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松潘-甘孜地块的丹巴二叠纪玄武岩(大石包组)具有较高的TiO2含量(>2%)和高的Ti/Y比值(平均519),显示LREE富集、HREE亏损的右倾型稀土配分型式((La/Yb)N=4.2~13.6),εNd(t)=-0.33~2.70,具有洋岛玄武岩(OIB)地球化学特征,形成于大陆板内环境。其源区来自原始地幔始于石榴子石稳定区的低程度部分熔融,岩浆上升过程中有来自地壳物质的加入,因而其不相容元素比值如Zr/Nb(4.41~13.09)、La/Nb(1.03~1.80)和Th/La(0.08~0.18)等,以及初始的87Sr/86Sr比值(0.706008~0.707257)均表现出不同程度的富集特征,岩浆演化早期经历了以辉石、橄榄石为主的分离结晶作用。该套玄武岩的元素-同位素地球化学特征和源区性质类似于峨眉山溢流玄武岩的高钛(HT)系列,因此认为其是峨眉山地幔柱活动的产物,属于峨眉山大火成岩省(ELIP)的一部分。松潘-甘孜地块和扬子西缘晚古生代以前地层的可比性以及峨眉山溢流玄武岩的分布特征显示,松潘-甘孜洋盆伴随着扬子克拉通的裂解而打开,并且可能都与峨眉山地幔柱有关,是地幔柱活动的浅部地质响应。 相似文献
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对扬子地块西缘康滇裂谷北段的丹巴变质玄武岩进行了系统的岩石学、元素-Nd同位素地球化学研究,结果表明该岩石为碱性玄武岩,样品相对富MgO、富TiO2,Mg#值介于0.51～0.59之间.稀土总量较高,轻重稀土分馏较明显,Th、Nb、Ta、Zr、Hf和LREE等不相容元素富集,Y和HREE明显亏损,地球化学特征与洋岛玄武岩(OIB)类似.岩浆形成于板内裂谷环境,起源于类似OIB的地幔源区,并在上升过程中受到了大陆岩石圈地幔(SCLM)物质不同程度的混染,同时还可能有少量下地壳物质的混染.样品在岩石化学上表现出地幔柱岩浆作用的痕迹,很可能与导致Rodinia超级大陆裂解的新元古代地幔柱事件有关. 相似文献
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滇西丽江及宁蒗、永胜地区广泛分布二叠纪玄武岩,它们可能是峨眉山大火成岩省的一部分。通过对丽江树底桥及宁蒗万马场二叠纪玄武岩进行的地球化学系统采样研究,认为这些玄武岩富集大离子亲石元素及高场强元素,具有与洋岛玄武岩相似的地球化学特征。与典型的峨眉山玄武岩地球化学成分的对比研究认为其属于峨眉山高钛玄武岩,为峨眉山地幔柱活动的产物。利用稀土元素进行反演模拟,估算高钛玄武岩源区的成分及岩浆的演化趋势,模拟计算结果显示,丽江树底桥玄武岩可能来自于尖晶石二辉橄榄岩与石榴石二辉橄榄岩的过渡源区(尖晶石∶石榴石=65∶35～1∶1)2%～3%的部分熔融,并经历了以单斜辉石为主的分离结晶作用(5%～15%);万马场玄武岩来自于相似的源区(尖晶石∶石榴石=45∶55～1∶1)3%左右的部分熔融,分离结晶程度≤5%。 相似文献
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桂西地区位于扬子地块西南缘,越北地块以北。桂西巴马等地出露层状—似层状基性岩（辉绿岩和玄武岩）,该地区的基性岩成因对于理解该区构造—岩浆作用具有十分重要的意义。对桂西巴马基性岩进行了岩石学和地球化学研究,对其岩石成因和岩浆源区特征进行了讨论。研究表明,桂西巴马基性岩属于碱性玄武质岩,相对富集轻稀土元素和Nb、Ti等微量元素,与峨眉山大火成岩省高Ti玄武岩相似,说明其与峨眉山地幔柱具有相关性。然而,对比峨眉山高Ti玄武岩,巴马基性岩表现出更高的Ti/Y值。不相容元素比值特征表明,桂西巴马基性岩岩浆演化呈现更高的Nb/Y值等演化趋势。结合Dy/Dy?与Dy/Yb、Ti/Y的协变关系,对桂西基性岩与峨眉山玄武岩岩浆源区中稀土元素的分异特征进行判别,揭示出桂西巴马基性岩和峨眉山高Ti玄武岩具有同源性。然而,巴马基性岩地幔熔融程度更低,可能是峨眉山大火成岩省外带的地幔柱岩浆作用延伸的结果,代表了峨眉山地幔柱高Ti玄武岩母岩浆的特征。 相似文献
