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1.
彭鹏飞  马媛  史荣君  王迪  许欣  颜彬 《海洋科学》2022,46(10):140-149
根据2018年7月、11月和2019年1月、4月对广东考洲洋牡蛎养殖海域进行4个季节调查获得的pH、溶解无机碳(DIC)、水温、盐度、溶解氧(DO)及叶绿素a(Chla)等数据,估算该区域表层海水溶解无机碳体系各分量的浓度、初级生产力(PP)、表层海水CO2分压[p(CO2)]和海-气界面CO2交换通量(FCO2),分析牡蛎养殖活动对养殖区碳循环的影响。结果表明:牡蛎养殖区表层海水中Chla、DIC、HCO3–和PP显著低于非养殖区;养殖淡季表层海水中pH、DO、DIC、HCO3–、和CO32–显著大于养殖旺季,养殖旺季的p(CO2)和FCO2显著大于养殖淡季。牡蛎养殖区表层海水夏季、秋季、冬季和春季的海-气界面CO2交换通量FCO2平均值分别是(42.04±9.56)、(276.14±52.55)、(–11.59±18.15)和(–13.02±6.71)mmol/(m2·d),冬季各站位FCO2值离散度较大,其中位数是–10.73mmol/(m2·d)。在全年尺度,表层海水p(CO2)及FCO2与水温呈显著正相关,与盐度呈显著负相关。在非养殖区,浮游植物光合作用可能对影响表层海水p(CO2)及FCO2起主导作用。养殖牡蛎钙化、呼吸作用等生理因素释放的CO2对表层海水p(CO2)及FCO2未产生显著影响。考洲洋养殖海域养殖旺季为CO2的源,养殖淡季整体为CO2的弱汇。  相似文献   

2.
水-气平衡法被广泛地应用于海水CO2分压（partial pressure,pCO2）的测定。该方法采用水-气平衡器,使海水与平衡器上部顶空中的空气进行CO2交换,达到平衡后测定该顶空空气中CO2的浓度,再换算成海水pCO2。水-气平衡器是海水pCO2测量仪器的关键部件,其性能在很大程度上决定所获得的pCO2数据的准确度和可靠性。本文介绍了水-气平衡器的平衡原理、平衡器时间常数的测量方法及影响因素,归纳了现有的4种用于海水pCO2测量的水-气平衡器即喷淋式、鼓泡式、层流式及混合式平衡器的结构与特点,着重介绍了两种新型的水 气平衡器即基于射流器的鼓泡式平衡器和基于球形降膜的层流式平衡器,比较了不同水-气平衡器的尺寸、运行参数及时间常数,分析了设计和应用水-气平衡器时需考虑的因素。本文可为使用水-气平衡器测定海水pCO2的技术人员提供技术参考。  相似文献   

3.
由于存在极高的初级生产和高效的碳代谢速率, 珊瑚礁海域二氧化碳(CO2)的汇/源属性仍存有争议。为明晰中国典型珊瑚礁海域CO2的汇源属性及驱动因素, 作者基于2022年11月(秋季)和2023年2月(冬季)在深圳杨梅坑海域的调查结果并结合室内培养实验所获得的数据, 探究了枯水季节典型亚热带珊瑚礁海水二氧化碳分压(pCO2)的分布特征及主要控制机制。结果表明, 调查期间pCO2的变化较大, 其范围为233.3~465.3 μatm。秋季表现为大气CO2的汇, CO2吸收通量为1.66±0.41 mmol C/(m2/d);冬季表现为大气CO2的弱源, 其释放通量为0.36±0.17 mmol C/(m2/d)。调查期间(枯水季)杨梅坑海域受淡水输入的影响较小, 季节性温度影响下的生物过程是驱动pCO2变化的关键因素, 其贡献pCO2总变化量的73.6%(表层)和66.5%(底层)。其中, 浮游植物光合作用的季节差异是导致海水CO2汇源转变的主要成因, 而微生物呼吸作用的影响甚微。相比较, 物理过程(CO2海-气交换、温度和盐度变化)对pCO2的影响相对较小, 其作用结果远低于生物过程。此外, 珊瑚的代谢活动对杨梅坑局部海域pCO2分布产生一定影响, 造成礁区pCO2值高于非礁区。因此, 海气CO2通量估算中不能忽视局部海域珊瑚代谢作用的影响。  相似文献   

