹岩属钙碱性系列,高SiO2,低K2O,为钠质型,稀土配分曲线显示Eu负异（dEu为0．29～0．58）的右倾型,富集Th、U、La、Ce和Hf,亏损Sr、Nb、Ta、Zr、P、Ti。二者地球化学特征存在明显差异,表明酸性火山岩并不是由基性岩浆分离结晶产生,而可能是与基性下地壳经不同程度的部分熔融有关;基性火山岩为经俯冲流体改造的亏损地幔部分熔融的产物。岩石地球化学分析结果虽然显示其兼具洋中脊和岛弧火山岩的地球化学特征,但结合区域地质背景,其可能并不是形成于弧后盆地环境,而是岛弧裂谷的产物,属于成熟岛弧。 相似文献
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中国北天山晚石炭世白杨沟火山岩的成因及地质意义 总被引：1，自引：1，他引：0
中国北天山作为中亚造山带西部重要的组成部分,其晚古生代的构造背景长期存在板内裂谷环境和岛弧环境两个截然不同的认识,有些学者还提出该地区有塔里木地幔柱的影响,从石炭纪到二叠纪均发育大量的双峰式火山岩。为了厘定其石炭-二叠纪模糊不清的构造属性以及火山岩的地质特征,本文对北天山博格达隆起带白杨沟地区火山岩进行了系统的研究。这套火山岩由枕状玄武岩、块状玄武岩、安山-英安质熔结凝灰岩、流纹岩和火山角砾岩组成。安山-英安质熔结凝灰岩和流纹岩属于Ⅰ型酸性岩,与枕状玄武岩及块状玄武岩整合接触。海相棘皮类化石的发现以及锆石SHRIMP U-Pb年龄(~311Ma)的测定指示这套白杨沟火山岩应属于晚石炭世祁家沟组。同时,安山-英安质熔结凝灰岩的发现表明白杨沟火山岩剖面并非双峰式火山岩,但与双峰式岩浆(玄武质和流纹质岩浆)有密切的成因关系。MELTS模拟计算指示白杨沟流纹岩和熔结凝灰岩不是与其共生的玄武岩高度结晶分异的产物。与含水玄武质岩石的部分熔融实验对比,正的ε_(Nd)(t)值(+5.9~+7.5)以及岛弧特征的微量元素性质则表明白杨沟流纹岩和熔结凝灰岩主要由含水的新生岛弧玄武质地壳(岩石)发生部分熔融形成。流纹岩很可能代表新生地壳部分熔融的直接产物。然而熔结凝灰岩中发育玄武质和长英质两类浆屑,大量斜长石晶屑的发育以及负Eu至正Eu异常(δEu=0.8~1.1)暗示安山-英安质熔结凝灰岩还受岩浆混合作用和长石堆晶作用的影响。结合博格达晚石炭世玄武岩的研究,本文认为博格达晚石炭世应为洋内岛弧后弧或弧后环境,与北天山洋(或称为准噶尔洋)向南俯冲有关。博格达隆起带石炭-二叠纪构造属性的转变很可能与东准噶尔弧和博格达弧在石炭-二叠纪界限时期发生的弧-弧碰撞作用有关。 相似文献
8.
西天山吐拉苏盆地大哈拉军山组火山岩地球化学特征及构造意义 总被引：2，自引：0，他引：2
吐拉苏盆地大哈拉军山组由两组火山岩组成,一组为玄武安山岩、安山岩,SiO2含量介于54.8%～59.4%之间,另一组为流纹岩,SiO2含量为70.6% ～74.1%,两组岩石具有相似的稀土和微量元素分配型式,均富集U、Th、K、Pb,而亏损Nb、Ta和Ti,同时两组岩石的一些微量元素对比值基本一致,表明流纹岩是本区玄武... 相似文献
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南祁连天峻巴龙贡嘎尔组变质火山岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及构造意义 总被引：1，自引：0，他引：1
南祁连山天峻县一带巴龙贡嘎尔组发育大量变质火山岩,其形成时代及构造意义缺乏详细研究,时代归属存在争议。本文以变质火山岩为研究对象,开展岩石学、地球化学和年代学研究。本文在变质火山岩中获得LA-ICP-MS锆石U-Pb年龄为736±6Ma和740±14Ma,时代为新元古代。岩石为变玄武岩、变质石英粗面质凝灰岩和变质流纹质凝灰岩,其SiO_2含量为48.10%～53.01%和64.14%～71.83%,属于碱性和亚碱性系列,构成双峰式火山岩组合。玄武岩稀土总量为56.3×10~(-6)～98.9×10~(-6),轻、重稀土分馏中等,δEu为0.89～1.16具微弱异常,微量元素Rb、Ba、K、Sr、La、Ce、Zr、Th等富集,Nb、P、Ti、Y等微弱—中等亏损。变质石英粗面质凝灰岩和变质流纹质凝灰岩的A/CNK为0.8～1.14,具有偏铝质—过铝质特征,稀土总量为155.5×10~(-6)～265.6×10~(-6),轻、重稀土分馏中等—强烈,δEu为0.63～0.94,具有弱—微弱异常,微量元素Rb、K、Ba、La、Ce、Zr、Th等富集, Sr、Nb、P、Ti、Yb等中等—强烈亏损。区域资料、前人成果及本文研究表明巴龙贡嘎尔组形成于新元古代的陆内裂谷环境,是Rodinia超大陆裂解事件的响应。 相似文献
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福建早侏罗世火山岩岩石地球化学特征及岩石成因研究 总被引：1，自引：0，他引：1
选择较有代表性的永定、平和、长泰—同安、闽清—永泰等地早侏罗世火山岩岩石主量、微量和Sr、Nd同位素分析测试成果,开展岩石地球化学特征对比研究,探讨岩浆起源、演化和不同类别的岩石成因。研究认为,早侏罗世火山岩主要属亚碱性钾质-普通系列,玄武岩属亚碱性高铁拉斑玄武岩系列。玄武岩稀土含量较高,配分曲线与典型OIB玄武岩变化趋势一致;高场强元素(HFSE)除Nb略亏损外,Ti、Zr、Nd具有明显正异常,Ta具有弱正异常;原始地幔标准化曲线位于典型大陆弧玄武岩之上。流纹岩稀土含量高,轻稀土富集,Eu负异常明显,高场强元素Nb、Zr等具有清晰正异常,Ti、P负异常明显。岩石地球化学特征研究表明早侏罗世火山岩岩石成因与地幔岩浆作用有关:基性单元——玄武质岩石岩浆主要来自于软流圈,亏损的地幔源区可能有早期富集岩石圈物质加入或是由于软流圈地幔上涌萃取了岩石圈地幔富集组分。酸性单元——流纹质岩石主要形成于上地壳,但不排除有幔源物质的混合。安山岩-英安岩是底侵的镁铁质岩浆与下地壳部分熔融岩浆混合均一化形成典型的MASH岩浆。早中生代处于印支运动后造山大陆裂解的地球动力学背景,后造山岩石圈伸展拉张致使软流圈减压上涌和部分熔融,所产生的岩浆沿北东向展布的裂解区域喷出地表形成火山岩带。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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