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桂西地区位于扬子地块西南缘,越北地块以北。桂西巴马等地出露层状—似层状基性岩(辉绿岩和玄武岩),该地区的基性岩成因对于理解该区构造—岩浆作用具有十分重要的意义。对桂西巴马基性岩进行了岩石学和地球化学研究,对其岩石成因和岩浆源区特征进行了讨论。研究表明,桂西巴马基性岩属于碱性玄武质岩,相对富集轻稀土元素和Nb、Ti等微量元素,与峨眉山大火成岩省高Ti玄武岩相似,说明其与峨眉山地幔柱具有相关性。然而,对比峨眉山高Ti玄武岩,巴马基性岩表现出更高的Ti/Y值。不相容元素比值特征表明,桂西巴马基性岩岩浆演化呈现更高的Nb/Y值等演化趋势。结合Dy/Dy*与Dy/Yb、Ti/Y的协变关系,对桂西基性岩与峨眉山玄武岩岩浆源区中稀土元素的分异特征进行判别,揭示出桂西巴马基性岩和峨眉山高Ti玄武岩具有同源性。然而,巴马基性岩地幔熔融程度更低,可能是峨眉山大火成岩省外带的地幔柱岩浆作用延伸的结果,代表了峨眉山地幔柱高Ti玄武岩母岩浆的特征。 相似文献
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广泛分布于中国西南川、滇、黔三省的峨眉山玄武岩是我国最早被国际认可的大火成岩省,受到了国内外学者的广泛关注。前人对大火成岩省西区玄武岩已达成多项共识,而对东区玄武岩的岩石组合、火山活动时限、岩石成因等方面还存在诸多争议。本文以峨眉山大火成岩省东区贵州普安玄武岩系为研究对象,通过解析典型剖面,明确该区玄武岩系岩石类型从底到顶总体为第1旋回的爆发相火山角砾岩、第2旋回的溢流相玄武岩以及第3旋回的火山沉积相凝灰岩。玄武岩系顶部凝灰岩锆石LA-ICP-MS U-Pb测年结果限定了大火成岩省东区火山活动时间持续上限为250 Ma。主微量元素显示该区玄武岩系以高Ti碱性玄武岩为主。玄武岩稀土元素球粒陨石标准化为轻稀土元素富集的右倾曲线模式,Rb和Sr亏损、Ba和Hf富集等特征与贵州地区玄武岩、峨眉山大火成岩省西区高Ti玄武岩以及OIB地球化学特征基本一致。微量元素显示该区玄武岩源区可能为受交代的石榴石地幔橄榄岩,由深部地幔柱上升至石榴石橄榄岩稳定区部分熔融产生熔融体,和富集交代流体的大陆岩石圈地幔混合形成,岩浆上升运移过程中发生了一定程度分离结晶作用和微弱地壳混染作用。研究表明,峨眉山大火成岩省东区普安玄武岩系形成于峨眉山地幔柱边部埋深较大、低程度部分熔融以及高压的环境。 相似文献
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峨眉山火成岩省东部盐津地区玄武岩的岩石地球化学分析结果表明,盐津玄武岩w(SiO2)为47.97%~52.33%,w(Na2O+K2O)为3.35%~6.57%,Ti/Y值为496.29~567.80,w(TiO2)为3.60%~4.14%,属于钙碱性高钛玄武岩(HT)。岩石LREE/HREE值为7.34~7.88,轻稀土元素富集,分馏程度高,总体亏损Ba,K,Sr,P。高场强元素Nb/U比值为26.39,Ce/Y-Sm/Y和Th/Nb-Ce/Nb等比值均呈明显正相关系,表明盐津地区峨眉山玄武岩受到了明显地壳混染作用。Nb-Nb/Y和La-La/Sm图解中样品投点呈倾斜直线,表明盐津玄武岩岩浆受分离结晶作用影响较弱,δEu值为0.86~0.93,CaO/Al2O3与Mg#无明显相关关系,以及镜下观察均表明仅有少量斜长石、单斜辉石的分离结晶。盐津玄武岩与盐源和越西等地高钛玄武岩地球化学特征相似,具地幔柱成因特征,岩浆可能起源于富集地幔。分配系数相近的强不相容元素Ce/Sm比值为25.50,La/Yb-Sm/Yb图解中样品靠近石榴石尖晶石二辉橄榄岩区域,表明岩浆源区为石榴石尖晶石二辉橄榄岩。 相似文献
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广西涠洲岛晚新生代玄武岩地幔源区及岩浆成因 总被引：1，自引：0，他引：1
