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1.
研究结果表明,富水中基性侵入杂岩可能为不同时代亏损地幔源岩浆侵入活动的产物。其中中细粒角闪辉长岩、具斑杂构造的中细粒角闪黑云辉长岩、中粗粒角闪黑云二长岩为同一岩浆源岩浆演化序列,角闪黑云二长岩中锆石U-Pb同位素年龄值(514.3±1.3)Ma代表了其形成时代,反映了早古生代的一次重要“造壳事件”。角闪黑云闪长岩的Sm、Nd同位素地球化学特征明显不同于前3种岩石,反映了富水中基性侵入杂岩形成演化的复杂性。  相似文献   

2.
研究结果表明,富水中基性侵入杂岩可能为不同时代亏损地幔源岩浆侵入活动的产物。其中中细粒角闪辉长岩、具斑杂构造的中细粒角闪黑云辉长岩、中粗粒角闪黑云二长岩为同一岩浆源岩浆演化序列,角闪黑云二长岩中锆石U-Pb同位素年龄值(514.3±1.3)Ma代表了其形成时代,反映了早古生代的一次重要“造壳事件”。角闪黑云闪长岩的Sm、Nd同位素地球化学特征明显不同于前3种岩石,反映了富水中基性侵入杂岩形成演化的复杂性。  相似文献   

3.
刘函  王国灿 《地质通报》2012,31(9):1461-1468
北阿尔金拉配泉北侧米兰群混合角闪斜长片麻岩被2期基性岩墙群(辉绿玢岩和棕闪煌斑岩)侵位。本次分别对三者进行了LA-ICP-MS锆石U-Pb同位素侧年。混合岩化角闪斜长片麻岩中锆石结晶年龄为2007Ma±25Ma,结合西北地区2.0Ga左右广泛的构造-热事件,可能与Columbia超大陆汇聚有关。辉绿玢岩和棕闪煌斑岩的年龄结构相似,锆石较老年龄组分分别为1962~2093Ma和1804~2038Ma,系在侵位时从围岩(混合角闪斜长片麻岩)中捕获的锆石的年龄;最年轻的年龄组分(79~94Ma)代表基性岩墙群的侵位时间,与阿尔金北缘断裂伸展活动有关;古生代年龄(288~504Ma)为岩墙群上侵过程中同化混染北阿尔金蛇绿混杂岩带部分岩石的年龄。  相似文献   

4.
石人嶂钨矿区发育的角闪辉长岩与钨矿密切共生,研究该矿区对认识粤北地区区域地质演化、深部岩浆信息以及区域基性岩与成钨作用关系研究意义重大,但到目前为止,尚未开展相关系统的研究。文章报道了角闪辉长岩的锆石和磷灰石U-Pb年代学、地球化学资料。磷灰石U-Pb年龄指示角闪辉长岩的结晶年龄为(171±14) Ma,形成于燕山早期晚阶段古太平洋板块俯冲背景下的岩石圈伸展的构造环境,其中,锆石为捕获锆石,具有3组年龄,分别记录了区域古元古代陆核增生,新元古代古华南板块的聚合和裂解,早中生代华南板块与华北板块,印支地块聚合的后造山伸展等多起构造事件。角闪辉长岩具有低Si、K、Mn,高Ca、Fe、Mg、Na、Ti的特征,富集Rb、Ta、Zr、Ti等,亏损Ba、Nb、Sr、Hf、Be、Cs、U、Th等元素,表明其源区具有E-MORB型富集地幔的属性。角闪辉长岩的形成主要受控于软流圈地幔的部分熔融。同时,由于角闪辉长岩的高氧逸度的特征及其较石人嶂钨矿成矿更早,角闪辉长岩的存在可能主要是为后期的钨矿化的叠加提供部分Ca、Fe等元素,并为富矿流体的运移提供通道。  相似文献   

5.
伸展系统中的基性、超基性岩与铜镍硫化物矿床密切相关。本文研究了塔里木板块东北边缘(可追溯到中元古代)的基性、超基性岩的岩石学、地球化学特征及其形成构造环境,认为该区的基性、超基性杂岩可分为两类:一类形成于裂谷作用早期(中元古代),另一类形成于裂谷作用鼎盛时期或弧后盆地阶段(早古生代)。后者可归入蛇绿杂岩中;前者与镍铜成矿系统密切相关,但很难完全归入已有的基性、超基性岩分类之中,属于一种新类型,建议将其命名为大陆边缘裂谷型基性超基性岩。研究区大陆边缘裂谷型基性超基性岩Sm-Nd模式年龄为1026~1749Ma,其深成岩(黑山岩体)岩石组合为:石英正长岩-辉长岩-角闪辉长岩-含云母斜长角闪辉橄岩-含云母角闪辉橄岩-含云母斜长角闪橄榄岩-辉石岩,超基性岩m/f平均值为5.5,∑REE为20.9×10-6~64.71×10-6,平均29.91,LREE略富集,辉长岩TiO2为0.92%;浅成岩(黑山北岩体)岩石组合为:灰黑色细粒角闪辉长(玢)岩-暗绿黑色细粒绿泥石化辉长苏长岩-深黑色中粒橄榄二辉岩,TiO2强烈富集,其中辉长(玢)岩TiO2为1.32%~3.32%,MgO、CaO亏损,Rb、Sr、Y、Zr、Nb、Ba、Cs、Hf、Ta、Th、U强烈富集,Sc、V、Cu较富集,Cr、Co、Zn亏损,LREE略富集。表明中元古代塔里木板块东北边缘已经出现活动大陆边缘后方伸展体制,在  相似文献   

