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1.
具有特殊成因机制的埃达克质岩石是探究深部岩浆动力学过程与区域构造演化的重要岩石探针之一。本文对北祁连造山带东段宁夏南华山地区出露的石洼里花岗岩进行了系统的锆石U-Pb年龄、主量-微量元素及锆石原位Hf同位素分析,以探讨其岩石成因及地球动力学意义。LA-ICP-MS锆石U-Pb定年结果表明石洼里花岗岩侵位年龄为452±4 Ma, 为晚奥陶世岩浆活动的产物。岩石具有较高的SiO2(68.60%~71.42%)、Al2O3(14.95%~15.75%)和Na2O(5.06%~5.79%)含量,较低的K2O(2.23%~3.10%)、MgO(0.91%~1.73%)含量和较高的Mg# 值(55~59),属弱过铝质钙碱性系列岩石; 岩石具有高Ba(1 025×10-6~1 250×10-6)、Sr(324×10-6~577×10-6)和低Y(6.99×10-6~7.69×10-6)、Yb(0.65×10-6~0.71×10-6)含量,较高的Sr/Y(45~79)和(La/Yb)N(17~31)值,且无明显Eu负异常。锆石εHf(t)值相对较高,变化范围为+0.5~+15.5。主量-微量元素及同位素分析结果表明石洼里花岗岩具有高镁埃达克岩的典型特征, 可能是在30~40 km深度的岛弧基性下地壳部分熔融的产物,其源区中可能存在早古生代的新生地壳。结合区内蛇绿岩、高压变质岩、弧岩浆岩的研究成果, 笔者认为受北祁连原特提斯洋北向俯冲影响,石洼里高镁埃达克岩形成于老虎山弧后盆地洋壳在晚奥陶世的南向俯冲过程中。 相似文献
2.
藏南冈底斯岩基东段朗县杂岩早白垩世岩浆作用:新特提斯洋二次俯冲 总被引：1，自引：1，他引：0
新特提斯洋长期俯冲消减作用在早白垩世可能经历二次俯冲启动或板片俯冲几何形态的重大转换。确定西藏南部冈底斯岩基早白垩世岩浆作用的岩石地球化学特征和作用方式是甄别上述过程的关键,对理解新特提斯洋的俯冲演化过程至关重要。本文就冈底斯岩基东段朗县杂岩中保存的各类早白垩世岩浆岩,开展了锆石U-Pb地质年代学和Hf同位素、全岩元素和同位素（Sr-Nd）组成分析。数据结果表明：1）基性岩侵位时代为早白垩世晚期（103.6~100.8Ma）,为高钾钙碱性偏铝质岩石,锆石εHf（t）=+0.3~+5.7,全岩εNd（t）=-0.8和-0.3,暗示其岩浆源区具有大量俯冲沉积物或流体的混入,为沉积物熔体和流体交代的地幔楔物质部分熔融的产物,经历了一定程度的角闪石分离结晶作用;2）中性岩形成于99.8~97.6Ma,略晚于基性岩,其主量元素与基性岩具有较好的线性关系,全岩εNd（t）=+1.1,具有较多的地幔物质参与,为基性岩浆进一步演化形成;3）酸性岩（脉体）记录了多阶段岩浆作用（124.1~95.3Ma）,根据同位素组成不同进一步划分为两类,第一类具有较低的全岩εNd（t）值（-8.3~-6.0）,其岩浆源区显示富集特征,tDM2=1385~1586Ma,由古老地壳物质的再熔融形成;第二类的锆石εHf（t）值（-2.8~+3.2）变化较大,岩脉的锆石εHf（t）=+0.4~+8.1,tDM=428~906Ma,全岩εNd（t）=+0.1和+0.8,表明岩浆源区具有不均一性,为古老地壳物质被富流体地幔岩浆改造形成;和4）镁铁质包体的主量元素与寄主花岗岩具有较好的线性关系,锆石的Hf同位素组成变化较大（εHf（t）=-9.3~+4.1）,变化范围可达13个ε单位,为岩浆混合成因。寄主花岗岩和角闪辉长岩分别作为酸性和基性端元,是基性岩浆与其诱发古老地壳熔融形成的花岗质岩浆经混合形成。结合冈底斯岩基早白垩世岩浆岩的研究结果,朗县杂岩在早白垩世（124~97Ma）的岩浆作用具有明显的岩浆混合现象,锆石Hf和全岩Sr-Nd同位素组成变化较大,可达13个ε单位,其岩浆源区复杂且富含流体,代表了新特提斯洋在早期（240~144Ma）经历漫长的俯冲之后,在早白垩世时期（~120Ma）俯冲带发生跃迁或俯冲角度达到临界点,导致大量俯冲沉积物和流体沿俯冲带俯冲下去,与发生部分熔融的地幔楔物质混合,底侵导致上覆古老地壳物质的再熔融,形成早白垩世复杂的岩浆岩组合,很可能是新特提斯洋二次俯冲开始的标志。 相似文献
3.