涠洲岛作为我国最年轻的第四纪火山岩岛,其火山活动表现出多期、多旋回和多喷发中心的特征,但其地幔源区特征和岩浆成因依然存在争议。本文对涠洲岛玄武岩开展了详细的矿物学和全岩主、微量元素及Sr-Nd-Pb同位素研究,以揭示其地幔源区特征和岩浆成因。涠洲岛玄武岩主要为碱性玄武岩,在岩浆上升过程,几乎未受到地壳物质的混染,经历了橄榄石和单斜辉石的分离结晶作用。轻稀土(LREE)富集、重稀土(HREE)亏损,轻、重稀土强烈分馏((La/Yb)N=14.42～28.64),Nb、Ta明显正异常,显示出与洋岛玄武岩(OIB)相似的微量元素和Sr-Nd-Pb同位素特征。Sr-Nd-Pb同位素比值变化较均一,且呈现出亏损地幔端元(DM)与富集地幔端元(EM2)的二元混合趋势。其中,EM2端元可能源于海南地幔柱。Sr/Sr*(1.21～2.36)和Eu/Eu*(1.01～1.11)正异常,指示源区存在再循环辉长岩洋壳组分。结合已有的地震层析成像结果和岩石地球化学数据,得出南海及周缘地区的晚新生代玄武岩的形成受控于海南地幔柱。伴随着海南地幔柱的上升,再循环的辉长岩洋壳经部分熔融与地幔橄榄岩反应生成石榴石辉石岩(贫硅辉石岩),石榴石辉石岩和未反应的地幔橄榄岩混合部分熔融形成涠洲岛玄武岩。 相似文献
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本文报道了六合-仪征第三纪大陆碱性玄武岩十八个样品的REE、Rb、Ba、Sr、Nb、Zr、Ni、Cr、V、Sc、Y、Ga、Zn、Cu等痕量元素含量,讨论了该岩套的成因及其地幔源区的特征。石榴石橄榄岩型地幔源区经较小程度部分熔融形成了基性原始岩浆;其后经过橄榄石和单斜辉石为主的结晶分异作用,演化后的岩浆喷出地表形成玄武岩套。本区碱性玄武岩的地幔源区曾受近期富集作用影响,具有富集LREE等不相容元素的特征。 相似文献
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The basalt clan 总被引：1，自引：0，他引：1
Eric A.K. Middlemost 《Earth》1975,11(4):337-364
The major element compositions of the various rocks that belong to the basalt clan are examined, and the basalt clan is defined as consisting of those volcanic rocks that contain between 44.0% and 53.5% silica. After examining both the diverse tectonic environments in which the basaltic rocks are found, and also the various petrographic suites to which they belong, or appear to belong, new chemical criteria were devised to divide them into the following groups: (1) low-potash basalt, (2) high-alumina basalt, (3) continental-flood basalt, (4) komatiitic basalt, (5) sodic basalt, (6) hawaiite, (7) phonolitic basalt, (8) potassic basalt, (9) trachybasalt, (10) leucitite, (11) sodic transitional basalt, and (12) potassic transitional basalt. The lunar mare-basalts are regarded as being transitional in their chemical character between the low-potash, ocean-floor basalts and the komatiitic basalts. While it was relatively easy to discover petrogenetic models that