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大别造山带南缘蕲春混杂岩带构造属性和地质时限存在争议.本文在1/5万区域地质调查和岩石地层学研究的基础上,通过对实测剖面中四个变质沉积岩基质样品进行了碎屑锆石LA-ICP-MS U-Pb测年和原位Hf同位素分析,为混杂带的形成和演化提供约束.结果表明,碎屑锆石年龄谱主要集中在802-911 Ma,1331-1536 Ma,1776-2224 Ma,2302-2789 Ma和2868-3401 Ma等区间,存在四个明显的特征年龄峰值:～811 Ma、～1385 Ma、～2020 Ma和 ～2479 Ma;碎屑锆石εHf(t)值介于-16.2～+4.5之间,主要为负值,两阶段模式年龄变化范围在1.4-3.8 Ga之间.最年轻的岩浆成因碎屑锆石年龄约束其最晚形成时代应该不早于 ～800 Ma.综合对比区域研究结果,认为变质沉积岩的物源可能主要来自于秦岭-大别造山带中早前寒武纪基底物质和近源的新元古代岛弧带,南大别地区可能存在新元古代时期的俯冲增生记录. 相似文献
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为探讨镁铁质-超镁铁质岩的岩石学特征及成岩成矿作用时间序列, 完善区域成岩成矿年代学格架, 对平川地区的镁铁质-超镁铁质岩进行了元素地球化学分析和LA-ICP-MS锆石U-Pb定年.测试结果显示, 黄草坪辉长岩成岩年龄为259.7±1.2 Ma, 其捕获锆石结晶年龄为269.8±2.4 Ma, 辉绿(玢)岩等次火山岩参考成岩年龄为248± Ma, 其变质锆石年龄为67± Ma.研究结果表明, 平川地区的镁铁质-超镁铁质岩产出于大陆裂谷环境, 岩浆源区来自上地幔尖晶石相二辉橄榄岩, 为一套同源异相有利于铁矿化形成的富钠质拉斑玄武质岩石系列.岩浆活动开始孕育时间不晚于269.8±2.4 Ma, 大规模岩浆活动发生于259.7±1.2 Ma, 其约束了岩浆分异型和火山喷发(溢)沉积型矿化的成矿时间, 次火山岩的成岩年龄约束了次火山热液型矿化的成矿时间上限, 变质锆石U-Pb年龄记录了平川地区经历了喜马拉雅期陆内造山作用.平川地区构造岩浆活动具有爆发性、阶段性和成矿专属性等特点, 镁铁质-超镁铁质岩的形成可能与岩石圈的大规模减薄作用有关, 攀西地区海西-印支期的成岩-成矿作用为同源岩浆受区域统一深部地球动力学背景约束演化的异相产物. 相似文献
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沉积物源对油气储层发育具有重要影响.为研究丽水-椒江凹陷西斜坡明月峰组上段物源的岩性组成及其分布特征,选取4口钻井4个砂岩样品进行碎屑锆石U-Pb定年,并对陆上潜在物源区岩层(体)的岩性和年龄进行统计分析.结果显示:(1)样品中碎屑锆石以岩浆锆石为主,主要的年龄区间为125~90 Ma、145~125 Ma及170~145 Ma,还有少量变质锆石,其年龄区间为235~210 Ma及2 087~1 653 Ma;(2)陆上潜在物源区中以火山岩占绝对优势(173~94 Ma),局部区域可能有较大规模白垩系永康群沉积岩,而变质岩(＞210 Ma)和侵入岩(107.0~87.8 Ma)仅零星出露.综合分析认为:研究区东北部明月峰组上段的物源以永康群火山-沉积岩和九里坪组火山岩为主,含有少量晚白垩世侵入岩;西南部以九里坪组、西山头组火山岩及元古代区域变质岩为主,侏罗纪火山岩为辅,这一区域可能更有利于优质储层的发育. 相似文献
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扬子地块西南缘大红山群石榴白云母-长石石英片岩的白云母40Ar-39Ar定年及其地质意义 总被引：1，自引：1，他引：0
大红山群是扬子地块西南缘出露的古元古代结晶基底,主要经历了绿片岩相-低角闪岩相变质作用.本研究对大红山群老厂河组变质中酸性岩和变质沉积岩——石榴白云母-长石石英片岩中的白云母进行了40Ar-39Ar测年,得到三个样品的坪年龄和40Ar/39Ar等时线年龄结果较统一,坪年龄代表的变质年龄分别为837.7±4.2Ma、839.6±4.2Ma和844.2±4.2Ma.变质沉积岩和变质中酸性岩的变质时代类似,均介于837～845Ma.大红山群变质基性岩中变质锆石的U-Pb定年年龄为849±12Ma(杨红等,2012),40Ar-39Ar测年数据与锆石定年数据相结合,说明大红山群古元古代结晶基底中的火山岩和沉积岩均在新元古代经历了同期变质作用,其主期低角闪岩相变质作用发生于新元古代837～850Ma.结合前人发表的扬子西缘～750Ma的变质年龄,扬子西缘从北向南的区域变质作用时限可扩展到750 ～850Ma.此外,扬子西缘存在750～850Ma的岩浆事件,本文研究结果说明,扬子地块西缘在新元古代不仅发生了大规模岩浆作用,也发生了750～850Ma的区域变质作用,扬子西缘存在新元古代的岩浆-变质事件.岩浆事件与变质事件之间可能存在相关性,即新元古代岩浆作用引起了扬子西缘的区域动力热流变质作用. 相似文献
