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孔辛头铜钼矿床产于胶东地区伟德山超单元院格庄二长花岗岩与荆山群大理岩接触带形成的夕卡岩中,主矿体呈透镜状、囊状、脉状产出,受岩体内部裂隙构造控制。分别采用电感耦合等离子体质谱、热表面电离质谱Re-Os同位素测试技术对其中的辉钼矿、黄铜矿、磁铁矿进行了研究。结果显示,辉钼矿Re-Os等时线年龄为117±1 Ma,黄铜矿Re-Os等时线年龄为118.4±3.2 Ma,与区域上尚家庄钼矿床、冷家钼矿床成矿时代一致,几个矿床成因均与伟德山超单元有关,表明了胶东地区存在燕山晚期的钼矿化事件。而磁铁矿Re-Os封闭性较差,无法得到年龄。黄铜矿初始~(187)Os/~(188)Os值为0.32±0.17,表明了孔辛头铜钼矿床金属成矿物质为壳幔混合来源,形成于早白垩世太平洋板块向亚欧大陆俯冲而成的弧后拉张背景之下。 相似文献
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内蒙古八大关斑岩型铜钼矿床成岩成矿年代学研究 总被引：4，自引：1，他引：3
八大关斑岩铜钼矿床是中国内蒙大兴安岭地区典型的斑岩型铜钼矿床之一。对矿区Ⅱ号岩体不同位置的2件岩石样品采用高精度的LA_ICP_MS锆石U_Pb测年,获得的锆石U_Pb年龄分别为(230.6±2.8)Ma和(230.5±4.4)Ma,两者在误差范围内非常一致,由此确认花岗闪长斑岩体的形成年龄约为230 Ma;对矿区7件辉钼矿样品采用Re_Os同位素测年,获得的Re_Os等时线年龄为(228.7±3.1)Ma,指示了八大关铜钼矿床辉钼矿的沉淀时间约为228.7 Ma。结合矿区岩相学、矿物学特征,辉钼矿呈浸染状分布于花岗闪长斑岩体内,且辉钼矿与黄铜矿密切共生,以及上述2种精确方法获得的年龄在误差范围内的一致性,说明花岗闪长斑岩即为成矿岩体,成岩与成矿大致同时或成矿略晚于成岩,表明八大关铜钼矿床形成于中三叠世,属于印支期成矿。 相似文献
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内蒙古北山地区小狐狸山钼矿床辉钼矿Re-Os同位素年龄及其地质意义 总被引：10，自引：1，他引：9
小狐狸山钼矿床是近年来在内蒙古北山地区新发现的一个具中型规模的隐伏矿床,辉钼矿化呈浸染状、星点状或细脉状分布于小狐狸山岩体的边缘相细粒花岗岩和过渡相中细粒似斑状花岗岩中,属斑岩型钼矿床.金属矿物主要为辉钼矿和黄铁矿以及少量的闪锌矿、黝铜矿、方铅矿、辉铋矿和磁铁矿.文章对矿床中6个辉钼矿样品进行了Re-Os同位素分析,获得模式年龄为216.3～220.1 Ma,等时线年龄为(220.0±2.2)Ma,MSWD值为0.54,187Os初始值为(0.23±0.30)ng/g.表明钼成矿时代为三叠纪,属印支期构造-岩浆活动的产物. 相似文献
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河南鱼池岭钼矿床辉钼矿铼-锇同位素年龄及地质意义 总被引：22，自引：12，他引：10
河南嵩县鱼池岭钼矿床是东秦岭钼矿带新发现的大型斑岩钼矿床,产于被前人认为白垩纪的合峪花岗岩基内部。鱼池岭矿床5件辉钼矿样品的铼锇同位素模式年龄介于(134.3±2.0)~(141.8±1.6)Ma 之间,铼锇等时线年龄为144.3±5.2Ma（1σ,MSWD=3.7）。据此,结合前人获得的年龄资料,确定合峪复式花岗岩基的岩浆侵入序列为：(1) 144Ma之前的似斑状黑云母二长花岗岩,(2) 144Ma左右的黑云母二长花岗斑岩,(3) 136~127Ma左右的巨斑状黑云母二长花岗斑岩,(4) <127Ma的(石英)正长斑岩脉或岩株;合峪复式花岗岩基形成于晚侏罗世—早白垩世,而非前人认为的仅限于白垩纪;成岩成矿构造背景为碰撞加厚的造山带地壳和岩石圈的伸展减薄或减压增温体制,岩浆侵入和成矿作用与地壳快速隆升事件相伴随。 相似文献
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内蒙东部白土营子钼铜矿田的矿床地质特征、辉钼矿Re-Os年龄及其意义 总被引：5，自引：1，他引：4