were able to account for the origin and evolution of the common sub-alkalic basalts, and even the sodic basalts, a variety of possible petrogenetic models had to be explored in order to account for the origin and evolution of the different basaltic rocks of the potash- and high-potash series. 相似文献
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利用地球化学方法判别大陆玄武岩和岛弧玄武岩 总被引：45，自引：0，他引：45
大陆地壳或岩石圈的混染作用可以给出似消减带信号,并导致将受到混染的大陆玄武岩误判为岛弧玄武岩。没有受到混染的软流圈(或地幔柱)源大陆玄武质岩石通常是以(Th/Nb)N<1、Nb/La≥1、低87Sr/86Sr(t)比值、高εNd(t)值及La/Nb和La/Ba比值与洋岛玄武岩相似并以具有缺乏Nb、Ta、Ti负异常的“隆起”状多元素地幔标准化分配型式为特征。当在所研究的火山岩系中发现有未受到混染的软流圈(或地幔柱)源玄武质岩石存在,基本上就可以排除它们有属于岛弧或活动大陆边缘火山岩系的可能。对于那些具有消减带信号的基性熔岩,可以根据Zr含量和Zr/Y比值,或利用Zr/Y-Zr图解,判断它们是否真正是岛弧或活动大陆边缘玄武岩。 相似文献
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峨眉山大火成岩省西部苦橄岩及其共生玄武岩的地球化学：地幔柱头部熔融的证据 总被引：12，自引：12，他引：12
丽江地区的苦橄岩位于峨眉山大火成岩省的西部，其与辉斑玄武岩、无斑玄武岩和玄武质火山碎屑岩共生。苦橄岩中的斑晶主要为富镁橄榄石，其F0含量最高达91．6％，CaO含量最高达0．42％，其内含有少量玻璃包裹体，指示了橄榄石是在熔体中结晶形成的。苦橄岩中的铬尖晶石具有高的Cr#值（73-75）。计算的初始岩浆的MgO含量大约为22wt％，初始熔融的温度为1630-1680℃。研究结果表明，玄武质岩石是苦橄质岩浆通过橄榄石和单斜辉石分离结晶形成的。苦橄岩和玄武岩的Nd-Sr-Pb同位素比值差别不大，只落在一个很小的范围内（如εNd（t）=-1．3 to＋4．0）。高的εNd（t）值以及抗蚀变不相容元素的原始地幔标准化图解与洋岛玄武岩相似，并且其重稀土元素特征指示了源区有石榴子石的残余，而且是低部分熔融的产物。同位素比值与抗蚀变不相容元素比值（如Nb／La）的相关性表明，岩浆形成过程中有少量的大陆地壳物质或者相对低εNd（t）组分的大陆岩石圈地幔的混染。因此，总体上，苦橄岩的地球化学特征的研究结果支持了峨眉山大火成岩省是地幔柱头部熔融的成因模型。 相似文献
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Thermochemistry and melting properties of basalt 总被引：1，自引：0，他引：1
M. A. Bouhifd P. Besson P. Courtial C. Gérardin A. Navrotsky P. Richet 《Contributions to Mineralogy and Petrology》2007,153(6):689-698
The heat capacities of the liquid, glassy and crystalline phases of an alkali basalt have been determined from relative enthalpies
measured between 400 and 1,800 K. Values given by available models of calculation generally agree to within 2% of these results.