4.
基于2010 年11 月对长江口外东海中北部海域的综合调查, 系统研究了该海域的无机碳体系参数的分布特征、海?气界面二氧化碳通量及其影响因素。研究结果表明, 该海域秋季溶解无机碳(DIC)高值区主要出现在调查海域东北部及长江口附近海域, 而调查海域南部DIC 含量较少且变化平缓, 其主要是受台湾东部流向东北方向的黑潮支流及长江冲淡水的影响; 表层海水CO2分压(pCO2)值变化范围为40.8～63.5 Pa, 呈现沿黑潮支流流入方向由东南向西北逐渐增高的趋势。秋季表层海水pCO2与温度(T)、盐度(S)有较好的负相关性, 说明海水温度升高和盐度增加, pCO2降低, 反之亦然。另外, 通过估算得出, 秋季CO2海-气交换通量为2.69～33.66 mmol/(m2·d), 平均值为(14.35 ± 7.06 )mmol/(m2·d),其在长江口邻近海域相对较大, 而在调查海域南部相对较小; 2010 年秋季水体向大气释放CO2的量(以碳计)为(2.35 ± 1.16)×104 t/d, 是大气CO2较强的源, 说明东海中北部海域秋季总体上是CO2的源。  相似文献   

5.
为探讨太阳紫外辐射(UVR,280~400 nm)和CO2浓度变化对大型海藻的复合效应,选择了常见的经济海藻龙须菜(Gracilaria lemaneiformis)为实验材料,研究了UVR(阳光紫外辐射)和CO2对其生长、光合作用、色素以及紫外吸收物质含量变化的复合作用。实验设置两个CO2梯度(380×10-6和800×10-6)和三种太阳辐射处理(PAB处理——全波长辐射处理, PA辐射处理——滤掉紫外线B和P处理——滤掉全部紫外线)。结果表明,CO2加富(800×10-6)显著地促进了龙须菜的生长,而UVR则产生抑制作用,但两者之间复合作用不显著。UVR促进了藻体的紫外吸收物质的合成,而且在高浓度CO2下经PAB辐射处理的含量要显著高于正常CO2浓度水平下的,这表明高浓度CO2促进了紫外吸收物质的合成。在光合作用受限制的低PAR条件下,紫外线A(UV-A)促进其光合作用,但高浓度CO2却抑制了藻体的光合作用速率。在正常浓度CO2水平下生长的藻体,UVR显著降低其光合作用能力,但是在高浓度CO2下生长的藻体,UVR这种负面效应不显著。UVR显著降低藻红蛋白的含量,高浓度CO2 在P和PA辐射处理下也显著降低藻红蛋白的含量,但在PAB辐射处理下却呈现相反的结果。高浓度CO2下生长的藻体通过增加体内紫外吸收物质的含量来维持较高浓度的藻红蛋白含量,增强了其抵御UVR的能力。  相似文献   

6.
微藻固碳是一种新型节能减排技术，具有长期可持续发展的潜力。本文对两株富油微藻（球等鞭金藻和微拟球藻）进行了富碳培养下生长特性及中性脂积累特性的研究。两株富油微藻的最佳培养条件为10%CO2浓度和f培养基。本研究对两株富油微藻的最大生物量产率、总脂含量、最大油脂产率、微藻的C含量和CO2固定率进行了测定。球等鞭金藻的各参数指标分别为：142.42±4.58g/（m2·d），39.95%±0.77%，84.47±1.56g/（m2·d），45.98%±1.75%和33.74±1.65g/（m2·d）。微拟球藻的各参数指标分别为：149.92±1.80g/（m2·d），37.91%±0.58%，89.90±1.98g/（m2·d），46.88%±2.01%和34.08±1.32g/（m2·d）。实验结果显示，两株海洋微藻均属于高固碳优良藻株，适合应用于微藻烟气减排技术开发，具备用于海洋生物质能耦合CO2减排开发的潜力。  相似文献   

