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1.
一九四九年详查铜陵铜官山鸡冠山区域时,在狮子山铜矿之氧化带内见有橄榄绿色之矿物生於石英脉之晶硐及裂缝内,该脉系穿插於三叠纪石灰岩及闪长岩侵入体之富含柘榴在接触带中,近处有白钨矿及黄铜矿,经室内吹管分析及显微化学试验,知其兼含铜钨,又作简单物理性检定,发浅蓝色萤光,後经陈四箴先生之定量分析,证明其为钨铜钙矿,在中国系初次发现,其成分与智利等处所产相彷,此系次生矿物,大致原生铜矿物受地表氧化时,含铜溶液与白钨矿相遇即可生成。 相似文献
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一九四九年详查铜陵铜官山鸡冠山区域时,在狮子山铜矿之氧化带内见有橄榄绿色之矿物生於石英脉之晶硐及裂缝内,该脉系穿插於三叠纪石灰岩及闪长岩侵入体之富含柘榴在接触带中,近处有白钨矿及黄铜矿,经室内吹管分析及显微化学试验,知其兼含铜钨,又作简单物理性检定,发浅蓝色萤光,後经陈四箴先生之定量分析,证明其为钨铜钙矿,在中国系初次发现,其成分与智利等处所产相彷,此系次生矿物,大致原生铜矿物受地表氧化时,含铜溶液与白钨矿相遇即可生成。 相似文献
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含铜钨酸钙矿物系一稀少而较少之矿物,系一九四九年秋作者往铜陵鸡冠山区调查铜矿时首先发见者。该矿物色呈橄榄绿,硬度四与五之间,玻璃质光泽甚强。比重四·八至五,体为半透明,折光率一·八以上,为一正方系中正光性符号之单轴晶体矿物。该矿物生於石英脉之晶硐内,孔隙中或裂缝里,呈大小不一之不规则粒状或块状矿物;但含此矿物之石英脉则穿插于含铜Skarn之节理成裂缝内。共生矿物按其发生次第有石英,白钨矿,矽孔雀石,孔雀石,含铜钨酸钙,褐铁矿及高岭土等。该含铜钨酸钙石英脉位铜矿氧化带之Skarn范围内,且常与白钨矿共生。关系密切,为一次生作用造成之矿物。 相似文献
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朱溪矿床是江南钨矿带中产于燕山期中酸性侵入岩与晚古生代碳酸盐岩接触带附近以矽卡岩矿体为主的钨铜矿床,发育“上铜下钨”的空间分带。浅部发育矽卡岩型和脉型铜矿体,深部发育矽卡岩型钨铜矿体、云英细脉-网脉型钨矿体及蚀变花岗岩型钨矿体。浅部矽卡岩型铜矿体中石榴子石U-Pb年龄为152.6±2.6 Ma、深部云英脉型钨矿体中白钨矿U-Pb年龄为153.4±2.2 Ma、深部矽卡岩型钨铜矿体中白钨矿U-Pb年龄为153.9±2.7 Ma,三者时代在误差范围内一致,表明钨、铜矿化均形成于同一热液体系,结合云英脉型钨矿体和矽卡岩型钨铜矿体中两类白钨矿的微量元素特征分析,流体起源于富WO42-、低Sr的高分异岩浆热液,白钨矿是以Ca2+空位的方式置换REE3+,稀土元素的分配行为记录了不同类型矿化流体性质。云英脉型钨矿化形成于还原环境,且氧逸度的显著降低以及围岩提供大量Ca2+促进了白钨矿的沉淀,而矽卡岩型钨铜矿化为相对开放的热液体系,后期经历了氧逸度升高,增强了流体富集金属Cu的能力,从而萃取... 相似文献
