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大岩子铂-钯矿区的岩石有白云岩、辉石岩脉、辉绿岩脉,矿体赋存在构造蚀变破碎带中,以外接触带的白云岩一侧为主,次为内接触带的辉石岩,矿石类型有矿化白云岩和矿化辉石岩两种类型。通过对含矿白云岩、含矿辉石岩、断层泥及辉绿岩的地球化学特征研究,认为大岩子矿床先后经历超基性岩浆的侵入,即形成辉石岩脉;基性岩浆的侵入,即形成辉绿岩脉;富含Pt、Pd的岩浆期后热液活动,即形成以Pt、Pd为丰、富含As、Cu、Sb、Ag、Cd的热液矿床,其中Pt、Pd的富集成矿主要与热液活动有关。 相似文献
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南天山古洋盆闭合、碰撞造山时限等洋-陆格局的演化过程是西天山备受关注的地球动力学问题,紧邻那拉提北缘断裂的新源地区二叠纪放射状辉绿岩墙提供了解决这个问题的良好机会。新源地区辉绿岩具辉绿结构,斑晶为斜长石和普通辉石,基质主要由斜长石、辉石、绿泥石等副矿物组成。岩石为富钠贫钾、过铝质、钙碱性岩浆系列。辉绿岩岩墙富集Rb、Th和La等元素,明显亏损Nb、Ta等元素,显示ε_(Nd)(t)为正值(+3.3～+3.8)和低的初始锶比值((~(87)Sr/~(86)Sr)_i=0.70479～0.70548),幔源物质明显。与该区石炭纪玄武岩地球化学性质相似,岩浆可能为二叠纪软流圈和岩石圈相互作用的产物,其起源与软流圈上涌有关。辉绿岩岩墙LA-ICP-MS锆石U-Pb年龄为280.4±3.6Ma,被解释为岩脉成岩年龄,即岩脉形成于二叠纪。结合区域构造背景,推测辉绿岩岩脉形成于塔里木地块与中天山-伊犁地块碰撞闭合后的板内伸展环境,并与南天山洋洋壳岩石圈板块断离密切相关。 相似文献
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工农超镁铁-镁铁岩带由橄榄岩、辉石岩、辉长岩、辉绿岩及基性火山岩组成,以构造岩片状产于工农断裂中,无就地分异现象。围岩中无明显热变质显示。橄榄岩的m/f比值为9.04~9.48,属镁质超镁铁岩。从超镁铁岩到镁铁岩,常量元素、稀土元素、微量元素有规律地变化,反映出岩石由同源岩浆分异而成。结合区域地质背景分析,工农超镁铁-镁铁岩是金沙江小洋盆向西俯冲消减过程中,攀天阁—崔依比弧间或弧后盆地扩张的产物,属科迪勒拉型蛇绿岩。 相似文献
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西昆仑库地蛇绿混杂岩由方辉橄榄岩和纯橄榄岩等地幔变质橄榄岩、豆荚状铬铁矿、堆晶橄榄岩、堆晶辉石岩和辉长岩、辉绿岩墙、块状和枕状玄武岩等组成。强亏损方辉橄榄岩为主的地幔岩组合,二辉石的低Al含量和铬尖晶石的高Cr#,以及岩石的富Mg、Ni和贫Al、Ca特征一致表明地幔橄榄岩类是经较高程度部分熔融后的地幔残余,与消减带之上蛇绿岩中的同类岩石相近。岩石富Rb、Ba、U、Th、LREE,说明地幔残余岩石受到了来自消减带的洋壳重熔组分的混染。堆晶岩以辉石岩和辉长岩为主,可能属PPG系列,指示岩浆是在消减带环境和含水条件下熔融的。辉长岩为低Ti蛇绿岩型,代表洋内弧后盆地早期环境或弧前环境。辉绿岩和玄武岩为洋中脊拉斑玄武岩和岛弧拉斑玄武岩的过渡类型;玄武岩和辉绿岩相比富Ba、Th、LREE,贫Ta,指示玄武岩较辉绿岩更多地受到来自消减带洋壳重熔组分的影响。库地蛇绿岩形成时的古构造环境是消减带之上的弧间或弧后盆地。 相似文献
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哀牢山南段长安金矿床岩浆岩的岩石学特征及其与成矿关系探讨 总被引：13，自引：12，他引：1