7.
过氧化氢(H2O2)等活性氧(ROS)物质因具有绿色高效的特点,在废水处理、杀菌消毒等领域受到研究者广泛关注。利用电催化生成H2O2是一种实时提供活性氧物质的有用方法。然而,目前报道的大多数高性能催化材料都是粉体形式,不便于在实际场景中的应用。因此,制备可直接应用的电极材料显得尤为重要。本研究利用喷涂-热解的制备方法,制备了高活性氧催化活性的氧化炭黑(O−CB)/多孔碳毡电极,通过聚四氟乙烯(PTFE)的修饰优化电极表面的氧气传质,成功制备氧掺杂碳气体扩散电极。研究结果表明,O−CB/PTFE-5 wt%电极具有最高的催化性能,其合成H2O2的速率达27.19 mg·L-1(mg catalyst)-1·cm-1·h-1。海洋典型污损微生物假单胞菌(Pseudomonas sp.)的抗菌实验表明,该电极电催化作用60 min产生的活性氧对Pseudomonas sp.的杀菌率可达到97.69%,作用120 min的杀菌率可达到99.99%。  相似文献   

8.
Time-series measurements of dissolved inorganic carbon (DIC) and nutrient concentrations were conducted in the northwestern North Pacific from October 2002 to August 2004. Assuming that data obtained in different years represented time-series seasonal data for a single year, vertical distributions of DIC and nutrients showed large seasonal variabilities in the surface layer (∼100 m). Seasonal variabilities in normalized DIC (nDIC) and nitrate concentrations at the sea surface were estimated to be 81–113 μmol kg−1 and 12.7–15.7 μmol kg−1, respectively, in the Western Subarctic Gyre. The variability in nutrients between May and July was generally at least double that in other seasons. In the Western Subarctic Gyre, estimations based on statistical analyses revealed that seasonal new production was 39–61 gC m−2 and tended to be higher in the southwestern regions or coastal regions. The seasonal new productions in the northwestern North Pacific were two or more times higher than in the North Pacific subtropical gyre and the northeastern North Pacific. It is likely that this difference is due to spatial variations in the concentrations of trace metals and the species of phytoplankton present. In addition, from estimations of surface pCO2 it was verified that the Western Subarctic Gyre is a source of atmospheric CO2 between February and May and a sink for CO2 between July and October.  相似文献   

9.
The paper presents a new model of electronic-vibrational kinetics of the products of ozone and molecular oxygen photodissociation in the terrestrial middle atmosphere. The model includes 45 excited states of the oxygen molecules O2(b 1, Σ g + ,v= 0−2), O2 (a 1Δ g , v= 0−5), and O2(X 3Σ g − , v= 1−35) and of the metastable atom O (1 D) and over 100 aeronomic reactions. The model takes into account the dependence of quantum yields of the production of O2(a 1Δ g , v= 0−5) in a singlet channel of ozone photolysis in the Hartley band on the wavelength of photolytic emission. Taking account of the electronic-vibrational kinetics is important in retrieval of the vertical profiles of ozone concentration from measured intensities of the Atm and IR Atm emissions of the oxygen bands above 65 km and leads to an increase in the ozone concentration retrieved from the 1.27-μm emission, in contrast to the previous model of pure electronic kinetics. Sensitivity analysis of the new model is made for variations in the concentrations of atmospheric constituents ([O2], [N2], [O(3P)], [O3], [CO2]), the gas temperature, rate constants of the reactions, and quantum yields of the reaction products. A group of reactions that most strongly affect the uncertainty of ozone retrieval from measured intensities of atmospheric emissions of molecular oxygen O2(b 1Σ g + , v) and O2(a 1Δ g , v) has been determined. Original Russian Text ? V.A. Yankovsky, V.A. Kuleshov, R.O. Manuilova, A.O. Semenov, 2007, published in Izvestiya AN. Fizika Atmosfery i Okeana, 2007, Vol. 43, No. 4, pp. 557–569.  相似文献   

