共查询到20条相似文献，搜索用时 109 毫秒
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建立了包括三千多个已测定的二元、三元熔盐系相图的熔盐相图智能数据库。在建库过程中 ,运用原子参数 -模式识别方法总结已知相图几何特征与其组分元素的原子参数 (离子半径和电负性 )关系的半经验规律 ,并将其用于未知相图几何特征的预报。还将若干不符合上述规律的已测相图列为可疑对象 ,对其重新作实验测定。通过这一做法 ,纠正了前人报道的忽略了某些中间化合物的相图 ,证明这些相图存在CsCaBr3 ,Cs2 CaF4等中间化合物。另一方面 ,还通过实验否定了前人声称发现的KNO3 -KI等相图的中间化合物。这说明 :原子参数 -模式识别算法和实验验证相结合 ,是一种对有疑问的相图评估的有效方法。熔盐相图智能数据库还具有根据原子参数 -模式识别方法对部分未知相图的若干特征的预报功能。初步研究结果表明 :这类智能数据库的研究方法对水 -盐系等相图研究也有应用价值。 相似文献
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采用基于扩展UNIQUAC模型的AQSOL027软件针对水盐体系Li-Na-K-Mg-Cl-SO_4-H_2O的六个五元子体系进行相平衡理论计算,首次报道了多个五元子体系在多个温度条件下的相图,将计算相图与已有实验相图以及基于其它热力学模型的计算相图进行了比较。结果表明:AQSOL027在相图计算中具有较好的准确性和可靠性。AQSOL027是一款基于Excel、用于计算复杂多温水—盐体系Li-Na-K-Mg-Ca-H-Cl-(HSO_4/SO_4)-(CO_2/HCO_3/CO_3)-(H_3BO_3/B_4O_7/BO_2)-OH-H_2O的计算机软件,集成了扩展UNIQUAC模型和相平衡算法,该软件可结合SysCAD和Aspen过程模拟器,实现盐田工艺过程的计算机辅助设计。 相似文献
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梯度太阳能池技术在盐湖化工中是一种经济分离无机盐产品的方法，本文创新性的采用等温蒸发法，模拟四元体系(LiCl + NaCl + Li2SO4 + Na2SO4 + H2O)在75℃等温蒸发相平衡，指导太阳池深池积温分离提取锂盐产品。实验测定了溶解度和溶液密度、pH值等物化性质，并绘制了干盐相图、水图和物化性质组成图。在该四元体系干盐相图中包含3个四元共饱点，7条单变量蒸发曲线和5个结晶区，分别为NaCl，Na2SO4，复盐Li2SO4·Na2SO4，Li2SO4·H2O和LiCl·H2O。采用 Pitzer模型和改进的HMW公式，拟合出该四元体系在75℃时的Pitzer单盐参数、混合离子作用参数和平衡固相的热力学平衡常数，并计算给该四元体系的相图，计算相图和实验相图有较大区别。等温蒸发相图能真实的反应盐湖中盐类沉积规律，并对指导太阳池分离盐类具有重要指导意义。 相似文献
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Bradford M. Clement Ewald Poetisi Timothy J. Bralower Emily CoBabe Jose Longoria 《Geophysical Journal International》2000,143(1):219-229
We present the results of a palaeomagnetic study of four mid-Cretaceous limestone sections exposed in northeastern Mexico. The limestones are weakly magnetized and exhibit two- to three-component magnetizations. These magnetization components appear to be carried by both a sulphide mineral and a magnetite-titanomagnetite mineral. The sulphide mineral carries a reverse polarity overprint that often makes it difficult to isolate definitively the higher-unblocking-temperature component. The high-unblocking-temperature component is well defined in the upper portion of the Santa Rosa Canyon section and in the Cienega del Toro section and passes the fold test. The characteristic remanent magnetization (ChRM) inclinations agree well with predicted mid-Cretaceous inclinations for these sites, although the declinations differ by more than 100°. The relative rotation between these two sites probably occurred as the thrust sheets were emplaced during Laramide deformation. At two of the sections, namely Cienega del Toro and the overturned Los Chorros sections, only normal polarity directions are observed. The La Boca Canyon and Santa Rosa Canyon sections exhibit zones of both normal and reverse polarity magnetization. Correlation of these polarity zones with the geomagnetic polarity timescale provides a time framework for lithostratigraphic and palaeoceanographic studies of these sections. 相似文献
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J. C. Samson 《Geophysical Journal International》1978,53(2):319-334
summary . Recent theoretical work has clarified the spatial characteristics of ULF (1–20 mHz) plasma waves in the magnetosphere, and the magnetic perturbations that these waves cause at the Earth's surface. This paper uses ground-based observations from seven, three-component, flux-gate magnetometers ranging in latitude from 58.7 to 77.7° N corrected geomagnetic latitude in order to evaluate the relevance of these theories. During the day, the sense of polarization and direction of the major axis of the pulsations in the horizontal plane follow the trend predicted by recent theories proposing a Kelvin—Helmholtz instability at the magnetopause as a source for these pulsations. The H component shows a distinct trend for the power to peak at lower latitudes as the frequency of the pulsation train increases. This feature is consistent with recent theoretical work which predicts pronounced latitudinal resonances in the D component in the magnetosphere, which are then rotated to the H direction on passing through the ionosphere to the ground. The experiment shows that at the ground the latitudinal resonance is most clearly marked by sharp peaks in the H and Z components, and by pronounced latitudinal phase shifts in the H and Z components. These phase shifts are not always accompanied by a latitudinal reversal in the sense of polarization in the horizontal plane. 相似文献
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Zoltan A. Der Douglas R. Baumgardt Robert H. Shumway 《Geophysical Journal International》1993,115(3):1012-1024