As derived from the new data and the enthalpy of vitrification measured at 973 K by oxide-melt drop solution calorimetry for
the same sample, the enthalpy of fusion of this basalt increases from 15.4 kJ/mol at 1,000 K to 33.6 kJ/mol at 1,800 K. Comparisons
between the enthalpies of fusion of basalt and model compositions confirm the small magnitude of the enthalpy of mixing between
the molten mineral components of the liquids. Minor variations in the chemical composition have only a small effect in the
heat capacity and the enthalpy of melting of basalt. The enthalpies of formation at 298 K from the oxides of the crystallized
and glass phases of this alkali basalt are −112.2 and −98.5 kJ/mol, respectively, for a gram formula weight based on one mole
of oxide components. 相似文献
16.
The genesis of mid-ocean ridge basalt 总被引：2，自引：0，他引：2
J.F.G. Wilkinson 《Earth》1982,18(1):1-57
The tholeiitic volcanics erupted at mid-ocean ridges (mid-ocean ridge basalts or MORB) constitute the dominant volcanic lithology on Earth. Analyses of tachylites from Atlantic, Pacific and Indian Ocean spreading centres range widely in 100 Mg/(Mg + Fe2+) ratios (= M) and M varies from 70 to 30. Glasses with M = 55?65 are the most common variants and only a small percentage of glass analyses has M approaching 70. The latter defines the M -value of basaltic melts in equilibrium with residual upper-mantle source peridotites with M ～ 88. The frequency histogram of the M -values of average compositions of MORB glasses at 88 ocean floor localities is similar in analysis distribution to the frequency histograms depicting variation in the M -values of glasses from the various spreading centres.M -values and nickel contents of MORB and the nature and compositions of the near-liquidus phases crystallized experimentally from MORB melts at elevated pressures have been applied to identify primary (unfractionated) melts erupted in a mid-ocean ridge environment. However, Ni abundances and high-pressure phase relationships are not necessarily unique or definitive parameters of primary melts. The latter are generally linked genetically with Mg-rich lherzolitic source rocks of ‘pyrolite’ type (M ～ 90. The spectrum of M -values displayed by MORB glasses, with a definite bias towards relatively Fe-rich compositions (average M of approximately 600 MORB glasses is 58.6), suggests that the melts may have evolved either via ferromagnesian fractionation of relatively Mg-rich parental melts (M = 70?80), or by partial melting of a heterogeneous upper mantle with variable M values, or as a result of magma mixing of already fractionated melts and primitive magma batches.For a number of reasons fractonation models based on the extraction of olivine or one or more of olivine, plagioclase and clinopyroxene, either from picritic melts (M > 75 or ‘primitive’ basaltic melts with M ～ 70, are questionable as prime controls of MORB chemistry. These include: (1) the extreme rarity of ‘quenched’ picritic or Mg-basaltic melts in ocean ridge environments; (2) the lack of adequate evidence of the appropriate (of necessity voluminous) complementary cumulates (dunites, allivalites, troctolites, anorthosites) demanded by olivine, plagioclase, or olivine + plagioclase fractionation models; and (3) the aberrent frequencies of glass M -values whereby the assumed derivatives (M = 55?65 are much more abundant (and presumably much more voluminous) than the alleged parents or transitional derivatives (65 < M < 75). The nature of the trends of Na2O, CaO and Al2O3 in Galapagos Spreading Centre tachylites of extended composition (M = 65?30) indicates the ‘gabbroic’ fractionation is also unlikely to exert important controls on MORB chemistry.As their M -values increase, mid-ocean ridge basalts increase in Al, Ca, Ni, Co, Cr and decrease in Ti, Mn, Na, K and P. Except for Al and Ca, these trends are similar to those displayed by upper-mantle peridotites increasing in M, i.e., becoming more refractory following one or more partial melting episodes. It is suggested that at least a majority of mid-ocean ridge basalts is intrinsically primary and generated by variable degrees of partial melting of heterogeneous lherzolitic upper mantle (80 < M < 90) with variable abundances of elements such as Ti, Al, Ca and Na and also depleted in large ion lithophile (LIL) elements. Negative europium anomalies in the rare-earth patterns of some oceanridge basalts (ferrobasalts with low M) are ascribed mainly to the persistence of residual plagioclase in relatively Fe-rich plagioclase lherzolite source rocks, following low degrees of partial melting. The partial melting events leading to the generation of mid-ocean ridge basalts took place over a relatively modes pressure range (approximately 8–15 kb) which encompassed the transition of plagioclase lherzolite to spinel lherzolite. This proposal appears consistent with the nature and occurrence of megacrysts (xenocrysts) of tschermakitic Cr-diopside (Ca43Mg52Fe5), olivine (mg 89–91), plagioclase (An92-85) and spinel (Fe2Al60Cr38) in some MORB. The megacryst compositions suggest that these phases represent disaggregated plagioclase peridotite or spinel lherzolite acquired by melts during their passage through the oceanic upper mantle. 相似文献
17.
大陆板内玄武岩数据挖掘:成分多样性及在判别图中的表现 总被引：7，自引：4，他引：3
通常认为,大陆溢流玄武岩(CFB)、裂谷玄武岩(CRB)、板内玄武岩(WPB)均产于板内构造环境,其地球化学特征与OIB类似,源于富集的下地幔,与地幔柱的活动有关。本文利用GEOROC数据库对全球CFB、CRB和WPB数据进行挖掘,发现上述三类玄武岩判别图投图几乎落入了全部的构造环境域,有些甚至主要落入MORB和IAB区,而不是落入WPB区。结果表明原先的玄武岩判别图的判别功能值得商榷,尤其对大陆玄武岩来说,许多判别图都存在问题。全体CFB、CRB和WPB的地球化学成分变化巨大,暗示其源区具有强烈的不均一性:部分CFB、CRB和WPB来自富集的地幔柱,仍然具有经典的OIB的特征;部分来自MORB的源区,与MORB的再循环作用有关;部分来自岛弧岩石圈之下的亏损地幔源区,以强烈亏损Nb-Ta为特征,类似岛弧玄武岩的地球化学特征。许多地区的大陆玄武岩可分为低钛和高钛两类,低钛玄武岩大多是亏损或强烈亏损的,而高钛玄武岩通常是富集型的。本文的研究表明,富集型大陆玄武岩可能来自富集的下地幔,而亏损的和强烈亏损的玄武岩可能来自具有MORB或岛弧特征的软流圈地幔。进一步指出,源区性质可能是大陆玄武岩多样性的主控因素,其次为部分熔融程度、熔融深度、结晶分离、陆壳混染以及AFC过程。 相似文献
18.
