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本文通过野外观察和室内研究,分析了贵州从江南加地区钨铜多金属矿的成矿规律,初步建立了成矿模式。南加地区钨矿的形成时代大致相当于雪峰期,铜矿主成矿期可能属于印支—燕山期。钨矿主要是该区雪峰期花岗岩和四堡群鱼西组地层提供成矿物质,而铜矿成矿物质可能来源于围岩花岗岩及深源。该区钨矿床主要分布在花岗岩体与四堡群变质岩的外接触带,受鱼西组中层间破碎带控制,形成部位主要是花岗岩凹陷部位,铜矿床主要分布在花岗岩体内部EW、NW和NNE向断层破碎带中,形成部位主要是花岗岩体顶部凸起部位。 相似文献
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大兴安岭锡多金属成矿带花岗岩地球化学特征 总被引：5，自引：0，他引：5
大兴安岭中南段华力西褶皱带是我国北方重要的锡多金属成矿带。已发现了许多大中型锡矿床、锡多金属矿床、铅锌矿床、铜矿床等。这些矿床形成与花岗岩有密切成因联系。本文较详细地阐述了花岗岩产出的地质背景,各期次花岗岩的地球化学特征,提出与成矿有关的花岗岩体地质地球化学判别标志。 相似文献
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新疆巴音布鲁克乔霍特铜矿区钾长花岗岩中钾长石的^40Ar-^39Ar年龄及其地质意义 总被引：5，自引：0，他引：5
采用单矿物40Ar-39Ar同位素年代学方法,对乔霍特铜矿区钾长花岗岩中钾长石进行精确的年龄测定,获得坪年龄为274.78±0.44 Ma,等时线年龄为272.7±3.0 Ma.鉴于该钾长花岗岩体形成之后未见构造变形和热液蚀变现象,因此40Ar-39Ar同位素年龄代表钾长花岗岩中钾长石结晶年龄,即钾长花岗岩体的结晶晚期年龄.根据钾长花岗岩体和乔霍特铜矿体的空间关系、铜矿石的品位变化、钾长花岗岩和铜矿石的稀土元素特征及铜矿石流体包裹体氢氧同位素组成等,认为乔霍特铜矿床的成矿作用直接与钾长花岗岩的侵入活动有关,钾长花岗岩中钾长石结晶年龄基本上代表乔霍特铜矿床成矿时代的下限. 相似文献
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江西卧龙谷花岗岩和铜厂花岗闪长斑岩的地球
化学特征及成因
——对赣东北地区铜矿成矿地质背景的制约 总被引：2，自引：1，他引：1
赣东北地区是江南造山带东北段重要的多金属成矿区。卧龙谷花岗岩体是典型的非铜矿成矿花岗岩体,由二长花岗岩组成,其LA-ICP-MS锆石U-Pb同位素分析揭示其岩浆结晶年龄为133 Ma±1Ma,形成于早白垩世。这些岩石表现出高的初始87Sr/86Sr比值（0.716079~ 0.719392）和较低的εNd(t)（-6.51~-5.14）值,指示其岩浆起源于壳源变质沉积岩部分熔融。铜厂花岗闪长斑岩体是典型的铜矿成矿花岗岩体,主要由花岗闪长斑岩组成,形成于中侏罗世（171Ma±3Ma）,表现出很低的初始87Sr/86Sr比值（0.704403~0.704475）、较高的εNd(t)（-1.14~+1.80）和高的Mg#值（28~53）,指示铜厂花岗闪长斑岩体可能为俯冲板片和俯冲沉积物部分熔融的产物,并受到幔源物质污染。通过非铜矿成矿卧龙谷花岗岩和成矿的铜厂花岗闪长斑岩的对比,分析中生代花岗质岩浆作用对成矿地质背景的制约,为区域斑岩型铜矿找矿提供找矿标志和基础地质背景资料。 相似文献
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甘肃梧桐井铁铜多金属矿区已发现的铁铜矿体主要产于大理岩和斜长花岗岩接触带上,严格受北东向断裂控制。在该矿区实施了1∶10000地面高精度磁测和1∶10000激电中梯测量工作。综合研究物探异常发现,不论磁异常还是激电异常,其展布方向均与矿区地层、构造走向基本一致,与地质构造关系密切,具有重要的找矿意义。圈定的磁异常和激电异常都是该区勘查铁、铜矿的直接找矿标志。激电异常和磁异常同时出现,特别是当激电异常处于磁异常强梯度带上时应高度重视。本次研究利用综合物探方法,结合矿区地质特征,进行了成矿预测,有效地指导了地质找矿工作,取得了较好的勘查效果。 相似文献
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贵州南加花岗岩类特征及其与成矿的关系 总被引：3，自引：3，他引：0
从江县南加花岗岩类包括似斑状花岗岩及二长花岗斑岩。本文论述了它们的地球化学特征,并对其形成的构造环境及与成矿作用的关系进行了不的分析。（１）主状花岗岩类具Ｓ型花岗岩的特点,这可能形成于先封闭“弧后盆地碰撞带”;（２）二长花岗斑岩既具有Ｉ型花岗岩的某些特点,也有Ｓ型花岗岩的一些特点,可能属碰撞后形成的钙碱性岩石;（３）似斑状花岗岩类与钨锡矿化关系密切,二长花岗斑岩则可能与铜矿化有关系。 相似文献
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广东省新兴县都斛铜矿床处于吴川—四会深大断裂的中部边缘带,其铜成矿活动主要受本区燕山期斑岩体和NE向断裂构造双重控制,已发现的脉状铜矿体产状各异,在空间上整体形成一个不规则的环状,单个矿体呈细脉分布在黑云母二长花岗岩中,并具有浸染状矿化分布在花岗闪长斑岩等斑岩型矿床的矿化特征。通过对该矿床成矿地质特征的综合研究,对比粤西地区及国内类似斑岩型矿床的找矿经验,认为都斛铜矿床具有斑岩型矿床地质特征,处于斑岩矿床外围或顶部的脉状矿体带,具有寻找斑岩铜矿的潜力。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献