本文以华北陆块东部早白垩世滁州闪长玢岩和管店石英闪长岩为研究对象,报道了新的全岩地球化学（主量元素、微量元素以及Sr-Nd同位素）以及锆石U-Pb年代学和Hf同位素的综合研究结果,进而约束其岩石成因和构造意义。滁州闪长玢岩中锆石发育振荡环带,管店石英闪长岩中锆石具条痕状吸收的特点,它们均为岩浆成因。锆石LA-ICP-MS U-Pb定年结果显示,滁州和管店闪长质锆石年龄分别为128±1Ma和130±2Ma,表明二者均形成于早白垩世。地球化学特征显示,滁州和管店闪长质岩石具有类似的主量元素和微量元素组成,整体具中等的SiO2含量（58.55%~60.12%）和富MgO（4.43%~5.10%,Mg#=57~61）的特征,Na2O/K2O比值为1.20~1.47,属于高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素（如Rb、Ba）,亏损重稀土元素和高场强元素（如Nb、Ta、Zr、Hf）,并具不同程度的Eu负异常（δEu=0.85~0.93）。它们具高的Sr（575×10-6~1035×10-6）和低的Y含量（10.2×10-6~15.3×10-6）以及高的Sr/Y比值（57~69）,属于埃达克质岩石。此外,滁州和管店闪长质岩石具有类似的Sr-Nd以及锆石Hf同位素的特征,滁州闪长玢岩的87Sr/86Sr初始比值介于0.7061~0.7066之间,εNd（t）值为-17.7~-16.9,锆石εHf（t）值变化于-23.1~-19.1之间,而管店石英闪长岩的87Sr/86Sr初始比值为0.7046~0.7059,εNd（t）值为-18.7~-15.8,锆石εHf（t）值为-25.6~-20.0。综合上述,滁州和管店闪长质岩石均属于高镁埃达克质岩石,起源于拆沉的加厚下地壳部分熔融的熔体与地幔橄榄岩反应的产物,形成于早白垩世华北东部陆块拆沉作用下的伸展背景。 相似文献
4.
冈底斯岩基是新特提斯洋北向俯冲和印度-欧亚大陆碰撞的重要岩浆记录,尼木地区位于冈底斯岩基中部。本文报道了尼木地区寄主二长花岗岩和辉长质包体的锆石U-Pb年代学、元素地球化学和锆石Hf同位素。锆石U-Pb定年结果表明,寄主花岗岩（197~190Ma）和包体（195Ma）同期侵位,形成于早侏罗纪。寄主二长花岗岩为弱过铝质高钾钙碱性系列岩石,富集轻稀土和K、U、Sr等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,锆石εHf（t）值为+13.9~+16.0,其可能来源于初生地壳的部分熔融;辉长质包体为准铝质钙碱性系列岩石,具有与寄主岩相似的稀土和微量元素分配特征,锆石εHf（t）值为+13.8~+16.0,其可能代表了侏罗纪形成的新生下地壳,即寄主岩石的岩浆源区;结合前人研究,本文认为尼木地区的寄主花岗岩和暗色包体可能与新特提斯洋北向俯冲引起的地幔和初生地壳的部分熔融有关。 相似文献
5.