The particle motion of regional arrivals is frequently treated in automatic phase-recognition schemes as that appropriate to simple P or S waves incident on an elastic, laterally homogeneous half-space. This model implies that the motion in ' P -type' phases can be described in terms of a single, generalized signal process and ' S -type' phases in terms of two independent processes ( SV and SH ) and thus, all regional arrivals could be fully characterized by three components of motion. In this paper, we present anlyses of the particle-motion patterns of various regional arrivals recorded at the ARCESS array from closely spaced events in the Kola Peninsula. We have found that only Pn -particle motion, described in terms of two independent signal processes, can be reliably characterized by three-component recordings. On the other hand, the various regional arrivals following Pn , such as Pg and Sn and Lg , can only be poorly characterized on the basis of three-component recordings alone. The reason is that these arrivals must be described in terms of more than two independent generalized signal processes, at least three for Pg and Sn , and possibly up to five for Lg . Recognition of these phases will thus require the use of more sensors than signal processes in the observing sensor configuration, such as three-component sensors combined with a small tripartite array. We have investigated the feasibility of adaptive, automatic recognition of regional arrivials by a wavefield extrapolation scheme utilizing such a mini-array. The process, which appear to be promising, adaptively learns the particle-motion patterns of individual arrivals, including complex site-response functions, from examples of closely located regional events. 相似文献
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Summary. The polarizations of shear waves recorded by networks of digital three-component seismometers immediately above small earthquakes near the North Anatolian Fault in Turkey display shear-wave splitting on almost all shear-wave seismograms recorded within the shear-wave window. This splitting is incompatible with source radiation-patterns propagating through simple isotropic structures but is compatible with effective anisotropy of the internal structure of the rock along the ray paths. This paper interprets the phenomena in terms of widespread crack-induced anisotropy. Distributions of stress-induced cracks model many features of the observations, and synthetic polarization diagrams calculated for propagation through simulated cracked rock are similar to the observed patterns. This evidence for widespread crack-induced anisotropy lends strong support to the hypothesis of extensive-dilatancy anisotropy (EDA) suggested by laboratory experiments in subcritical crack-growth. The crucial evidence confirming some form of EDA would be observations of temporal changes in shear-wave splitting as the stress field alters the crack density and crack geometry. There is some weak evidence for such temporal changes at one site, but further analysis of suitable digital three-component seismometer networks in seismic areas is required to confirm EDA. 相似文献
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Surface wave tomography of the western United States from ambient seismic noise: Rayleigh and Love wave phase velocity maps 总被引：18，自引：0，他引：18
Fan-Chi Lin Morgan P. Moschetti Michael H. Ritzwoller 《Geophysical Journal International》2008,173(1):281-298
We present the results of Rayleigh wave and Love wave phase velocity tomography in the western United States using ambient seismic noise observed at over 250 broad-band stations from the EarthScope/USArray Transportable Array and regional networks. All available three-component time-series for the 12-month span between 2005 November 1 and 2006 October 31 have been cross-correlated to yield estimated empirical Rayleigh and Love wave Green's functions. The Love wave signals were observed with higher average signal-to-noise ratio (SNR) than Rayleigh wave signals and hence cannot be fully explained by the scattering of Rayleigh waves. Phase velocity dispersion curves for both Rayleigh and Love waves between 5 and 40 speriod were measured for each interstation path by applying frequency–time analysis. The average uncertainty and systematic bias of the measurements are estimated using a method based on analysing thousands of nearly linearly aligned station-triplets. We find that empirical Green's functions can be estimated accurately from the negative time derivative of the symmetric component ambient noise cross-correlation without explicit knowledge of the source distribution. The average traveltime uncertainty is less than 1 s at periods shorter than 24 s. We present Rayleigh and Love wave phase speed maps at periods of 8, 12, 16,and 20 s. The maps show clear correlations with major geological structures and qualitative agreement with previous results based on Rayleigh wave group speeds. 相似文献
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The basis for earthquake prediction 总被引：3，自引：0，他引：3
Stuart Crampin 《Geophysical Journal International》1987,91(2):331-347
Summary. Recent advances in understanding the behaviour of shear waves propagating in the crust make the routine prediction of earthquakes seem practicable. Accumulating evidence suggests that most of the Earth's crust is pervaded by distributions of fluid-filled cracks and microcracks that are aligned by the contemporary stress-field so that the cracked rockmass is effectively anisotropic to seismic waves. This causes shear-waves to split, and shear-wave splitting is observed whenever shear-waves propagating along suitable raypaths in the crust are recorded by three-component instruments. These distributions of cracks are known as extensive-dilatancy anisotropy or EDA. Many characteristics of the crack- and stress-geometry can be monitored by analyzing shear-waves propagating through the cracked rockmass. Observations of temporal variations of the behaviour of shear-wave splitting in seismic gaps confirm these hypotheses, and suggest that stress changes before earthquakes may be monitored by analyzing shear-waves. In particular, monitoring earthquake preparation zones with three-component shear-wave vertical-seismic-profiles could lead to techniques for the routine prediction of earthquakes. 相似文献