白土营子斑岩型-石英脉型钼铜矿田是华北板块北缘西拉沐沦钼矿带南部新近发现的与岩浆热液活动密切相关的钼铜成矿系统.本文在矿床地质特征研究的基础上,对矿田内三个重要钼铜矿床开展了辉钼矿Re-Os同位素定年,初步获得:1)白土营子斑岩型钼铜矿床的成矿年龄为248.O±10Ma(MSWD=0.52,n=6);2)白马石沟石英脉型铜钼矿的成矿年龄为248.6±6.7Ma(MSWD=1.06,n=4);3)库里吐石英脉型钼铜矿的成矿年龄为245.0±4.3Ma(MSWD =0.71,n=5);这一结果揭示该矿集区的钼铜矿化发生在早三叠世.该成矿系统的形成适值早三叠世西伯利亚板块与华北板块碰撞造山过程的晚期,二长花岗斑岩的UST结构证明含矿流体来自岩浆作用.早三叠世钼铜成矿作用在华北板块北缘及邻区有一定的普遍性,找矿前景可观. 相似文献
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内蒙古苏尼特左旗乌兰德勒钼铜多金属矿床辉钼矿铼-锇同位素定年及其地质特征 总被引：14，自引：0，他引：14
中蒙边境内蒙古苏尼特左旗乌兰德勒钼铜多金属矿床是内蒙古二连—东乌旗成矿带上近几年国土资源地质大调查工作过程中新发现的一个规模较大的矿床,包括赋存于上部细粒石英闪长岩、中粗粒花岗闪长岩中细脉浸染状矿体和赋存于隐伏的细粒二长花岗岩中的浸染状矿体,属典型的斑岩型钼矿床。文章通过采集WZK1钻孔211.2～214m细脉浸染状矿石的辉钼矿纯样,获得辉钼矿的等时线年龄为(134.1±3.3)Ma,并对比了矿区细粒二长花岗岩的锆石SHRIMP年龄(131.4±1.6)Ma,两者基本一致,表明矿床的形成主要与隐伏的燕山期细粒二长花岗岩有着密切关系。测定的辉钼矿铼-锇同位素年龄能够精确代表该矿床的成矿时间,表明在乌兰德勒区域找矿工作中,需要密切关注燕山期构造-岩浆活动的相关成矿作用。 相似文献
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哈萨克斯坦阿克沙套大型钨钼矿床处于中亚成矿域巴尔喀什成矿带内。该矿床为云英岩型浸染状矿床, 具有云英岩型矿床的典型矿物组合、围岩蚀变、矿体形态和结构构造。矿区产出有伟晶岩、石英长石脉, 含有钨钼矿、石英和黄玉云英岩矿体等。本文对阿克沙套钨钼矿床辉钼矿样品进行了铼-锇同位素分析, 得到辉钼矿模式年龄(平均值)为289.3 Ma, 处在早二叠世。分析认为, 阿克沙套云英岩型钨钼成矿作用是晚石炭世中亚成矿域大规模斑岩型铜钼成矿作用延续的结果, 属中亚造山带海西晚期构造-岩浆活动的产物。 相似文献
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河南沙坡岭矿床位于华北克拉通南缘的熊耳地体,产在燕山期花岗岩与围岩太华超群的外接触带,为东秦岭最近发现的细脉浸染型钼矿床。矿体受断裂或围岩裂隙控制,呈细脉、网脉状产出,矿石类型包括细脉状、浸染状和块状。为确定沙坡岭钼矿床成矿时代,本文利用辉钼矿Re-Os同位素定年,研究表明:采集的6件辉钼矿样品Re-Os单样年龄为158.3±1.5~160.7±1.2 Ma,其加权平均值为160±1 Ma(2σ误差,MSWD=2.1),指示沙坡岭钼矿化发生于晚侏罗世,且早于花山岩基约30 Ma,指示与花岗岩基无关。另外,一件产于花山复式岩体的团块状辉钼矿样品Re-Os单样年龄为130.5±1.0 Ma,与赋矿的花山岩体成岩时代一致,同样与前人报道的辉钼矿年龄(125.4~129.4 Ma)基本一致,且不存在明显的单颗粒辉钼矿187Os迁移,表明部分钼矿化形成于早白垩世。因此,辉钼矿Re-Os同位素定年显示沙坡岭矿床存在晚侏罗世和早白垩世两期钼矿化。结合矿床地质特征、成矿构造演化,认为沙坡岭钼矿与熊耳地体的花山岩基、花岗斑岩以及相关热液矿床,均属于秦岭造山带陆陆碰撞过程中挤压向伸展转变体制的产物。 相似文献
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马家洼金钼矿床位于小秦岭北缘,矿体发育在由近东西向脆韧性断裂构造带控制的石英脉中。对该矿床辉钼矿样品进行的Re-Os同位素年代学研究表明:模式年龄范围是232.5～268.4 Ma,等时线年龄为(232±11)Ma,即钼成矿作用时代为早、中三叠世。辉钼矿样品的Re含量范围是(0.474～0.791)×10~(-6),初始~(187)Os/~(188)Os比值为2.4±6.4,Re-Os同位素组成特征指示了成矿物质主要来源于地壳。马家洼石英脉型金钼矿床是区域伸展体制下构造-流体成矿事件的产物。在华北板块南缘太古宙基底岩系中的脆韧性断裂构造带中寻找印支期和燕山期石英脉型金钼矿床和钼矿床是一个新的找矿方向。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献