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钨和铜有明显不同的地球化学性质,但钨、铜在矿床中可以共伴生,原因还不清楚。长江中下游成矿带发育典型的斑岩-矽卡岩-层状铜（钨）多金属成矿系统,其中层状铜（钨）矿体成矿时代数据相对较少。作者以该带九瑞矿集区武山铜矿区新发现的钨矿（化）体为研究对象,开展了矿相学、白钨矿原位U-Pb年代学和元素地球化学的研究。研究发现,武山矿床具有层状、矽卡岩型、斑岩型3类铜矿体均有白钨矿矿化,矿床整体由浅至深存在Cu→Cu-W的分带规律。3类矿石中的白钨矿产状类似,充填在粗粒黄铁矿晶体间隙,或呈浸染状分布,被黄铜矿、闪锌矿等交代,产于退化蚀变阶段;其中斑岩中还存在少量晚世代白钨矿,与石英、黄铁矿共生,形成细脉并穿切花岗闪长斑岩,为石英-硫化物阶段产物。通过对退化蚀变阶段白钨矿进行测年和地球化学研究,作者获得了层状矿体含钨黄铜矿矿石中的白钨矿原位LA-ICP-MS U-Pb同位素年龄为（140.6±1.5）Ma,代表层状铜钨矿体成矿时代,在误差范围内与前人获得的斑岩、矽卡岩型矿体的成矿时代基本一致。层状矿体中白钨矿的稀土元素特征和Sr/Mo值符合岩浆热液矿床特征,相比矽卡岩型、花岗岩型白钨矿,层状矿体中白钨矿具有明显较低Mo含量,反映了形成于相对低氧逸度条件;另外,层状矿体中白钨矿具有正Eu异常和与围岩相近的高Y/Ho值的特征,推测其是流体充分交代了含碳围岩地层导致流体性质的明显改变,并且有利于白钨矿和黄铁矿的沉淀,可从深部黄龙组层间部位形成钨品位更富的黄铁矿矿石得到佐证。文章从白钨矿角度证实层状矿体是斑岩-矽卡岩成矿系统的重要组成部分,提出在九瑞矿集区已知铜矿床的深部,尤其是燕山期中酸性侵入岩与含碳质碳酸盐岩的接触带及黄龙组层位,是寻找富钨矿体的新找矿方向。白钨矿的U-Pb同位素定年为长江中下游成矿带层状矿体的成矿时代提供了新的可靠依据。 相似文献
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李创举 《大地构造与成矿学》2017,41(4):698-709
英德白水寨钨矿床位于粤北钨多金属成矿带雪山嶂矿田内,是近年来新发现的石英脉型钨矿床,初步探明储量已达中型规模。矿区浅部发育白钨矿线脉-细网脉密集带,往深部演化成黑钨矿细脉带,并在钙质地层发育地段形成了白钨矿体。与典型的石英脉型钨矿相比,该矿床具有浅部线细网-细脉带钨矿物"上白钨矿下黑钨矿"、发育细网脉与矽卡岩共存的白钨矿(化)体、矿石矿物组合中出现大量黄铁矿的特征,但总体属于石英脉型钨矿床,深部含矿岩浆热液是成矿的重要条件。详细的野外勘探资料显示,该矿床已具有"五层楼"成矿规律的雏形,物探成果指示深部岩体埋深0.5~1.2 km,而地表-浅部矿化带处于"五层楼"模式的细网脉标志带-细脉带的空间位置,矿区深部勘查脉带型钨矿有很大空间。 相似文献
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我国西南“三江”地区的金沙江成矿带,以富产铜铅锌资源著称,迄今尚未有钨矿体的发现。近期,该成矿带内的羊拉大型铜矿床深部新发现了钨矿体,为金沙江铜多金属成矿带内的首次报道。新发现的钨矿体宽2～10m,呈不规则脉状及团块状产出于泥盆系里农组二段大理岩内,其中钨矿石已达到工业品位,可作为伴生资源开采利用。初步研究表明,白钨矿原位U-Pb年龄为(30.6±1.7) Ma、(30.3±2.4) Ma,反映其形成于渐新世,明显晚于铜矿体的成矿年龄,花岗闪长岩可能为钨矿提供了成矿物质。钨矿体的发现,表明羊拉矿床可能经历了多期成矿作用的叠加复合。 相似文献