On the ages of flood basalt events 总被引：2，自引：0，他引：2
We review available data constraining the extent, volume, age and duration of all major Phanerozoic continental flood basalts (CFB or traps) and oceanic plateaus (OP), together forming the group of large igneous provinces (LIP), going from the smallest Columbia flood basalts at ～16 Ma to the as yet ill-known remnants of a possible trap at ～360 Ma in eastern Siberia. The 16 traps (CFB and OP) reviewed form a rather unimodal distribution with an initial modal volume of the order of 2.5 Mkm3. Most provinces agree with a rather simple first order model in which volcanism may have lasted of the order of 10 Ma, often resulting in continental break-up, but where most of the volume was erupted in about 1 Ma or sometimes less. This makes CFBs/OPs (LIPs) major geodynamic events, with fluxes exceeding the total output of present day hot spots and even possibly exceeding over short times the entire crustal production of mid-ocean ridges. The proposed correlation between trap ages and the ages of several geological events, including mass extinctions and oceanic anoxia, is found to have improved steadily as more data have become available, to the point that the list of trap ages may coincide with many major divisions in the geological time scale. The four largest mass extinctions in the last 260 Ma coincide to the best resolution available with four traps, making a causal connection between the two through some form of catastrophic climatic perturbations the most likely hypothesis. The time sequence of LIPs appears to have been random and there is no robust evidence for long time trends in the corresponding crustal production rate over the last 260 Ma. 相似文献
19.
Mark D. Feigenson Albrecht W. Hofmann Frank J. Spera 《Contributions to Mineralogy and Petrology》1983,84(4):382-389
The simplified model of basalt genesis described in Part I of this series, equilibrium partial melting followed by Rayleigh-type fractional crystallization, is applied to a stratigraphically controlled sequence of basalt flows from Kohala volcano. Major-element compositions were determined for 52 samples and show a time-stratigraphic progression from tholeiites through transitional basalts to alkali basalts. Twenty-six of these samples were analyzed by isotope dilution for K, Rb, Cs, Sr, Ba and the REE, 13 for87Sr/86Sr, and 19 for Co, Cr, Ni and V by atomic absorption. After a simple, first-order correction for the effects of fractional crystallization (involving mostly olivine and aluminous clinopyroxene), the major element concentrations cluster tightly, and the incompatible trace elements show monotonic increases in concentration as a function of stratigraphic height. The process identification plot shows that all the (fractionation corrected) melt compositions can be explained by equilibrium partial melting of compositionally identical batches of source material. The REE and Sr are fractionated because of the presence of residual clinopyroxene. Garnet may also be present but in much smaller amounts. In this respect our results differ significantly from those of Leeman et al. (1980). The calculated chondrite-normalized REE patterns of the source are nearly flat to slightly convex upward. Therefore there is no need to invoke special mechanisms, such as metasomatic REE preenrichment of the source, in order to explain the petrogenesis of the suite of lavas. Specifically, Ce concentrations ranging from 20 to 250 times chondritic are all explained by the same calculated source pattern having a chondrite-normalized ratio of Ce/Sm=0.9±0.2. However, the normalized ratio Ce/Ba?2 shows that the source is not simply primitive mantle. 相似文献
20.
This paper outlines in general terms the role of metamorphic transformations during rock deformation. Long duration, triaxial stress relaxation tests at 600°C. 160 MPa confining pressure on wet crushed basalt, sheared in sawcuts made in intact basalt cylinders are reported. Mechanical data are interpreted in terms of a material which shows a small strain-rate sensitivity to large variations in applied stress, but which work hardens dramatically as a result of marked microstructural changes which occur during straining. Permanent distortions of c. 20% were produced in the samples.Tests at 100 MPa pore-water pressure resulted in the formation of oriented overgrowths of amphibole, preferentially developed on less stressed interfaces between original grains and in pore spaces. Substantial redistribution of feldspar also occurred. At low pore pressures no amphibole formed and only feldspar was recrystallized. Much of the original porosity of the rock was eliminated in all cases.The mechanical and microstructural data are interpreted in terms of flow by some combination of grain sliding and diffusional accommodation, with the reprecipitated, diffused material being the product of a chemical reaction involving all original solid phases plus water. From a consideration of the effects of the reaction on the chemical potential gradients driving diffusion, it is concluded that although the syntectonic hydration exerts a profound effect on the microstructural and mineralogical development of the rock during deformation, there is no substantial enhancement of the rate of strain.Similar microstructural developments also occur in natural rocks deformed during retrogressive metamorphic events, and examples are described for comparison. 相似文献