北山柳园地区中志留世埃达克质花岗岩类及其地质意义 总被引：7，自引：3，他引：4
北山柳园地区发育的埃达克质片麻状花岗闪长岩为钙碱性岩浆系列,具有较高SiO2 (>56%),Al2O3 (>15%)和较低的MgO (<3%)含量,Na2O>K2O; 并且具有高的Sr含量(>400×10-6)和Sr/Y比值; 样品轻重稀土强烈分异(La/Yb)N ＝18~86,强烈亏损重稀土Yb与Y,具有不明显的Eu异常(δEu＝0.90~0.95); 富集LREE和大离子亲石元素(LILE),而亏损HREE、高场强元素(HFSE: Nb、Ta),与世界上典型的俯冲洋壳熔融形成的埃达克岩相似。然而样品具有相对高的(87Sr/86Sr)I (0.70635~0.70636)和相对低的εNd(t) (-0.8~-0.9),以及锆石具有相对较低的εHf (t) (-0.8~+2.7)同位素特征,比典型的俯冲洋壳熔融形成埃达克岩具有更多的放射成因,推测可能是源区加入了地壳物质/沉积物/或特殊的洋壳(OIB/E-MORB)熔融,以及侵位过程中地壳物质的混染所造成的。埃达克质片麻状黑云母花岗岩锆石LA-ICPMS年龄为424±4Ma,代表了花岗岩埃达克花岗岩的结晶年龄。花牛山岛弧带在中晚志留世时期具有较高的地热梯度,发育了大面积高εNd(t)钙碱性花岗岩和区域围岩发生了高温变质作用。因此,柳园埃达克岩是由于热的洋壳向花牛山岛弧地体俯冲过程中熔融形成的,俯冲洋壳熔融是本地区早古生代大规模地壳增生的重要方式之一。 相似文献
6.
大别造山带研子岗碱性岩体成因及其构造意义：锆石U-Pb年龄和地球化学制约 总被引：5，自引：1，他引：4
出露于大别造山带西南部的研子岗碱性杂岩体侵位于元古代和新太古代随县群中,本文采用锆石LA-ICPMS U-Pb定年方法,获得岩体的主体岩性角闪正长岩的岩浆锆石年龄为133± 1Ma,代表岩体的结晶年龄,这一年龄也是大别造山带中已知形成时代最早的早白垩世碱性岩体的结晶年龄（单颗粒锆石U-Pb法）。研子岗碱性杂岩体具有碱性岩典型的富碱（K2O＋Na2O＝8.38%~11.26%）、低硅（SiO2＝63.41%~66.51%）的特点。主要矿物为微斜条纹长石,暗色矿物主要为镁角闪石。地球化学特征表明,全部岩石均具有高Ba-Sr花岗岩类高Ba（1230× 10-6~4865× 10-6）、高Sr（583× 10-6~2088× 10-6）和无负Eu异常（Eu/Eu*＝0.97~1.12）等特征,并具有A型花岗岩的部分地球化学特征。岩石的Y/Nb比（0.46~1.09）较低,具洋岛玄武岩的部分地球化学特征,(87Sr/86Sr) i初始比值（0.70513~0.70543）较低,表明岩体的物源主要来源于幔源。Nd二阶段模式年龄(t2DM=1859~1942Ma)和锆石Hf二阶段模式年龄(tDM2=2130~2330Ma）较老,εNd(133)值(-12.5~-11.4）和εHf(133)值(-18.2~-15.4）较低。综合分析表明,岩体主要为古老的富集岩石圈地幔物质低程度部分熔融和随后地壳物质轻度AFC（混染和分离结晶作用）过程的产物,源岩熔融的热量主要来源于软流圈物质的上涌底侵作用提供。研子岗岩体形成于碰撞后构造环境,岩体的形成预示着大别造山带早白垩世造山过程的即将结束,板内时期的即将来临。 相似文献
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在柴北缘东段识别出早古生代埃达克岩-富Nb玄武岩的火山岩组合。埃达克岩富Na2O、贫K2O，K2O/Na2O比值介于0.14~0.43之间；高Sr（614×10-6~1043×10-6），但亏损Y（3.26×10-6~14.1×10-6）和Yb（0.33×10-6~1.46×10-6），具有高的Sr/Y比值（44~282）；富集Sr、Ba等大离子亲石元素，亏损Nb、Ta、Ti等高场强元素及Cr、Ni、Co、V等相容元素。富Nb玄武岩富Na2O、贫K2O、高TiO2，其Nb含量较高，介于16.9×10-6~17.9×10-6之间，具有高的Nb/Ta、Nb/U、（Nb/La）N比值，同时富集高场强元素。埃达克岩锆石U-Pb定年得到453±4Ma和457±4Ma的结晶年龄。锆石εHf（t）范围较大，介于3.40~13.23之间，对应的二阶段模式年龄tDM2介于1059~566Ma之间，显示以新生物质为主的特征。综合研究表明柴北缘东段埃达克岩可能为岛弧环境下俯冲的南祁连大洋板片部分熔融的产物。板片来源的埃达克质熔体交代或与上覆地幔楔橄榄岩反应，导致被交代的地幔橄榄岩部分熔融而形成富Nb玄武质岩浆。柴北缘东段埃达克岩-富Nb玄武岩火山岩组合的厘定表明南祁连洋可能直到~455Ma之前并未完全闭合，同时表明俯冲大洋板片的部分熔融可能是柴北缘早古生代地壳增生的一种重要方式。 相似文献
8.