长安大型金矿床位于哀牢山成矿带南段,矿区内出露煌斑岩、辉长岩、辉绿岩、正长花岗岩、正长花岗斑岩等岩株和岩脉,矿体均与脉岩共生或相互切穿。各类岩浆岩和矿石的地质、岩相学、岩石地球化学的系统研究表明,矿区内岩浆岩可能为同源岩浆演化产物,但煌斑岩、辉绿岩与矿化关系更为密切。金成矿物质具有壳幔混源的特点,成矿流体由岩浆水与地层变质水混合而成。在喜山期,强烈的壳幔相互作用过程导致了区内的岩浆和热液活动,大规模富碱岩浆上侵的热驱使岩浆水循环并与矿区地层在造山作用下脱水产生的富CO2的变质水混合,萃取地层及略早形成的脉岩中的Au等成矿元素,在适宜的物理化学条件下和成矿空间内卸载并富集成矿。 相似文献
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中国北方造山带岩浆铜镍硫化物矿床及其地球动力学背景——以吉林红旗岭矿床为例 总被引：2，自引：0，他引：2
中国北方兴蒙造山带东段吉林省中南部产有一系列铜镍硫化物矿床,红旗岭矿床代表的是早三叠纪同造山期与超镁铁质-镁铁质岩浆作用相关的矿床类型.含矿母岩主要是由辉长岩-二辉岩-橄榄辉石岩-辉石橄榄岩等构成的杂岩体和顽火辉石岩超基性岩脉,构成星点状—稀疏浸染状、稠密浸染状、斑杂状、致密块状四种矿石类型.硅酸盐岩石的矿物组合为橄榄石+斜方辉石+单斜辉石+角闪石+斜长石,为钙碱性系列岩石组合类型.岩石化学显示其微量元素富集轻稀土元素和大离子亲石元素Rb、Ba,亏损高场强元素Ti、Nb,相似于俯冲带拉斑玄武岩,可能为幔源岩浆混染地壳物质的结果.同位素年代学证实岩体就位时间约为250Ma左右的早三叠纪,与区域变质和中国北方大面积的同造山花岗岩年龄相似.暗示了含矿岩体的形成和华北板块与西伯利亚板块碰撞造山作用有关,是造山挤压过渡期伸展体制下岩浆作用的产物. 相似文献
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曲德贡然巴超单元是西藏南部也拉香波倾日变质核杂岩核部的地质体，为喜山晚期岩浆侵入活动的产物，包括两个单元，绒博单元和曲珍单元，岩石系列属钙碱性系列，为明显同源岩浆演化序列，岩石地球化学元素指示具有火山弧一同构造碰撞带背景下“S”型花岗岩特征，形成于板块碰撞后陆内调整阶段，属地壳伸展拉张构造环境下的产物，从而为探讨该区的变质核杂岩穹窿成因提供了依据。 相似文献
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一种新的微细浸染型金矿——产于辉绿岩中的微细浸染型金矿特征及找矿标志 总被引：1，自引：1，他引：1
在桂西北地区新发现了两个直接产于辉绿岩中、以辉绿岩为赋矿主岩的微细浸染型金矿床(点)。金矿床受断裂构造和岩性控制,含矿岩石为蚀变辉绿岩。矿区内基性岩为成矿提供了矿源和水源,并成为直接的赋矿主岩。找矿标志为:穿过辉绿岩的断裂蚀变带;发育硅化、黄铁矿化等蚀变作用;发育Au及Au、Sb、Hg、As元素综合异常。 相似文献
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在前人研究成果和野外调查基础上,对新资深大断裂变质带特征进行系统总结,从宏观构造、显微构造与组构、岩石矿物学、年代学和地球化学等多学科角度综合研究,分析了新资断裂带各类岩石组构成因,并建立了其活动演化期次。新资深大断裂变质带构造岩主要包括定向组构系列岩石和块状系列岩石,主要是由早期的韧性变形变质作用阶段和晚期的脆性破碎作用阶段先后作用形成。越城岭岩体西侧规模巨大的花岗片麻岩带应属新资深大断裂变质带的一部分,属早期活动的产物,其原岩为越城岭岩体,为断裂变质和动力热流变质作用形成。韧性剪切系列岩石按变形变质强度可分为高温高压韧性剪切带和中温高压韧性剪切带,表明韧性剪切作用具有多期性。新资断裂带活动演化主要经历了四个阶段,始于加里东期,至喜山期均有活动,现在的新资断裂带是经过多个阶段不同类型变质作用由东向西不断迁移和相互叠加的结果。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献