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松潘-甘孜造山带东缘的三叠纪-侏罗纪中酸性花岗岩,如塔公岩体,为晚三叠世的碰撞造山以及燕山期的构造演化提供了重要信息.区域地质调查填图表明,塔公岩体为石英闪长岩、花岗闪长岩、黑云母二长花岗岩.其地球化学特征表明岩石主体属高钾钙碱性系列、准铝质-过铝质过渡系列,稀土配分曲线显示其轻稀土富集、重稀土亏损,具有壳源岩浆特征,稀土-微量元素投点结果表明花岗岩形成于造山时期后碰撞阶段.对塔公花岗岩体采集的4件同位素样品的年龄数据质量较高,为214±1 Ma、214±1 Ma、215±1 Ma、216±1 Ma;该组年龄可以作为限制印支晚期扬子、华北和昌都板块之间碰撞时限的证据.基于塔公花岗岩类的岩石地球化学特征、同位素年代学特征,结合区域研究资料,认为松潘-甘孜造山带东缘类似塔公岩体的晚三叠世花岗岩类形成于昌都、扬子和华北地块后碰撞阶段的岩石圈拆沉作用. 相似文献
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位于藏东-滇西高原构造急剧转折地段的独龙江地区,其花岗岩体内系统垂向取样的9个花岗闪长岩样品的磷灰石裂变径迹年龄数据在4～6.8Ma之间.裂变径迹分析显示样品应处于剥露的部分退火带,其表观年龄主体表现为冷却年龄,部分具混合年龄特征.热史分析揭示出岩体至少记录了自晚中新世以来的3个显著冷却阶段.早期的时限可推至约13～8Ma,中、晚期的时限分别在约5.5Ma和2.8Ma,基本可以与区域上的不整合相对应.依据冷却史推导的各阶段剥蚀速率分别为0.10～0.12mm/a,0.26～0.3mm/a和0.85～1.02mm/a,可以与藏东-滇西高原周缘及邻区的盆地沉积记录相对应.研究结果为探讨藏东-滇西高原晚中新世以来的构造抬升-伸展变形提供了定量的参照时限. 相似文献
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内蒙古扎兰屯地区林西组以砂板岩组合为重要特征,形成时代为晚二叠世.对扎兰屯地区林西组粉砂质泥质板岩、粉砂岩2个样品进行了LA-ICP-MS锆石U-Pb测年.结果显示,150个谐和-近谐和年龄主要分布于6个年龄区间：259.7~281.9 Ma （n=18）,加权平均年龄为273.3 Ma;291.3~311.5 Ma （n=110）,加权平均年龄为298.1 Ma;319.2~334.5 Ma （n=10）,加权平均年龄为327.0 Ma;340.3~375.2 Ma （n=9）,加权平均年龄为356 Ma;399.7~400.7 Ma （n=2）,加权平均年龄为400.2 Ma;728.5~765.4 Ma （n=2）,加权平均年龄为750.0 Ma,上述6组年龄峰值与区域上的岩浆事件基本吻和.林西组主要物质供给区为研究区内早二叠世侵入岩及大石寨组火山岩,占碎屑物总含量的85%,少部分来自于晚石炭世之前的古生代侵入岩及扎兰屯群等地质体.林西组与宝力高庙组分别记录了晚古生代250~270 Ma及310~325 Ma之间发生的两次重要的区域隆升事件. 相似文献
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西昆仑康西瓦西北部库尔良早古生代角闪闪长岩花岗闪长岩锆石SHRIMP U—Pb测年 总被引：2，自引：3，他引：2
依据1:25万康西瓦幅区域地质调查成果,重点对库尔良早古生代深成岩的同位素年代学进行了详细的研究,获得了裂解期细粒黑云母角闪闪长岩锆石SHRIMP U-Pb年龄均值506.8Ma±9.8Ma,中粒似斑状花岗闪长岩单颗粒锆石U-Pb法年龄500.2Ma±1.2Ma,表明其形成时代均为中寒武世。该同位素年龄的获得,为进一步详细地研究库地-其曼于特早古生代构造-岩浆岩带的裂解时限提供了直接的时代证据。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献