藏南冈底斯岩基晚白垩世早期岩浆岩保存了有关新特提斯洋的俯冲演化过程和大陆地壳生长的重要信息。本文对朗县杂岩中出露的晚白垩世早期中酸性岩（岩脉）开展了全岩元素地球化学、锆石U-Pb地质年代学、同位素（Sr、Nd和Hf）组成的研究。闪长岩和花岗闪长岩年龄为92.4~86.9Ma,花岗岩（脉）年龄为91.9~88.6Ma,均为晚白垩世早期岩浆作用的产物。闪长岩和花岗闪长岩具有高钾钙碱性偏铝质特征,具有较高的锆石Hf（εHf（t）=+8.3~+13.2,平均值+10.9）和全岩Nd（εNd（t）=+3.2~+2.7）同位素组成,为受俯冲板片流体和大洋沉积物熔体共同交代的地幔楔部分熔融形成,闪长岩岩浆源区形成深度较浅且受板片流体的交代程度较高,花岗闪长岩岩浆源区更深,受沉积物熔体交代程度较高。花岗岩（脉）在主量元素、稀土元素和微量元素组成上显示明显差异,可划分为两类,第一类花岗岩属于低钾钙碱性系列,Na2O/K2O>3.0,稀土总量较高,具有明显的Eu负异常,Sr/Y低（<7.2）。在主量元素组成上,该类花岗岩与闪长岩和花岗闪长岩形成较好的线性演化关系,表明它们可能是上述中酸性岩浆演化的产物。第二类花岗岩属于高钾钙碱性系列,Na2O/K2O较低（均<1.0）,铝饱和指数较高（A/CNK=1.01~1.02）,发育角闪石,稀土总量较低,具有微弱负或无Eu异常（Eu/Eu*=0.88~1.12）,Sr/Y比值（33.8~55.4）较高,锆石Hf（εHf（t）=+4.1~+10.8）和全岩Nd（εNd（t）=+0.8）同位素组成都较低,为新生下地壳部分熔融形成。结合冈底斯岩基晚白垩世早期（100~87Ma）岩浆岩已有的研究结果,认为新特提斯洋板片自早白垩世以高角度俯冲,在晚白垩世早期俯冲板片发生回撤,导致软流圈物质上涌增强,诱发熔流体交代过的地幔楔较高程度的部分熔融形成镁铁质岩浆。这些镁铁质岩浆上升侵位到下地壳,发生不同程度的分离结晶作用并诱发新生下地壳部分熔融,形成晚白垩世岩石地球化学性质各异的岩浆岩。 相似文献
9.