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Pascal Audet Michael G. Bostock Jean-Philippe Mercier 《Geophysical Journal International》2007,171(3):1212-1225
It is now widely accepted that elastic properties of the continental lithosphere and the underlying sublithospheric mantle are both anisotropic and laterally heterogeneous at a range of scales. To fully exploit modern three-component broad-band array data sets requires the use of comprehensive modelling tools. In this work, we investigate the use of a wide-angle, one-way wave equation to model variations in teleseismic 3-D waveforms due to 2-D elastic heterogeneity and anisotropy. The one-way operators are derived based on a high-frequency approximation of the square-root operator and include the effects of wave propagation as well as multiple scattering. Computational cost is reduced through a number of physically motivated approximations. We present synthetic results from simple 1-D (layer over a half-space) and 2-D (subduction zone) models that are compared with reference solutions. The algorithm is then used to model data from an array of broad-band seismograph stations deployed in northwestern Canada as part of the IRIS-PASSCAL/LITHOPROBE CANOE experiment. In this region radial-component receiver functions show a clear continental Moho and the presence of crustal material dipping into the mantle at the suture of two Palaeo-Proterozoic terranes. The geometry of the suture is better defined on the transverse component where subduction is associated with a ∼10 km thick layer exhibiting strong elastic anisotropy. The modelling reproduces the main features of the receiver functions, including the effects of anisotropy, heterogeneity and finite-frequency scattering. 相似文献
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Oleksandr Kit 《Applied geography (Sevenoaks, England)》2012,32(2):660-667
This paper outlines a methodology to identify informal settlements out of high resolution satellite imagery using the concept of lacunarity. Principal component analysis and line detection algorithms were applied alternatively to obtain a high resolution binary representation of the city of Hyderabad, India and used to calculate lacunarity values over a 60 × 60 m grid. A number of ground truthing areas were used to classify the resulting datasets and to identify lacunarity ranges which are typical for settlement types that combine high density housing and small dwelling size - features characteristic for urban slums in India. It was discovered that the line detection algorithm is advantageous over principal component analysis in providing suitable binary datasets for lacunarity analysis as it is less sensitive to spectral variability within mosaicked imagery. The resulting slum location map constitutes an efficient tool in identifying particularly overcrowded areas of the city and can be used as a reliable source in vulnerability and resilience assessments at a later stage. The proposed methodology allows for rapid analysis and comparison of multi-temporal data and can be applied on many developing urban agglomerations around the world. 相似文献
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Under Rayleigh equilibrium condition, stable isotopic ratio in residual water increases with the decrease of the residual water proportion f exponentially, and the fractionation rate of stable isotopes is inversely proportional to temperature. However, under kinetic evaporation condition, the fractionation of stable isotopes is not only related to the phase temperature but also influenced by the atmospheric humidity and the mass exchange between liquid and vapor phases. The ratio δ in residual water will not change with f after undergoing evaporation of a long time for great relative humidity. The rate that the evaporating water body reaches isotopic steady state is mainly dependent on the relative humidity in atmosphere. The analysis shows that the actual mean linear variety rates, about -30.0, of the δ18O in residual water versus the residual water proportion at Nagqu and Amdo stations are consistent with the simulated process under temperature of 20 oC and relative humidity of 50%. The distillation line simulated under Rayleigh equilibrium condition is analogous to the global meteoric water line (MWL) as the temperature is about 20 oC. Under non-equilibrium condition, the slope and constant values of distillation line are directly proportional to temperature and relative humidity. According to the basic data, the simulated distillation line is very consistent with the actual distillation line of Qinghai Lake. 相似文献