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中条山地区八一铜矿床中白钨矿的发现及其找矿意义 总被引：2，自引：1，他引：1
中条山地区是我国重要铜矿基地之一,虽然区域资料中有钨的化探异常,但以往没有发现有价值的钨矿。文章在八一铜矿研究过程中,通过X射线荧光光谱野外快速分析仪检测、荧光灯检查、光薄片鉴定和电子探针分析,查定出含铜矿脉中赋存白钨矿矿物,其共伴生矿物主要是黄铜矿、闪锌矿和方铅矿,脉石矿物以方解石、白云石和石英为主。通过对白钨矿矿物、金属硫化物、主要脉石矿物的电子探针分析,结合碳同位素组成,初步判断八一铜矿为岩浆热液成因。八一铜矿脉中白钨矿的发现,不但对深入研究我国钨矿的区域成矿规律具有重要意义,也有助于丰富中条山地区的矿床学研究内容,拓展找矿思路。 相似文献
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内蒙古红花尔基钨多金属矿床成岩成矿年代学研究 总被引：6，自引：3，他引：3
红花尔基钨多金属矿床是近年在大兴安岭中北部新发现的一处储量达大型规模的钨多金属矿床,矿体受含矿花岗岩体控制,总体呈平缓似层状赋存于花岗岩体内的顶部接触带。含矿花岗岩为不等粒结构,岩体无显著变形变质特征,保存基本完好。岩体含矿部位均遭受强烈的绢云母化、云英岩化、硅化等蚀变,与成矿有关的蚀变主要为绢云母化。矿床主要有用金属矿物为白钨矿和辉钼矿,岩体内辉钼矿与白钨矿大体具上钼下钨的分带特点,其钨矿体呈细脉状或稀疏大脉状分布于灰白色蚀变花岗岩内,多伴随硅化石英脉。辉钼矿呈细脉状、薄膜状或团块状产于花岗岩内,地层中局部可见与黄铁矿、黄铜矿、白钨矿共生,显示该矿床为一高温热液脉型钨多金属矿床。笔者对矿区2件含矿花岗岩样品——黑云母花岗岩HHW-1、HHW-12进行了LA-ICP-MS锆石U-Pb测年,2件样品的年龄结果具有一致性,谐和年龄为（179.4±2.3）Ma~（179.2±1.8）Ma;同时,对矿区7件辉钼矿样品进行了铼-锇同位素分析,获得同位素等时线年龄为（176.8±2.2）Ma（MSWD=0.29）,岩体的形成年龄稍早于成矿年龄,在测试误差范围内具有一致性。结合野外地质特征及岩相学研究,我们认为黑云母花岗岩体与成矿密切相关,矿床成岩及成矿时代均为早-中侏罗世,属燕山期构造-岩浆活动的产物。 相似文献
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新疆阿尼亚拉克钨铜矿区位于柴达木微板块之祁漫塔格古生代复合沟弧带,该带为W-Sn-Pb-Zn-Fe-Cu-多金属矿带。矿床的赋矿地层为蓟县系狼牙山组和青白口系丘吉东沟组碎屑岩-碳酸盐岩建造,含矿岩性一为条带状绿帘石-透辉石矽卡岩及矽卡岩化大理岩;另一种为条带状云英岩化变石英砂岩和变粉砂岩。矿体主要受地层和侵入体接触带的控制,形态多呈层状、透镜状和脉状。围岩蚀变主要有矽卡岩化（包括石榴子石化、透辉石化、透闪石化、阳起石化、符山石化、硅灰石化、绿帘石化）、云英岩化、硅化、黄铁矿化等。阿尼亚拉克钨铜矿是以蓟县系狼牙山组和青白口系丘吉东沟组为赋矿岩系,以印支晚期二长花岗岩为热动力源,且受岩体与灰岩接触带和近EW向层间构造破碎带控制的岩浆中-高温热液交代充填矽卡岩-云英岩型钨铜矿床。阿尼亚拉克钨铜矿床的发现对祁漫塔格地区钨锡、铅锌、铁、金铜成矿远景区的地质找矿具有重要意义。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献