10.
2014年冬季西太平洋浮游植物光合作用特征   总被引：2，自引：1，他引：1  
利用浮游植物荧光仪Phyto-PAM测量了西太平洋浮游植物最大光化学量子产量、快速光曲线系数,结合相应的生态因子,对西太平洋浮游植物进行了原位光合作用特征研究。结果表明：西太平洋走航断面表层浮游植物最大光化学量子产量Fv/Fm值基本在0.2以下,而DY（大洋）断面Fv/Fm平均值仅为0.16,光能利用效率α的变化范围为0.007-0.117,平均值为0.039;相对最大电子传递速率rETRmax变化范围为6.8-113.4（μmol/（s·m2））,平均值为32.72（μmol/（s·m2））;饱和光强Ek的变化范围为60.3-1662.7（μmol/（s·m2））,平均值为846.83（μmol/（s·m2））。DY断面Fv/Fm最大值水层与DCM层（叶绿素最大层）相吻合,既保护了浮游植物光反应中心不受强烈光辐射影响,又支持了DCM层浮游植物相对较强的光合作用和对整个水体初级生产力的贡献率。DY断面浮游植物具有极低的光能利用效率却需要较高的光强来达到光饱和,导致这种生活环境下浮游植物处于一种低活衰老的状态,这是造成某些大洋海区低生产力现象出现的原因之一。  相似文献   

11.
Using data from the European remote sensing scatterometer（ERS-2） from July 1997 to August 1998,global distributions of the air-sea CO2 transfer velocity and flux are retrieved.A new model of the air-sea CO2 transfer velocity with surface wind speed and wave steepness is proposed.The wave steepness（5） is retrieved using a neural network（NN） model from ERS-2 scatterometer data,while the wind speed is directly derived by the ERS-2 scatterometer.The new model agrees well with the formulations based on the wind speed and the variation in the wind speed dependent relationships presented in many previous studies can be explained by this proposed relation with variation in wave steepness effect.Seasonally global maps of gas transfer velocity and llux are shown on the basis of the new model and the seasonal variations of the transfer velocity and llux during the 1 a period.The global mean gas transfer velocity is 30 cm/h after area-weighting and Schmidt number correction and its accuracy remains calculation with in situ data.The highest transfer velocity occurs around 60°N and 60°S,while the lowest on the equator.The total air to sea CO2 llux（calculated by carbon） in that year is 1.77 Pg.The strongest source of CO2 is in the equatorial east Pacific Ocean, while the strongest sink is in the 68°N.Full exploration of the uncertainty of this estimate awaits further data.An effectual method is provided to calculate the effect of waves on the determination of air-sea CO2 transfer velocity and fluxes with ERS-2 scatterometer data.  相似文献   

12.
The global distributions of the air-sea CO2 transfer velocity and flux are retrieved from TOPEX/Poseidon and Jason altimeter data from October 1992 to December 2009 using a combined algorithm. The 17 a average global, area-weighted, Schmidt number-corrected mean gas transfer velocity is 21.26 cm/h, and the full exploration of the uncertainty of this estimate awaits further data. The average total CO2 flux （calculated by carbon） from atmosphere to ocean during the 17 a was 2.58 Pg/a. The highest transfer velocity is in the circumpolar current area, because of constant high wind speeds and currents there. This results in strong CO2 fluxes. CO2 fluxes are strong but opposite direction in the equatorial east Pacific Ocean, because the air-sea CO2 partial pressure difference is the largest in the global cceans. The results differ from the previous studies calculated using the wind speed. It is demonstrated that the air-sea transfer velocity is very important for estimating air-sea CO2 flux. It is critical to have an accurate estimation for improving calculation of CO2 flux within climate change studies.  相似文献   

13.
The parameter that describes the kinetics of the air-sea exchange of a poorly soluble gas is the gas transfer velocity which is often parameterized as a function of wind speed. Both theoretical and experimental studies suggest that wind waves and their breaking can significantly enhance the gas exchange at the air-sea interface. A relationship between gas transfer velocity and a turbulent Reynolds number related to wind waves and their breaking is proposed based on field observations and drag coefficient formulation. The proposed relationship can be further simplified as a function of the product of wind speed and significant wave height. It is shown that this bi-parameter formula agrees quantitatively with the wind speed based parameterizations under certain wave age conditions. The new gas transfer velocity attains its maximum under fully developed wave fields, in which it is roughly dependent on the square of wind speed. This study provides a practical approach to quantitatively determine the effect of waves on the estimation of air-sea gas fluxes with routine observational data.  相似文献   