6.
东昆仑中段的白日其利基性岩体由橄榄辉长岩、斜长岩和角闪辉长岩组成.主体岩相角闪辉长岩的锆石LA-ICP-MSU-Pb年龄表明,其侵位于248.9Ma+4.2Ma,为早三叠世阿尼玛卿古特提斯洋关闭过程中的岩浆活动.结合前人的研究,认为东昆仑造山带中生代岩浆混合作用至少始于早三叠世,白日其利岩体为研究俯冲阶段岩浆混合作用提...  相似文献   

7.
阿尔泰南缘杰尔库都克酸性岩脉LA-ICP-MS锆石U-Pb测年   总被引:2,自引:0,他引:2  
野外地质调查发现在阿尔泰造山带南缘杰尔库都克地区,额尔齐斯断裂以南发育一套酸性岩脉。岩脉主要侵位于石炭系火山-沉积地层中,岩石主要为流纹斑岩。LA-ICP-MS锆石U-Pb测年结果显示,酸性岩脉形成于(279±3)Ma的早二叠世。岩脉是岩石圈(地壳)伸展的重要标志,该年龄的获得为阿尔泰造山带南缘早二叠世岩石圈伸展提供了重要证据。  相似文献   

8.
姜洪颖  贺振宇 《地球科学》2022,47(9):3270-3284
北山造山带位于中亚造山带南部,是中亚造山带的重要组成部分.为了进一步深入认识北山造山带晚古生代的构造?岩浆演化过程,选择北山造山带南部石板墩?白墩子地区的晚古生代花岗岩?闪长岩开展了岩石学、锆石U-Pb定年、Hf同位素、微量元素及岩石地球化学研究.LA-ICP-MS锆石U-Pb年代学研究限定了石板墩花岗岩形成于~304~ 302 Ma,石板墩闪长岩形成于~291 Ma,白墩子石英闪长岩形成于~270 Ma.它们的锆石Hf同位素均呈现较亏损的特征(εHf(t)=-2.0~+15.7),且由老到新,亏损程度依次增加.岩石学和地球化学特征暗示了亏损地幔来源岩浆在北山造山带晚古生代岩浆活动中的主导作用,亏损地幔来源岩浆与古老地壳部分熔融形成的岩浆以不同比例混合,形成了复杂的岩石组合.因此,晚石炭世?早二叠世花岗岩?闪长岩可能形成于后撤式增生造山作用导致的弧后伸展构造环境.   相似文献   

9.
王烨  李碧乐  吴琼  王国志 《世界地质》2017,36(2):441-451
对孤山子基性-超基性岩体的岩相学、锆石U-Pb年代学和全岩地球化学等方面研究,确定了该岩体的形成时代、岩石成因及其形成的构造环境。该杂岩体主要由辉石岩和角闪辉石岩组成,元素地球化学上,贫SiO_2(34.28%~49.22%)、K_2ONa_2O、富MgO(4.54%~13.26%)特征,属碱性系列岩石。岩石稀土元素球粒陨石标准化配分模式为轻稀土富集型,(La/Yb)_N=8.14~36.19,Eu异常不明显,稀土元素原始地幔标准化分布模式相似,为上地幔富集地幔熔融。岩石富集大离子亲石元素(如Rb、Ba、K)和LREE(如La和Ce),明显亏损高场强元素(Nb、Ta、Ti)和HREE。样品Nb/U、Ce/Pb和La/Sm比值显示岩体经历了有限的地壳混染。锆石的LA-ICP-MS U-Pb年代学研究表明,岩石锆石U-Pb年龄分为3类:一类锆石U-Pb年龄为(1 392±10)Ma,应为孤山子超基性侵入体侵位过程中捕获的碎屑锆石;第二类锆石U-Pb年龄为(274.5±2.1)Ma,为岩浆侵位时形成的锆石;第三类锆石U-Pb年龄为(53.02±1.1)Ma,为热液锆石。研究认为,岩体的岩浆源区主要为亏损地幔,可能受晚古生代古亚洲洋俯冲洋壳的脱出流体迭加作用和地壳物质的混染。结合区域构造演化,认为岩体形成于古亚洲洋闭合后挤压向伸展转换的构造背景。  相似文献   

10.
牛鼻子梁岩体位于柴达木地块的北缘,出露面积约8 km2,平面形态呈长条状,主要由斜长二辉橄榄岩、斜长单辉橄榄岩、角闪二辉橄榄岩、角闪橄榄岩、角闪橄榄二辉岩、黑云母化二辉岩、角闪辉石岩、橄榄辉石角闪石岩、角闪橄榄辉长岩、细粒辉长岩、似斑状辉长岩、暗色辉长岩、辉长岩、淡色辉长岩、石英闪长岩和英云闪长岩组成。文章通过岩石学、矿物学、地球化学研究,得到锆石U-Pb年龄为(361.5±1.2)Ma,Sm-Nd等时线年龄为(347±26)Ma。研究认为,牛鼻子梁基性-超基性岩体含矿岩石产于大陆边缘环境。岩体形成于泥盆纪晚期。岩浆分异充分,岩石类型丰富,岩浆演化过程中主要发生了橄榄石和斜长石的分离结晶/堆晶作用。岩体的母岩浆应属于拉斑玄武岩质岩浆。从目前发现的矿化情况来看,牛鼻子梁基性-超基性杂岩体为含矿岩体,有很好的找矿前景。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

19.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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