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1.
华北地台金伯利岩岩浆活动时代讨论   总被引:13,自引:0,他引:13  
路凤香  赵磊 《岩石学报》1995,11(4):365-374
华北地台金伯利岩岩浆活动可分为三个时期:(1)中元古代金伯利岩和钾镁煌斑岩岩浆活动期,以鄂尔多斯陆核边缘山西阳高岩区为代表(1649~1811Ma);(2)古生代金伯利岩岩浆活动,以冀鲁辽陆核边缘的铁岭岩区、中部的复县和蒙阴岩区为代表(含矿金伯利岩,457~462Ma);(3)中~新生代金伯利岩岩浆活动时期,以鹤壁和涉县岩区为代表(117~52Ma)。含矿金伯利岩岩浆活动与华北地台中奥陶世晚期的造陆抬升作用有关。这类岩浆形成时必须处于克拉通岩石圈底部有小的热扰动以及流体作用的条件,而过高的地温梯度反而起到破坏金刚石保存的作用。  相似文献   

2.
鄂尔多斯古陆具有稳定的结晶基底和沉积盖层,也存在有利于金伯利岩形成的深切地幔的深大断裂构造。在山西柳林尖家沟地区发现众多金伯利岩,在山西应县和大同地区发现金伯利岩、钾镁煌斑岩及似金伯利岩等与金刚石形成有关的岩体,在这些地区也发现少量微粒金刚石和大量指示矿物;圈出内蒙古新庙、陕西店塔2个铬尖晶石指示矿物异常区。陕西店塔地区还发现与金伯利岩岩浆活动有关的环状构造。鄂尔多斯古陆区具备原生金刚石形成条件,具有良好的找矿潜力。  相似文献   

3.
鲁西蒙阴地区是我国金刚石原生矿重要产地之一,其含金刚石金伯利岩命名为常马庄单元。本文对该区金伯利岩地质特征进行了梳理,按岩石命名原则对该地区含金刚石金伯利岩不同岩石类型进行了重新划分和命名,共划分了细斑微粒金伯利玢岩类、粗斑细微粒金伯利玢岩类和含碎屑细斑或中细斑微粒金伯利玢岩类3个岩石类型和13个亚类型,同时首次从早至晚划分了细斑微粒金伯利玢岩类→含围岩角砾中细斑微粒金伯利玢岩类→粗斑细微粒金伯利玢岩类的侵入序列。通过对前人研究资料的综合分析并结合野外实地考察认为:以前套用南非金伯利岩型金刚石原生矿中心式火山喷发型成矿模式作为蒙阴地区含金刚石金伯利岩的成矿模式不符合该区实际地质特征。提出了该区金刚石金伯利岩新的成矿模式为中心式—裂隙式复合潜火山隐爆岩浆序次侵入充填型岩浆侵入角砾岩筒及其伴生的岩脉、岩床模型。  相似文献   

4.
我国金伯利岩型金刚石矿床的若干地质特征及其找矿标志   总被引:9,自引:0,他引:9  
董振信 《矿床地质》1991,10(3):255-264
金伯利岩型金刚石矿床是世界上重要的金刚石矿床类型:也是我国迄今所发现的唯一的金刚石原生矿床类型。本文阐述了我国金伯利岩分布的构造部位、时代、产状、与暗色岩类的关系、围岩及其蚀变特征、岩管的岩相特征、岩石类型及岩石化学特征,并指出了该类矿床的找矿标志。  相似文献   

5.
西村岩管是在苏北地区发现的第一个金伯利岩管,颠覆了苏北地区无金伯利岩的历史。从岩石学、地球化学和伴生矿物等方面分析了西村岩管的地质特征,并进一步探讨其金刚石找矿意义。从区域背景和金刚石形成条件看,西村地区具备了金伯利岩侵位和金刚石矿形成的基本地质条件,而西村岩管为金刚石矿就位提供了母岩条件;西村金伯利岩与山东、辽宁金伯利岩具有相似的地球化学特征,是幔源岩浆低程度部分熔融的产物,且在岩浆上升过程中普遍遭受了壳源物质的混染,后期碳酸盐化现象普遍发育;其相容元素含量与山东金伯利角砾岩相似,均为典型的金伯利岩型配分模式,稀土元素表现为轻、重稀土元素强烈分馏的特征;伴生指示矿物主要为榴辉岩型含铬镁铝榴石、富铬透辉石和富镁铬尖晶石,其特征均表现出含矿金伯利岩的特点。  相似文献   