14.
海-气CO2通量估算模型中参数的可靠性是决定模型可靠性的重要因素, 也决定了模型估算结果的可靠性, 因此开展海-气CO2通量计算模型中误差传递规律与敏感性分析, 对模型参数端元因子的误差控制, 提高模型预测精度和降低不确定性十分重要。但由于模型中参数众多, 且各种参数间彼此相互影响, 使得误差传递过程与敏感性分析十分复杂困难。本文在海-气界面CO2通量观测建模过程详细分析的基础上, 以海-气界面CO2分压差的经典通量计算模型为基础, 以实测数据通量计算过程为例, 针对模型中的参数变量, 在假设参数变量的误差正态分布的前提下, 利用Monte Carlo手段分析各参数变量的误差在模型中的传递规律, 并将单因子扰动试验法用于海-气界面CO2通量建模的参数敏感性分析。模拟和分析结果表明:CO2通量计算过程中误差经模型传递后的分布规律存在正态分布、指数分布等多种形式;气体交换系数对通量计算结果的敏感性最大, 通量估算中的风速和表层海水温度是必须进行精度控制的关键参数。  相似文献   

15.
Direct measurements of the air-sea CO2 flux by the eddy covariance technique were carried out in the equatorial Indian Ocean. The turbulent flux observation system was installed at the top of the foremast of the R/V MIRAI, thus minimizing dynamical and thermal effects of the ship body. During the turbulent flux runs around the two stations, the vessel was steered into the wind at constant speed. The power spectra of the temperature or water vapor density fluctuations followed the Kolmogorov −5/3 power law, although that of the CO2 density fluctuation showed white noise in the high frequency range. However, the cospectrum of the vertical wind velocity and CO2 density was well matched with those of the vertical velocity and temperature or water vapor density in this frequency range, and the CO2 white noise did not influence the CO2 flux. The raw CO2 fluxes due to the turbulent transport showed a sink from the air to the ocean, and had almost the same value as the source CO2 fluxes due to the mean vertical flow, corrected by the sensible and latent heat fluxes (called the Webb correction). The total CO2 fluxes including the Webb correction terms showed a source from the ocean to the air, and were larger than the bulk CO2 fluxes estimated using the gas transfer velocity by mass balance techniques.  相似文献   

16.
Current estimations of gas exchange between the ocean and the atmosphere are based on the concepts about diffusive gas transfer across the interface and about a stationary character of the processes; however, under a strong wind, these concepts are invalid. Transfer equations for gas constitutents of the air are incorporated into a numerical model of a nonstationary upper layer of the ocean. These equations contain the source function—gas transfer by bubbles, which becomes noticeable even at a wind speed of 8–10 m/s. The fluxes of oxygen and CO2 are calculated at a specified wind speed, dependences of these fluxes on the wind speed are constructed, and estimates for the average annual fluxes are obtained for several areas of the Gulf Stream and Kuroshio. A substantial change in the difference of the air-water gas contents under a strong wind, caused by the turbulent exchange growth and appreciably affecting the gas exchange, is noted. The influence of the carbonate system of seawater on the CO2 transfer during a storm is estimated. The results obtained are compared to the estimates based on the traditional approach.  相似文献   