苏鲁超高压岩石部分熔融时间的准确限定：来自含黑云母花岗岩中锆石U-Pb定年、REE和Lu-Hf同位素的证据 总被引：13，自引：8，他引：5
在北苏鲁超高压变质带中,广泛分布强变形的新三叠纪含黑云母花岗岩和伟晶岩脉。锆石中矿物包体激光拉曼测试、阴极发光图像分析、不同性质锆石微区LA-(MC)-ICP-MS和SHRIMP U-Pb定年、REE及Lu-Hf同位素测试等综合研究结果表明,北苏鲁威海地区超高压正片麻岩在构造折返的 (高压)麻粒岩相升温减压阶段,发生部分熔融 (深熔)作用形成了花岗质岩浆,并在临近角闪岩相退变质作用之前结晶结束形成了含黑云母的花岗岩。该类含黑云母花岗岩中的锆石成因复杂,可划分为三类锆石微区。第一类为强发光效应 (白色)继承性岩浆锆石 (微区I),具有典型的岩浆结晶环带,矿物包体为Qtz+Kfs+Ap,记录的206Pb/238U年龄为790~782Ma;第二类为新生锆石微区 (微区II),发光强度相对较弱 (灰色-灰白色),也具有较明显的岩浆结晶环带,矿物包体为Qtz+Kfs+Ab+Ap,记录的206Pb/238U年龄为222~217Ma,加权平均年龄为219±2Ma,表明苏鲁超高压地体的部分熔融 (深熔)作用发生在新三叠纪,这组年龄比苏鲁地体超高压变质时代 (235~225Ma)明显偏新,指示部分熔融 (深熔)作用的时代要晚于苏鲁地体的超高压变质时代;第三类锆石微区 (微区III)围绕第二类锆石微区分布,发光强度最弱 (黑色),也具有典型的岩浆结晶环带,矿物包体十分少见,为Qtz+Ap,记录的206Pb/238U年龄集中于216~209Ma之间,加权平均年龄为214±2Ma,应代表部分熔融 (深熔)而成的岩浆结晶结束的年龄,这组年龄比苏鲁地体构造折返晚期角闪岩相退变质时代(210~200Ma)偏老,表明新生岩浆结晶结束的时间要早于角闪岩相退变质时代。继承性岩浆结晶锆石 (微区I) 176Hf/177Hf(t)=0.281975~0.281984,176Hf/177Hf=0.00196~0.00221,εHf(t)=-11.6~-11.8,相应的tDM2=2160~2170Ma,与研究区周围新元古代 (795~730Ma)正片麻岩继承性岩浆结晶锆石的Lu-Hf同位素特征十分相似,表明新元古代正片麻岩是新三叠纪部分熔融 (深熔)成因的含黑云母花岗岩的母岩。新三叠纪新生岩浆结晶锆石的核部 (微区II)和边部 (微区III)具有类似的176Hf/177Hf(t)、176Hf/177Hf比值和εHf(t)值,176Hf/177Hf(t)=0.282110~0.282199,176Hf/177Hf=0.00041~0.00183,εHf(t)=-15.8~-19.1,tDM2=1980~2130Ma,表明新三叠纪由超高压正片麻岩部分熔融而成的岩浆自结晶开始到结束是在一个相对封闭体系条件下完成的。晚期角闪岩相退变质作用对其Lu-Hf同位素体系也未造成破坏。 相似文献
10.
新疆准噶尔北东缘乌图布拉克岩体形成时代、地球化学特征及地质意义 总被引：9，自引：5，他引：4
乌图布拉克岩体位于准噶尔北东缘,额尔齐斯-玛因鄂博构造带南侧。岩体主要由花岗闪长岩和二长花岗岩组成,有少量石英闪长岩和钾长花岗岩。岩体的锆石SHRIMP U-Pb年龄为360.1±3.6Ma。岩石的K2O+Na2O=7.05%~9.48%,A/NKC=0.91~1.04,属准铝-过铝质“I”型花岗岩。岩石稀土总量低,∑REE为72×10-6~184×10-6,轻稀土富集,(La/Yb)N=5~13。石英闪长岩、花岗闪长岩、二长花岗岩具弱的铕负异常或无明显异常（δEu=0.72~0.98）;钾长花岗岩铕负异常明显（δEu=0.15~0.21）。在微量元素配分模式中,具有Sr、Ba、P、Ti的亏损,而Nb、Ta亏损不明显。岩石有低的Sr初始值（0.70165~0.70462）和高的εNd(t)u（+4.7~+6.9）。2个样品的Nd模式年龄分别为758Ma和551Ma。上述特征表明,岩浆可能具有较复杂的来源,推测该岩体岩浆可能来源于年轻的玄武质地壳,并有幔源物质的加入。综合本文资料及区域地质特征分析,阿尔泰造山带后碰撞时限可能为360~290Ma,即泥盆纪末-石炭纪末。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
15.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
16.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
17.
18.
19.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
20.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which
are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite
and quartz veins.
The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock,
alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite,
volcanic tuff, phosphatic rock and chert breccia.
The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow
level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly
alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic
than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits
with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other
as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate
and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction
with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon. 相似文献