6.
苏北第二轮金刚石找矿历时8 a,尚未发现含矿的金伯利岩或金刚石矿床。从苏北找矿实际出发,结合最新的金刚石成矿理论和进展,提出和探讨了制约苏北原生金刚石找矿的几个问题,进一步探讨了找矿方向。研究认为: 苏北原生金刚石找矿的首要目标为古生代金伯利岩,在郯庐断裂带西侧,由于徐宿弧形构造的存在,可能使得该期金伯利岩被掩盖于推覆体之下; 郯庐断裂带与古生代金伯利岩没有成因联系,但其在伸展阶段控制发育的断陷红盆,可能使得带内的古生代金伯利岩被掩盖在白垩系之下。今后的找矿方向应重点集中在郯庐断裂带内的城岗隆起上,郯庐断裂带西侧的含角砾基性岩亦是值得关注的对象。在开展找矿勘查时,应充分考虑工作区地质与地形条件、方法适应性和局限性等因素,因地制宜选择勘查方法组合。  相似文献   

7.
王思琪  郑建平  韩双  王俊烈 《地质学报》2020,94(9):2676-2686
辽南金伯利岩岩区是我国最大的原生金刚石矿产区,该区金刚石主要寄主岩石类型为斑状金伯利岩。橄榄石是金伯利岩中最重要的造岩矿物,根据其结构特征可以分为橄榄石粗晶、橄榄石斑晶以及基质中微细粒三个世代。本文将岩相学特征和前人研究成果相结合,构建辽南斑状金伯利岩岩浆起源、上升、喷发和成岩模型,探讨各世代矿物的形成过程。具体包括:深部交代地幔部分熔融,形成初始碳酸盐岩浆;初始岩浆上升过程中捕获的岩石圈地幔橄榄岩不断溶解(形成橄榄石粗晶),岩浆成分发生改变,成为金伯利岩岩浆;金伯利岩岩浆迅速上升侵位,至地表处爆破喷发,最后冷却固结形成包含粗晶及其他两个世代橄榄石的斑状金伯利岩。  相似文献   

8.
辽宁瓦房店地区是我国著名的金刚石矿产地之一,前人在该区做过大量的研究工作,但找矿方法一直没有突破。本文采用音频大地电磁测深法(AMT)对已知的金伯利岩矿区进行试验,探讨AMT技术在金伯利岩矿区深部探测的应用效果。针对30号金伯利岩岩管区布设了5条剖面,结果显示岩管呈低阻反映,异常明显。结合地质资料,初步推断该区断裂、成矿带和低阻异常展布特征,为在该区进一步开展矿产勘查提供基础资料,对今后瓦房店地区寻找隐伏的金伯利岩体具有重要意义,也为其他类似地区寻找隐伏金伯利岩提供新思路。  相似文献   

9.
倪培  朱仁智 《地质学报》2020,94(9):2557-2573
金伯利岩型金刚石原生矿床含矿性评价是了解金刚石成矿规律和指导区域性找矿的重要依据。华北克拉通是我国重要的金刚石成矿远景区,目前已发现了两个重要的含金刚石金伯利岩岩区(山东蒙阴和辽宁瓦房店)。近年来,对岩区内不同品位金刚石典型矿床的研究表明金伯利岩中的金刚石品位取决于以下两个重要的地质过程:金伯利岩岩浆对金刚石的捕获作用和金伯利岩岩浆对金刚石的熔蚀作用。在华北克拉通下方存在一个金刚石稳定区,温度为950~1200 ℃,压力为4. 4~6. 1 GPa。山东蒙阴和辽宁瓦房店金伯利岩岩浆在上升过程中穿过该区域并捕获其中的金刚石,成为含矿岩浆;而铁岭和鹤县等金伯利岩岩浆在上升过程中不穿过该区域,成为不含矿岩浆。在穿过金刚石稳定区时,富矿的金伯利岩捕获了更多的金刚石以及金刚石的伴生指示矿物(如镁铝榴石,镁铬铁矿);而贫矿的金伯利岩则相对捕获了少量的金刚石和指示矿物。这些指示矿物往往参加了金刚石的形成过程,有些作为缓冲剂控制了反应(岩浆或熔体)的氧化还原状态,有些则作为反应物或者生成物参与到反应中。部分指示矿物(如镁铝榴石)还进一步地记录了金刚石形成后金伯利岩岩浆对金刚石的交代作用。金伯利岩岩浆温度(T),氧逸度(fO2)和挥发份(H2O和CO2)均会对金刚石的熔蚀作用产生影响,其中氧逸度作用最大,温度次之,而挥发份作用最弱。在华北克拉通,金伯利岩中指示矿物(镁铝榴石、镁铬铁矿)和金伯利岩岩浆特征(温度,氧逸度和挥发份)共同组成了金伯利岩型金刚石原生矿的评价指标。  相似文献   

10.
辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区,现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个,累计提交1221万克拉储量,占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析,发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系;Ni、Cr、Co含量与金刚石含量呈正相关,而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa,温度1083~1261℃,在上述温、压条件下,结合岩浆化学组成,估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作,总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素,认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布,严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆,在一定的封闭条件下,受构造与岩性双重控制,多期性的爆发与侵入交替作用所形成,并建立了具有较高氧逸度和较高密度的流变性软流圈,通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式,希望为下一步找矿工作提供参考。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

19.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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