17.
The oceanic biogeochemical fluxes in the North Pacific, especially its northwestern part, are discussed to prove their importance on a global scale. First, the air-sea exchange processes of chemical substances are considered quantitatively. The topics discussed are sea salt particles transported to land, sporadic transport of soil dust to the ocean and its role in the marine ecosystem, the larger gas transfer velocity of CO2 indicating the effect of bubbles, and DMS and greenhouse gases other than CO2. Next, chemical tracers are utilized to reveal the water circulation systems in the region, which are the Pacific Deep Water including its vertical eddy diffusivity, the North Pacific Intermediate Water and the Japan Sea Deep Water. Thirdly, the particulate transport process of chemical substances through the water column is clarified by analyzing the distribution of insoluble radionuclides and the results obtained from sediment trap experiments. Fourthly, the northern North Pacific is characterized by stating the site decomposing organic matter and Si playing a key role in the marine ecosystem. Both are induced by the upwelled Pacific Deep Water. Fifthly, the oceanic CO2 system related to global warming is presented by clarifying the distribution of anthropogenic CO2 in the western North Pacific, and roles of the upwelled Pacific Deep Water and the continental shelf zone in the absorption of atmospheric CO2. Finally, Mn and other chemical substances in sediments are discussed as recorders of the early diagenesis and indicators of low biological productivity during glacial ages in the northwestern North Pacific. It is concluded that the western North Pacific is characterized mainly by the Pacific Deep Water bringing nutrients to the northern North Pacific, located at the exit of the global deep water circulation and, therefore, the region plays a key role in the global biogeochemical fluxes. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

18.
进一步研究强风条件下海-气湍流动量交换以及海浪特征,有助于提高数值天气模式对台风强度演变、移动路径以及恶劣海况的预报能力。依照前人的方法将台风分为风向与浪向(1)相同,(2)相反,和(3)交叉3个扇形区,并结合台风路径数据,得到了浮标数据相对于台风的方位。分别对3种类型的浮标数据进行分析,进而发现了波浪高度和相速度随风速增加而变化的规律。并利用GWW参数化方案计算出摩擦速度(u*)、拖曳系数(CDN)和粗糙长度(z0)。将这些结果与前人代表性的研究论文中所用观测数据和所得研究结论进行比较,结果表明二者有较强的一致性。该研究证明GWW参数化方案在强风条件下依然有很好的适用性。  相似文献   

19.
叶灿  成泽毅  高宇  宋金宝  李爽 《海洋与湖沼》2023,54(6):1537-1550
当水流经过海洋地形时,水流的不稳定性会引起垂向混合并伴随大量湍流过程。针对传统海气耦合模式缺少在湍流尺度上讨论海洋地形与风速对海气相互作用影响的问题,使用并行大涡模拟海气耦合模式(the parallelized large eddy simulation model, PALM)在5 m/s的背景风场下,引入理想立方体地形,对比有无地形的影响;设置地形边长为L,高为3L (其中大气部分高L), L与水深H之比为L/H=1/2;然后保持地形条件不变。设置5、10和15 m/s三种风速,讨论风速对小尺度海气相互作用的影响。研究表明:地形在大气部分减弱顺风向速度,增强侧风向速度,影响0～5L的高度区域,而对垂向作用较小;无地形条件下湍流垂向涡黏系数Km在-0.3L时,水深达到最大值0.024 m2/s,有地形条件下Km在-0.8L时,达到最大值为0.16 m2/s,地形的存在使得上层海洋混合加强, Km最大值增加1个数量级。随风速增大海洋和大气中的净热通量、淡水通量和浮力通量都相应...  相似文献   

20.
基于卫星资料建立的CCMP风场、ECMWF波浪和最新CO2分压数据, 分别用4种以风速为单参数和2种包含海况影响的双参数气体交换速率公式, 估算了全球海-气CO2通量, 发现前者的结果比后者平均小30%左右, 从整体上看, 与单参数公式相比, 双参数公式使得海洋中CO2源和汇的强度均明显增强。在此基础上, 讨论了时间平均尺度对海-气CO2通量估计的影响, 结果表明, 标量平均法比矢量平均具有更好的稳定性, 但依然使得短时间平均比长时间平均得到的CO2通量值要大, 月平均与6 h平均相比, 单参数公式和双参数公式分别使海洋的净吸收量减少33%和5%, 说明双参数公式具有较好的稳定性。研究还发现, 1988-2009年间, 全球平均风速有增大的趋势, 2006年前后出现一个极大值, 但相应的CO2年净通量基本保持稳定, 甚至其绝对值有所减小、海洋的吸收能力减弱的倾向。  相似文献   

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